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Bis(trimethylsilyl) Sulfide

Mark A. Matulenko, A. Degl'innocenti, A. Capperucci
Published 2007 · Chemistry

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[3385-94-2] C6H18SSi2 (MW 178.44) InChI = 1S/C6H18SSi2/c1-8(2,3)7-9(4,5)6/h1-6H3 InChIKey = RLECCBFNWDXKPK-UHFFFAOYSA-N (reduction of S, Se, and Te oxides;4 formation of thiocarbonyl derivatives under mild conditions;7 formation of allylsilanes from ketones or allylic alcohols13) Alternate Name: TMS2S. Physical Data: bp 164 °C; d 0.846 g cm−3. Solubility: sol diethyl ether, THF, CH2Cl2, MeCN, and aromatic solvents. Form Supplied in: colorless cloudy liquid, commercially available. Handling, Storage, and Precautions: avoid strong oxidizing agents. The reagent is moisture sensitive, flammable, and decomposes to CO, CO2, H2S, and sulfur oxides. Stench, mucous membrane (lungs, eyes) and skin irritant. Store in cool dry place free of oxygen. Use in a fume hood.
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