Online citations, reference lists, and bibliographies.
← Back to Search

Controlled Preparation Of MnO2 Hierarchical Hollow Nanostructures And Their Application In Water Treatment

Jinbo Fei, Y. Cui, X. Yan, W. Qi, Y. Yang, Kewei Wang, Q. He, J. Li
Published 2008 · Materials Science

Cite This
Download PDF
Analyze on Scholarcy
Share
Manganese oxides are of considerable importance in technological applications, including ion-exchange, molecular adsorption, catalysis, and electrochemical supercapacitors owing to their structural flexibility combined with novel chemical and physical properties. Up to now, various nanostructures of MnO2, such as nanoparticles, [6] nanorods/-belts/-wires/-tubes/fibers, nanosheets, mesoporous/molecular sieves and branched structures, urchins/orchids, and other hierarchical structures have been synthesized by different methods. Over the past years, fabrication of hierarchical hollow nanostructures has attracted significant interest because of their widespread potential applications in catalysis, drug delivery, acoustic insulation, photonic crystals, and other areas. Until now, the general approach for preparation of hollow structures has involved the use of various removable or sacrificial templates, referred to as “hard”, such as monodispersed silica, polymer latex spheres and reducing metal nanoparticles, as well as “soft” ones, for example, emulsion droplets/ micelles and gas bubbles. Furthermore, lots of one-pot template-free methods for generating hollow inorganic microand nanostructures have been developed employing novel mechanisms, including the nanoscale corrosion-based insideout evacuation and Kirkendall effect. Recently, rhombododecahedral silver cages have been prepared by self-assembly coupled with the precursor crystal-templating approach. By treating the external morphologies of hollow structures, unique properties can be obtained. Thus, it is desirable to develop easy methods to control the morphologies of assembled systems with well-defined hierarchical structures. Herein, we report a simple controlled preparation of hierarchical hollow microspheres and microcubes of MnO2 nanosheets through self-assembly with an intermediate crystaltemplating process. As shown in Figure 1, the synthesis is performed by a three-step process. Particularly, discrete spherical and cubic hollow MnO2 nanostructures with controlled morphologies can be prepared by changing the morphologies of MnCO3 precursors, which can be simply obtained by adding the (NH4)2SO4 solution in the reaction system, and the
This paper references
10.1002/ANIE.200502722
Corrosion-based synthesis of single-crystal Pd nanoboxes and nanocages and their surface plasmon properties.
Y. Xiong (2005)
10.1002/1521-3773(20020118)41:2<333::AID-ANIE333>3.0.CO;2-5
From Surfactant–Inorganic Mesostructures to Tungsten Nanowires The authors thank Prof. G. D. Stucky for helpful discussions. This work was supported by the National Science Foundation of China and the State key project of Fundamental Research for Nano-materials and Nano-structures.
Y. Li (2002)
10.1039/B111723H
Rational synthesis of α-MnO2 single-crystal nanorods
Xun Wang (2002)
10.1126/SCIENCE.282.5391.1111
Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating
Caruso (1998)
10.1021/CM049025D
Structural Characterization of Self-Assembled MnO2 Nanosheets from Birnessite Manganese Oxide Single Crystals
X. Yang (2004)
10.1002/ANIE.200250695
ZnSe semiconductor hollow microspheres.
Q. Peng (2003)
10.1016/J.ULTSONCH.2005.09.010
Organized and highly dispersed growth of MnO2 nano-rods by sonochemical hydrolysis of Mn3acetate.
V. Kumar (2006)
10.1002/ADFM.200500504
Hydrothermal Synthesis of Structure‐ and Shape‐Controlled Manganese Oxide Octahedral Molecular Sieve Nanomaterials
Wei-Na Li (2006)
10.1021/CM049285V
Nanocrystalline α-MnO2 Nanowires by Electrochemical Step-Edge Decoration
Qiguang Li (2004)
10.1021/CM0217809
Synthesis of a Li−Mn-oxide with Disordered Layer Stacking through Flocculation of Exfoliated MnO2 Nanosheets, and Its Electrochemical Properties
L. Wang (2003)
10.1002/CHEM.200390024
Synthesis and formation mechanism of manganese dioxide nanowires/nanorods.
Xun Wang (2003)
10.1016/S0927-7757(03)00195-X
Carbonate microparticles for hollow polyelectrolyte capsules fabrication
A. Antipov (2003)
10.1038/nature05570
Chemical reduction of three-dimensional silica micro-assemblies into microporous silicon replicas
Z. Bao (2007)
10.1002/1521-3757(20020118)114:2<343::AID-ANGE343>3.0.CO;2-Q
From surfactant-inorganic mesostructures to tungsten nanowires.
Y. Li (2002)
10.1016/J.CATCOM.2005.12.008
Large-scale synthesis of β-MnO2 nanorods and their rapid and efficient catalytic oxidation of methylene blue dye
W. Zhang (2006)
10.1021/ES001848Q
Mn(III) center availability as a rate controlling factor in the oxidation of phenol and sulfide on delta-MnO2.
P. Nico (2001)
10.1021/JA0177105
Selected-Control Hydrothermal Synthesis of α- and β-MnO2 Single Crystal Nanowires
Xun Wang (2002)
10.1016/J.MATERRESBULL.2006.04.011
A redox-assisted supramolecular assembly of manganese oxide nanotube
Li Tao (2006)
10.1002/ANIE.200461859
Morphosynthesis of rhombododecahedral silver cages by self-assembly coupled with precursor crystal templating.
J. Yang (2005)
10.1021/JA021364P
Redoxable nanosheet crystallites of MnO2 derived via delamination of a layered manganese oxide.
Yoshitomo Omomo (2003)
10.1002/ADFM.200400222
Synthesis of MnO2 Nanoparticles Confined in Ordered Mesoporous Carbon Using a Sonochemical Method
S. Zhu (2005)
10.1166/JNN.2006.371
Microemulsion-mediated solvothermal synthesis and morphological evolution of MnCO3 nanocrystals.
X. Wu (2006)
10.1021/CM061458O
Highly Electrochemical Reaction of Lithium in the Ordered Mesoporosus β-MnO2
Jiayan Luo (2006)
10.1021/NL0343598
Ultrathin, protective coatings of poly(o-phenylenediamine) as electrochemical proton gates: Making mesoporous MnO2 nanoarchitectures stable in acid electrolytes
J. Long (2003)
10.1002/(SICI)1521-4095(199903)11:4<324::AID-ADMA324>3.0.CO;2-A
MORPHOSYNTHESIS OF CALCIUM CARBONATE (VATERITE) MICROSPONGES
D. Walsh (1999)
10.1002/ADMA.200600504
Self‐Assembled 3D Flowerlike Iron Oxide Nanostructures and Their Application in Water Treatment
Liangshu Zhong (2006)
10.1039/B610601C
MoS2 hierarchical hollow cubic cages assembled by bilayers: one-step synthesis and their electrochemical hydrogen storage properties.
Lina Ye (2006)
10.1016/J.MATLET.2005.07.070
Preparation of α-Mn2O3 and MnO from thermal decomposition of MnCO3 and control of morphology
Shuijin Lei (2006)
10.1021/CG050221M
Rational Growth of Various α-MnO2 Hierarchical Structures and β-MnO2 Nanorods via a Homogeneous Catalytic Route
Zhengquan Li (2005)
10.1063/1.1873044
Hollow nanostructures based on the Kirkendall effect: Design and stability considerations
K. Tu (2005)
10.1021/JP052370L
One-Step Preparation of Single-Crystalline β-MnO2 Nanotubes
Deshan Zheng (2005)
10.1002/1521-3773(20020617)41:12<2163::AID-ANIE2163>3.0.CO;2-G
Morphosynthesis of Octacalcium Phosphate Hollow Microspheres by Polyelectrolyte-Mediated Crystallization
A. Bigi (2002)
10.1021/CM034191R
Fabrication and Characterization of Multilayer Ultrathin Films of Exfoliated MnO2 Nanosheets and Polycations
L. Wang (2003)
10.1039/B615972A
Templated synthesis of hierarchically porous manganese oxide with a crystalline nanorod framework and its high electrochemical performance
H. Chen (2007)
10.1002/(SICI)1521-3765(20000204)6:3<413::AID-CHEM413>3.0.CO;2-9
Hollow capsule processing through colloidal templating and self-assembly
Caruso (2000)
10.1002/(SICI)1521-4095(200002)12:3<206::AID-ADMA206>3.0.CO;2-5
Preparation of Mesoscale Hollow Spheres of TiO2 and SnO2 by Templating Against Crystalline Arrays of Polystyrene Beads
Ziyi Zhong (2000)
10.1063/1.119253
Microstructural study of hollandite-type MnO2 nano-fibers
M. Benaissa (1997)
10.1126/science.221.4607.259-a
Peroxidase-Catalyzed Removal of Phenols from Coal-Conversion Waste Waters
A. Klibanov (1983)
10.1002/1521-3757(20020617)114:12<2267::AID-ANGE2267>3.0.CO;2-N
Morphosynthesis of octacalcium phosphate hollow microspheres by polyelectrolyte-mediated crystallization.
A. Bigi (2002)
10.1002/ADMA.200602499
Mesoporous Crystalline β‐MnO2—a Reversible Positive Electrode for Rechargeable Lithium Batteries
F. Jiao (2007)
10.1016/0021-9797(87)90470-X
Preparation of monodispersed manganese (IV) oxide particles from manganese (II) carbonate
S. Hamada (1987)
10.1126/SCIENCE.279.5348.208
A laser ablation method for the synthesis of crystalline semiconductor nanowires
Morales (1998)
10.1126/SCIENCE.1093276
Self-Assembly of Mesoscopic Metal-Polymer Amphiphiles
Sungho Park (2004)
10.1039/B414204G
One-step solution-based catalytic route to fabricate novel alpha-MnO2 hierarchical structures on a large scale.
Zhengquan Li (2005)
10.1039/B511296F
Synthetic architecture of interior space for inorganic nanostructures
H. Zeng (2006)
10.1002/ADFM.200500436
Hydrothermal Growth of Manganese Dioxide into Three‐Dimensional Hierarchical Nanoarchitectures
Y. Ding (2006)
10.1002/ADMA.200401183
Synthesis of monodisperse colloidal spheres, capsules, and microballoons by emulsion templating
C. I. Zoldesi (2005)
10.1002/CHEM.200390189
Growth of well-aligned gamma-MnO2 monocrystalline nanowires through a coordination-polymer-precursor route.
Y. Xiong (2003)
10.1021/JA0434073
Generating MnO2 nanoparticles using simulated amorphization and recrystallization.
T. X. Sayle (2005)
10.1021/JA048195O
Mesoscale organization of CuO nanoribbons: formation of "dandelions".
B. Liu (2004)
10.1016/J.APSUSC.2004.04.035
γ-MnO2 nano-sieve membrane: preparation, characterization and reaction studies
Lili Zhao (2004)
10.1038/381499A0
Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries
A. Armstrong (1996)
10.1021/IC051715B
Facile controlled synthesis of MnO2 nanostructures of novel shapes and their application in batteries.
F. Cheng (2006)
10.1021/NL0345062
Large-scale hierarchical organization of nanowire arrays for integrated nanosystems
D. Whang (2003)
10.1002/ANIE.200352956
Pt hollow nanospheres: facile synthesis and enhanced electrocatalysts.
Han-Pu Liang (2004)
10.1016/J.JCRYSGRO.2006.06.046
Solvothermal route synthesis of single-crystalline α-MnO2 nanowires
G. Yue (2006)
10.1021/NL062263I
Incorporation of homogeneous, nanoscale MnO2 within ultraporous carbon structures via self-limiting electroless deposition: implications for electrochemical capacitors.
Anne E. Fischer (2007)
10.1021/JA048940X
Electrochemical catalysis of styrene epoxidation with films of MnO(2) nanoparticles and H(2)O(2).
L. Espinal (2004)
10.1126/SCIENCE.1096566
Formation of Hollow Nanocrystals Through the Nanoscale Kirkendall Effect
Y. Yin (2004)
10.1126/SCIENCE.1074868
Colloidosomes: Selectively Permeable Capsules Composed of Colloidal Particles
A. Dinsmore (2002)
10.1002/EJIC.200500983
Facile and Selected‐Control Synthesis of β‐MnO2 Nanorods and Their Magnetic Properties
G. Wang (2006)
10.1088/0957-4484/16/10/015
Large-area synthesis of high-quality beta-MnO(2) nanowires and the mechanism of formation through a facile mineralization process.
F. Zhou (2005)
10.1126/SCIENCE.1070821
Self-Assembly at All Scales
G. Whitesides (2002)
10.1002/ANIE.200501556
General synthetic route toward functional hollow spheres with double-shelled structures.
M. Yang (2005)
10.1088/0957-4484/18/2/025601
Template-free low temperature hydrothermal synthesis and characterization of rod-shaped manganese oxyhydroxides and manganese oxides
J. Sampanthar (2007)
10.1021/JA026032Z
Fabrication of hollow palladium spheres and their successful application to the recyclable heterogeneous catalyst for suzuki coupling reactions.
S. Kim (2002)
10.1021/JA0294459
Self-assembly of microporous manganese oxide octahedral molecular sieve hexagonal flakes into mesoporous hollow nanospheres.
Jikang Yuan (2003)
10.1126/SCIENCE.1090163
Self-Assembled Silica-Carbonate Structures and Detection of Ancient Microfossils
J. García-Ruiz (2003)
10.1016/J.APSUSC.2005.02.126
Nano-porous manganese oxide formed by self-assembled agglomeration of nanocrystallites
Nobuyasu Suzuki (2005)
10.1021/CG060223M
Novel Branched ?-MnOOH and -MnO 2 Multipod Nanostructures
Deshan Zheng (2006)
10.1016/J.JCRYSGRO.2005.09.012
Multiple branched α-MnO2 nanofibers: A two-step epitaxial growth
Yuanhui Zheng (2006)



This paper is referenced by
10.1002/9783527670819.CH11
Hollow Inorganic Spheres
Atsushi Shimojima (2015)
10.1016/J.PHYSE.2014.08.006
Adsorptive removal and kinetics of methylene blue from aqueous solution using NiO/MCM-41 composite
X. Xiao (2015)
10.1039/C4RA11032C
Synthesis of porous MgAl2O4 spinel and its superior performance for organic dye adsorption
Junying Tian (2015)
10.1039/C4TA05995F
The anion effect on the oxygen reduction of MnX (X = O, S, and Se) catalysts
X. Liu (2015)
10.1142/S1793292018500042
Facile Fabrication of Hollow Li3PO4 Catalyst via Ostwald Ripening
Jihai Zhang (2017)
10.1039/C5EW00152H
Inorganic engineered nanoparticles in drinking water treatment: a critical review
Konstantinos Simeonidis (2016)
10.1016/J.MATLET.2014.08.048
Facile synthesis of hollow sphere MnCO3: A cheap and environmentally benign anode material for Li-ion batteries
T. Kesavan (2014)
10.1002/advs.201600162
Self‐Templated Synthesis of Ultrathin Nanosheets Constructed TiO2 Hollow Spheres with High Electrochemical Properties
Huiqi Xie (2016)
10.1016/J.MICROMESO.2015.09.055
Fabrication synthesis of porous Al2O3 hollow microspheres and its superior adsorption performance for organic dye
Jun-ying Tian (2016)
10.1002/9783527610419.NTLS0145
Metal Oxide Nanomaterials for Water Treatment
Jinbo Fei (2010)
10.1021/la402769u
Shape-controlled synthesis of hollow silica colloids.
Yong Wang (2013)
10.1039/C5RA26362J
Fabrication of manganese dioxide/carbon/attapulgite composites derived from spent bleaching earth for adsorption of Pb(II) and Brilliant green
Jie Tang (2016)
10.1142/S1793604718500078
Effects of Sn doping on capacitive performance of σ-MnO2 on the high operating temperatures
H. Lin (2017)
10.1021/am404457u
Preparation and enhanced photocatalytic activity of TiO₂ nanocrystals with internal pores.
Lu Ren (2014)
10.1002/anie.201105283
Highly active nanoreactors: nanomaterial encapsulation based on confined catalysis.
Marcos Sanlés-Sobrido (2012)
10.1063/1.4705516
Controlled synthesis and electromagnetic performance of hollow microstructures assembled of tetragonal MnO2 nano-columns
Yuping Duan (2012)
10.12677/JAPC.2014.33003
单分散锐钛矿型TiO 2 亚微米球的制备与光催化性能研究 Synthesis and Photocatalytic Activity of Uniform Anatanse TiO 2 Sub-Microspheres
巧娜 李 (2014)
10.1016/J.COLSURFA.2016.10.025
Removal of Cr(VI) and Hg(II) ions from wastewater by novel β-CD/MGO-SO3H composite
Y. Liu (2017)
10.1016/j.electacta.2020.135991
Dual-confined sulfur cathodes based on SnO2-decorated MoS2 microboxes for long-life lithium–sulfur batteries
Fan Li (2020)
10.1039/C1JM11950H
Large-scale preparation of 3D self-assembled iron hydroxide and oxide hierarchical nanostructures and their applications for water treatment
Jinbo Fei (2011)
10.1016/J.MSEB.2008.12.036
Synthesis and characterization of ZnO and TiO2 hollow spheres with enhanced photoreactivity
X. Li (2009)
10.1021/am406009t
Layered NaxMnO₂+z in sodium ion batteries-influence of morphology on cycle performance.
Nicolas Bucher (2014)
10.1088/2053-1591/AAD2C6
Novel ZnO–MnO2–Cu2O triple nanocomposite: Facial synthesis, characterization, antibacterial activity and visible light photocatalytic performance for dyes degradation-A comparative study
Vahid Hoseinpour (2018)
10.1038/srep13299
Investigation on preparation and performance of spinel LiNi0.5Mn1.5O4 with different microstructures for lithium-ion batteries
Y. Xue (2015)
10.4028/www.scientific.net/MSF.688.107
Facile Controlled Synthesis of Manganese Oxide Hierarchical Microspheres by Hydrothermal Method
Dong Yan Li (2011)
10.1039/c5cc01554e
Facile fabrication of diphenylalanine peptide hollow spheres using ultrasound-assisted emulsion templates.
Q. Li (2015)
10.1016/j.cej.2020.124458
Oxygen-defective MnO2−x rattle-type microspheres mediated singlet oxygen oxidation of organics by peroxymonosulfate activation
Jie Yu (2020)
10.1039/C1JM13964A
Large-scale preparation of hierarchical manganese oxide octahedral molecular sieves (OMS-1) composed of nanoplate microspheres via a facile one-pot reflux method
Hao-jie Cui (2011)
10.1016/J.ELECTACTA.2016.01.106
Rational synthesis of Cu-doped porous δ-MnO2 microsphere for high performance supercapacitor applications
Shuoqing Zhao (2016)
10.1016/J.APT.2019.02.007
Synthesis of mono-dispersed mesoporous Mn2O3 powders with micro-nanostructure for removing Congo red dye from aqueous solution
Guicai Qi (2019)
10.1016/J.SPMI.2014.06.022
Structure, morphologies and dye removal efficiency of ZnO nanorods grown on polycrystalline Zn substrate
Tiantian Yin (2014)
10.1016/J.JPOWSOUR.2014.06.034
Hierarchical hollow urchin-like NiCo2O4 nanomaterial as electrocatalyst for oxygen evolution reaction in alkaline medium
J. Wang (2014)
See more
Semantic Scholar Logo Some data provided by SemanticScholar