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Kleider Machen Leute: Heck-Reaktion Im Neuen Gewand†

A. D. Meijere, Frank E. Meyer
Published 1994 · Art

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Die von Richard F. Heck Ende der sechziger Jahre entdeckte Palladium-katalysierte Kupplung von Aryl- und Alkenylhalogeniden mit Alkenen hat sich nach gelegentlichem Auf- und Abschwellen des darauf gerichteten Interesses in den letzten sechs Jahren nachhaltig gemausert. Durch geschickte Auswahl der Substrate und sorgfaltige Anpassung der Reaktionsbedingungen gelingen beeindruckende Sequenzen auch unterschiedlicher Reaktionstypen nicht nur nacheinander, sondern vielfach in einem einzigen Verfahrensschritt. Die mittlerweile etablierte Heck-Reaktion – und eine Reihe mit ihr mechanistisch verwandter Palladium-katalysierter Umwandlungen an Aren-, Alken- und Alkinderivaten – bietet ungezahlte Moglichkeiten, elegant und hochkonvergent komplexe Molekule aufzubauen; dabei bereiten Sauerstoff- und Stickstoffatome (mit Einschrankungen auch Schwefel- und Phosphoratome) in den Reaktionen keine Probleme. Das Spektrum der neueren Erfolge beginnt mit den chemo- und regioselektiven Einfachkupplungen hochfunktionalisierter Substrate mit unsymmetrisch mehrfach substituierten Reaktionspartnern. Es reicht allerdings viel weiter uber Kaskadenreaktionen mit Knupfung von drei, vier, funf oder gar acht neuen CC-Bindungen unter Bildung von oligofunktionellen und oligocyclischen Produkten von beeindruckender Molekulkomplexitat bis hin zum enantioselektiven Aufbau von anspruchsvollen Naturstoffmolekulen mit quartaren stereogenen Zentren, wie die Beispiele Crinan, Picrotoxinin, Morphin und viele mehr belegen. Zweifellos last sich schon heute die Heck-Reaktion aus dem Methodenarsenal der praparativen Organischen Chemie nicht mehr wegdenken; abzuwarten bleibt lediglich, wann sie Einzug in ein industrielles Produktionsverfahren halten wird.
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10.1016/S0040-4039(00)84489-5
Synthesis of allylic alcohols via organopalladium additions to unsaturated epoxides
R. Larock (1986)
10.1246/BCSJ.59.927
Synthesis of 3-Substituted Indoles by a Palladium-Assisted Reaction
A. Kasahara (1986)
10.1351/pac198658060869
New synthetic reactions catalyzed by palladium complexes
J. Tsuji (1986)
10.1021/JA00271A037
Palladium-catalyzed coupling of vinyl triflates with organostannanes. Synthetic and mechanistic studies
W. Scott (1986)
10.1002/ANGE.19860980605
Palladium‐katalysierte Kupplungsreaktionen organischer Elektrophile mit Organozinn‐Verbindungen
J. Stille (1986)
10.1016/S0040-4039(00)87818-1
Palladium-catalysed reductive addition of aryl iodides to aryl and alkylethynylsilanes: A stereo and regioselective route to functionalized 2,2-disubstituted vinylsilanes
A. Arcadi (1986)
10.1016/S0040-4039(00)85084-4
Complete reversal of regiochemistry in cyclic acylpalladation. Novel synthesis of quinones.
E. Negishi (1986)
10.1021/JA00270A043
Palladium-catalyzed regio- and stereoselective cyclized coupling of lithium alkynoates with allyl halides
N. Yanagihara (1986)
10.1021/JA00278A065
Triply convergent synthesis of (-)-prostaglandin E2
C. Johnson (1986)
10.1016/S0040-4020(01)82115-3
Syntheses of (5E)-PGE2 and New 6-Functionalized Derivatives by the Use of Palladium-Catalyzed Decarboxylative Allylic Alkylation
T. Tanaka (1986)
10.1016/S0040-4039(00)84856-X
12-methylidene-10(Z), 13(Z)-nonadecadienoic acid, a new irreversible inhibitor of soybean lipoxygenase
E. Corey (1986)
10.1016/S0040-4039(00)83920-9
Palladium-catalyzed carbonylation of aryl triplates. Synthesis of arenecarboxylic acid derivatives from phenols
S. Cacchi (1986)
10.1016/S0040-4039(00)85262-4
Palladium catalyzed triethylammonium formate reduction of aryl triflates. A selective method for the deoxygenation of phenols.
S. Cacchi (1986)
10.1016/0022-328X(86)84065-7
Transition metals and olefins. A promising land: A personal account
B. Trost (1986)
10.1016/0022-328X(86)84056-6
Group VIII metal-catalyzed CC bond-forming sequences
G. Chiusoli (1986)
10.1021/JO00376A044
Synthesis of (E)-(2-arylethenyl)silanes by palladium-catalyzed arylation of vinylsilanes in the presence of silver nitrate
K. Karabelas (1986)
10.1002/ANIE.198605081
The Palladium‐Catalyzed Cross‐Coupling Reactions of Organotin Reagents with Organic Electrophiles [New Synthetic Methods (58)]
J. Stille (1986)
10.1021/JA00280A003
Theoretical Studies of Oxidative Addition and Reductive Elimination. 3. C-H and C-C Reductive Coupling from Palladium and Platinum Bis( phosphine) Complexes
J. J. Low (1986)
10.1016/S0040-4039(00)83898-8
Carbopalladation des alkylidenecyclopropanes. obtention de dienes-1,3 et de styrenes fonctionnalises.
G. Balme (1986)
10.1021/JO00363A009
Synthesis and chemistry of alkylpalladium compounds prepared via vinylpalladation of bicyclic alkenes
R. Larock (1986)
10.1016/S0040-4039(00)84208-2
Palladium-catalyzed reaction of phenyl fluoroalkanesulfonates with alkynes and alkenes
Q. Chen (1986)
10.1021/JO00374A041
Transition-metal-catalyzed reactions of trimethylsilyl cyanide. 4. Palladium-catalyzed cyanation of aryl halides by trimethylsilyl cyanide
N. Chatani (1986)
10.1021/JO00366A004
Stereocontrolled total synthesis of 1.alpha.,25-dihydroxycholecalciferol and 1.alpha.,25-dihydroxyergocalciferol
E. Baggiolini (1986)
10.1016/0022-328X(86)80306-0
The reaction of aryl iodides with hindered α,β,γ,δ-dienones in the presence of the [Pd(OAc)2(PPh3)2]-trialkylammonium formate reagent
A. Arcadi (1986)
10.1016/0022-328X(86)84066-9
25 Years in the Organic Chemistry of Palladium
J. Tsuji (1986)
10.1016/S0040-4020(01)87528-1
Synthesis of polycyclic ketones via carbonylative cyclization of organopalladium compounds derived from norbornene and norbornadiene
R. Larock (1986)
10.1016/S0040-4039(00)84303-8
Palladium-catalyzed synthesis of dienynes related to vitamin D from enol triflates
L. Castedo (1986)
10.1016/S0040-4020(01)87277-X
New general synthetic methods involving π-allylpalladium complexes as intermediates and neutral reaction conditions
J. Tsuji (1986)
10.1039/CS9871600187
Stereochemical aspects of the intramolecular Diels–Alder reaction
Donald Craig (1987)
10.1021/JO00383A019
Stereospecific arylation of alkenylsilanes with arylpalladium acetates
K. Ikenaga (1987)
10.1080/00397918708057796
Pteridines. 52. A Convenient Synthesis of 6-Formylpterin1
E. Taylor (1987)
10.1021/JA00245A064
Metal-mediated approach to enynes
B. Trost (1987)
10.1016/S0040-4039(01)81080-7
Palladium-catalyzed acylation of activated alkenes with bridgehead acid chlorides
K. Hori (1987)
10.1016/S0040-4039(00)96279-8
A novel approach to α-keto acid derivatives via palladium-catalyzed arylation and vinylation of methyl α-methoxyacrylate
S. Cacchi (1987)
10.1016/S0040-4020(01)81636-7
Formation de dérivés cyclopenténiques et vinylcyclopropaniques lors de la carbopalladation de diesters et d'α-sulfonylesters alléniques
M. Ahmar (1987)
10.1016/S0040-4039(00)95764-2
A preparation of 3-aryl-2,5-dihydrothiophene-1,1-dioxides from aryl iodides
P. Harrington (1987)
10.1002/ANGE.19870991213
Ein einfacher, allgemeiner Zugang zu brückenanellierten [2.2]Paracyclophandienen†‡
O. Reiser (1987)
10.1002/ANIE.198712771
A Facile, General Route to Bridge‐Annelated [2.2]Paracyclophanedienes
O. Reiser (1987)
10.1021/OM00144A030
Palladium chloride-sodium bicarbonate-catalyzed phenylation of acyclic allylic alcohols. 3. 1,2-Chirality transfer in a Heck reaction via a Wacker-type intermediate
W. Smadja (1987)
10.1021/JO00392A007
Regiochemistry of palladium-catalyzed arylation reactions of enol ethers. Electronic control of selection for .alpha.- or .beta.-arylation
C. Andersson (1987)
10.1016/S0040-4039(00)96556-0
Attaque nucleophile intramoleculaire d'organopalladiques issus de la carbopalladation d'alkylidenecyclopropanes.
Guy Fournet (1987)
10.1021/JO00227A038
Intramolecular alkene arylations for rapid assembly of polycyclic systems containing quaternary centers. A new synthesis of spirooxindoles and other fused and bridged ring systems
M. M. Abelman (1987)
10.1021/JO00391A002
Novel synthesis of .alpha.,.beta.-unsaturated ketones by the palladium-catalyzed arylation of ketenes with aroyl chlorides or the decarbonylative cross-condensation of acyl halides
T. Mitsudo (1987)
10.1021/JA00249A065
Biomimetic aerobic 1,4-oxidation of 1,3-dienes catalyzed by cobalt tetraphenylporphyrin-hydroquinone-palladium(II). An example of triple catalysis
Jan-E Bäckvall (1987)
10.1021/ja00237a029
Stereospecific cross-coupling of vinyl halides with vinyl tin reagents catalyzed by palladium
J. Stille (1987)
10.1016/S0040-4039(00)95678-8
Efficient palladium-mediated synthesis of a spirocyclic model for fredericamycin A.
M. Ciufolini (1987)
10.1016/S0040-4020(01)86782-X
Organopalladium approaches to prostaglandins. 7.1
R. Larock (1987)
10.1016/S0040-4039(00)95818-0
A route to conformationally restricted antioestrogens by coupling of a vinyl triflate with an aryl zinc chloride
R. Mccague (1987)
10.1021/JA00248A032
Palladium-catalyzed reactions in the synthesis of 3- and 4-substituted indoles. 2. Total synthesis of the N-acetyl methyl ester of (.+-.)-clavicipitic acids
P. Harrington (1987)
10.1021/JA00242A024
Palladium- or nickel-catalyzed reactions of alkenylmetals with unsaturated organic halides as a selective route to arylated alkenes and conjugated dienes: scope, limitations, and mechanism
E. Negishi (1987)
10.1016/S0040-4039(00)96615-2
Stereoselective synthesis of bicyclo[3.3.0]oct-1-en-3-one derivatives
F. Camps (1987)
10.1016/S0040-4039(00)95465-0
Palladium catalyzed stereospecific Michael arylation of 6-alkyl-5,6-dihydro-2H-pyran-2-ones
G. Stokker (1987)
10.1016/S0040-4039(00)96710-8
Synthesis of nitrogen heterocycles via palladium-catalyzed intramolecular cyclization
R. Larock (1987)
10.1016/S0040-4039(00)95583-7
A regiospecific benzoylation of alkyl vinyl ethers catalysed by palladium
C. Andersson (1987)
10.1055/S-1991-26621
Preparation of 2,3,4,5-Tetrahydropyridines from 5-Alkynylamines Under the Catalytic Action of Gold(III) Salts
Y. Fukuda (1987)
10.1080/00397918708063906
A Palladium-Catalyzed Synthesis of β-Ionone from 2,2,6-Trimethylcyclohexanone
T. Breining (1987)
10.1016/S0040-4039(00)95372-3
Syntheses of the picrotoxane skeleton via the palladium (II) - catalyzed carbacyclization reaction
B. Trost (1987)
10.1021/JO00246A055
Palladium(0)-catalyzed cyclization followed by allylation of allylic alkynoates and a related system
T. Tsuda (1988)
10.1016/S0040-4039(00)82478-8
Palladium-catalyzed intermolecular allylic arylation of cyloalkenes
R. Larock (1988)
10.1016/S0040-4020(01)86659-X
Reactions of vinylsilanes with lewis acid-activated iodosylbenzene: stereospecific syntheses of vinyliodonium tetrafluoroborates and their reactions as highly activated vinyl halides
M. Ochiai (1988)
10.1021/JA00222A033
Prostaglandin synthesis. 16. The three-component coupling synthesis of prostaglandins
Masaaki Suzuki (1988)
10.1002/ANIE.198811133
Transition Metals in the Synthesis and Functionalization of Indoles [New Synthesis Methods (72)]
L. Hegedus (1988)
10.1016/S0040-4039(00)80458-X
Synthesis of a Calicheamicin Deoxyaglycone Model by an Intramolecular Acetylide Cyclization
A. Kende (1988)
10.1016/S0040-4039(00)82114-0
Synthesis studies directed toward gelsemine. Preparation of an advanced pentacyclic intermediate
W. Earley (1988)
10.1021/JA00215A068
Palladium-catalyzed polyene cyclizations of dienyl aryl iodides
M. M. Abelman (1988)
10.1016/S0040-4020(01)90347-3
Regiospecific formation of 1,3-dienes by the palladium catalysed intra- and inter-molecular coupling of vinyl halides.1
R. Grigg (1988)
10.1021/JO00256A003
Synthesis of 1-trimethylsilyl 1,3-dienes by the palladium-catalyzed reaction of trimethylvinylsilane with vinyl iodides/silver nitrate or vinyl triflates
K. Karabelas (1988)
10.1016/S0040-4039(00)80581-X
Synthesis of benzofurans via palladium-promoted cyclization of ortho-substituted aryl allyl ethers
R. Larock (1988)
10.1016/0040-4039(88)85101-3
A concise, palladium-catalyzed approach to (±)-lysergic acid
S. Cacchi (1988)
10.1002/ANGE.19881000904
Synthese und Funktionalisierung von Indolen mit Übergangsmetallreagentien
L. Hegedus (1988)
10.1021/CR00089A006
Transition metal-mediated cycloaddition reactions of alkynes in organic synthesis
N. Schore (1988)
10.1016/0167-6989(88)90250-4
[Poly(styryl)phenanthroline]palladium catalyst. Synthesis and some of its applications in vinylic substitution reactions with organic halides
Zhang Zhuangyu (1988)
10.1021/JO00249A018
Isoquinolinium salt syntheses from cyclopalladated benzaldimines and alkynes
Guangzhong. Wu (1988)
10.1021/JA00218A048
Palladium-catalyzed arylation of siloxycyclopropanes with aryl triflates. Carbon chain elongation via catalytic carbon-carbon bond cleavage
S. Aoki (1988)
10.1016/S0040-4039(00)80263-4
A Synthesis of β-necrodol via a palladium catalyzed reductive enyne cyclization
Barry M. Trost (1988)
10.1016/S0040-4039(00)80814-X
Regiospecific palladium catalysed tandem cyclisation-anion capture processes. Stereospecific group transfer from organotin reagents.
Barry Burns (1988)
10.1021/JO00239A056
Cross-coupling of organosilanes with organic halides mediated by a palladium catalyst and tris(diethylamino)sulfonium difluorotrimethylsilicate
Y. Hatanaka (1988)
10.1016/S0040-4039(00)82356-4
Synthesis of vinylic lactones via palladium-catalyzed coupling of vinylic halides or triflates and unsaturated carboxylic acids
R. Larock (1988)
10.1021/JO00244A052
Regioselective palladium-catalyzed arylation of vinyl ethers with 4-nitrophenyl triflate. Control by addition of halide ions
C. Andersson (1988)
10.1021/JA00216A045
In situ cuprate formation via transmetalation between vinylstannanes and higher order cyanocuprates
James R. Behling (1988)
10.1016/S0040-4039(00)82047-X
Palladium catalyzed reaction of 2-alkynylanilines with allyl chlorides. Formation of 3-allylindoles
K. Iritani (1988)
10.1021/JO00253A026
Mercury in organic chemistry. 36. Synthesis of (.pi.-allyl)palladium compounds and 1,4-dienes via vinylpalladation of monocyclic alkenes
R. C. Larock (1988)
10.1016/S0040-4020(01)90346-1
The regioselectivity of rhodium and palladium-catalysed cyclisations of 2-bromo-1,6- and -1,7-dienes
R. Grigg (1988)
10.1016/S0040-4039(00)86722-2
Evidence for (π-allyl)palladium(II)(quinone) complexes in the palladium-catalyzed 1,4-diacetoxylation of conjugated dienes
Jan-Erling Bäckvall (1988)
10.1021/JA00216A053
Bimetallic catalysis. A new method for the activation of chloroarenes toward palladium-catalyzed coupling with olefins
J. Bozell (1988)
10.1016/0040-4039(88)85042-1
Dual binding modes to the receptor for platelet activating factor (PAF) of anti-paf trans-2,5-diarylfurans
E. Corey (1988)
10.1016/S0040-4039(00)80167-7
Synthesis of silylated 1,3-dienes via the carbopalladation of allenes.
B. Cazes (1988)
10.1016/S0040-4039(00)82444-2
Palladium-catalyzed cyclic acylmetalation of allylic electrophiles as a route to cyclopentenone derivatives
E. Negishi (1988)
10.1016/0022-328X(88)87019-0
Palladium-(II) and -(IV) complexes as intermediates in catalytic CC bond-forming reactions
M. Catellani (1988)
10.1016/S0040-4020(01)85839-7
The palladium-tributylammonium formate reagent in the stereoselective hydrogenation, and stereo- and regioselective hydroarylation of alkyl 4-hydroxy-2-alkynoates: a route to substituted butenolides
A. Arcadi (1988)
10.1016/0040-4039(88)85047-0
Synthesis of bicyclic and polycyclic alkenes via palladium-catalyzed intramolecular arylation and vinylation
R. Larock (1988)
10.1016/S0040-4039(00)80488-8
Palladium catalysed tandem cyclisation-anion capture processes.Hydride ion capture by vinylpalladium species.
Barry Burns (1988)
10.1016/S0040-4039(00)80424-4
Vinyl trifluorosulfonates in the carbopalladation of allenic hydrocarbons
B. Friess (1988)
10.1016/S0040-4039(00)80681-4
Synthesis of homoallylic alcohols via palladium-catalyzed coupling of organomercurials and vinylic oxetanes
R. Larock (1988)
10.1021/JA00228A071
Synthesis of a remarkably stable bicyclo[7.3.1]diynene esperamicin A1/calicheamicin .gamma. system. Structural requirements for facile formation of a 1,4-diyl
P. Magnus (1988)
10.1016/0040-4039(88)85046-9
Efficient synthesis of carbobicyclic and carbopolycyclic compounds via intramolecular carbopalladation catalyzed by palladium-phosphine complexes
E. Negishi (1988)
10.1016/S0040-4039(00)80376-7
Palladium-catalyzed cyclization of alkenyl and aryl halides containing α, β-Unsaturated carbonyl groups via intramolecular carbopalladation
B. O'Connor (1988)
10.1080/00397918808057822
A Short, Highly Stereoselective Palladium and Phase Transfer Catalyzed Synthesis of Pellitorine
Tuy T Jeffery (1988)
10.3987/COM-87-4414
Practical synthesis of unnatural (+)-physostigmine and carbamate analogues
A. Brossi (1988)
10.1021/JO00258A050
Metal-promoted cyclization. 21. Palladium-catalyzed procedures for [3 + 2] annulation via intramolecular alkenylpalladation and arylpalladation
Y. Zhang (1988)
10.1021/JO00252A064
Intramolecular arylations of soft enolates catalyzed by zerovalent palladium
M. Ciufolini (1988)
10.1021/JA00210A071
Synthesis of the bicyclic core of the esperamicin/calichemicin class of antitumor agents
S. Schreiber (1988)
10.1016/S0040-4039(00)80489-X
Palladium catalysed tandem cyclisation-anion capture processes.Hydride ion capture by alkyl- and π-allyl-palladium species
Barry Burns (1988)
10.1021/JA00229A073
A catalytic reductive cyclization of 1,6-diynes
B. Trost (1988)
10.1021/JO00237A002
Synthesis of .beta.-arylvinyl ethers by palladium-catalyzed reaction of aroyl chlorides with vinyl ethers
C. Andersson (1988)
10.1021/JO00253A018
Palladium-catalyzed aroylation of alkyl vinyl ethers. An entry to monoprotected 1-aryl-1,3-dicarbonyl equivalents
C. Andersson (1988)
10.1002/ANIE.198910371
Selective 1:3 Coupling of Norbornene and Iodobenzene: A Facile Synthesis of Benzo[e]pyrenes with Annelated Cycloaliphatic Moieties
O. Reiser (1989)
10.1080/00397918908052721
Utilization of “Bis(Triphenylphosphine)Palladium” as Catalyst in the Cross Coupling Reaction of Terminal Acetylenes with Alkenyl Halides
F. Camps (1989)
10.1016/0022-328X(89)85235-0
Synthesis of substituted cinnamic acids and cinnamonitriles via palladium catalyzed coupling reactions of aryl halides with acrylic acid and acrylonitrile in aqueous media
N. A. Bumagin (1989)
10.1002/ANGE.19891011035
Aktivierung der CCl‐Bindung: Katalytische Carbonylierung von Dichlormethan und Chlorbenzol
M. Huser (1989)
10.1016/S0040-4039(01)80325-7
New palladium mediated cyclopentanation of alkenes bearing a δ nucleophilic substituent
G. Fournet (1989)
10.1016/0040-4020(89)80112-7
Conjugate addition vs. vinylic substitution in palladium-catalysed reaction of aryl halides with β-substituted-α,β-enones and -enals
A. Amorese (1989)
10.1021/CR00097A002
1,2-Additions to heteroatom-substituted olefins by organopalladium reagents
G. Daves (1989)
10.1016/S0040-4039(00)76184-3
Organopalladium approaches to prostaglandins. 10. An efficient synthesis of prostaglandin E2 via vinylpalladation of 4-cyclopentene-1,3-diol
R. Larock (1989)
10.1002/ANIE.198915021
The Effect of Acetylene Substituents on a PdII‐Catalyzed Cycloisomerization. Total Synthesis of (–)‐Sterepolide and Assignment of Absolute Stereochemistry
B. Trost (1989)
10.1016/0040-4020(89)80008-0
Palladium-catalyzed reaction of organic haldids with organotin compounds involving olefin insertion: synthesis of 2,3-di-substituted norbornanes
M. Kosugi, (1989)
10.1016/S0040-4039(00)99273-6
Palladium-catalysed stereoselective hydrovinylation of disubstituted acetylenes: Preparation of functionalized 1,2,4-trisubstituted-1,3-dienes
A. Arcadi (1989)
10.1021/JO00262A014
Benzo[d]naphtho[1,2-b]pyran-6-one C-glycosides: aryltri-n-butylstannanes in palladium-mediated coupling with 2,3-dihydropyran and furanoid glycals
R. A. Outten (1989)
10.1002/ANGE.19891011125
Der Einfluß von Substituenten einer Acetyleneinheit auf eine PdII‐katalysierte Cycloisomerisierung; Totalsynthese von (‐)‐Sterepolid und Bestimmung der absoluten Konfiguration
B. Trost (1989)
10.1021/JO00270A011
Palladium-catalyzed intermolecular vinylation of cyclic alkenes
R. Larock (1989)
10.1016/S0040-4039(00)70636-8
Synthesis of aryl-substituted aldehydes and ketones via palladium-catalyzed coupling of aryl halides and non-allylic unsaturated alcohols
R. Larock (1989)
10.1002/ANIE.198913861
Chlorocarbon Activation: Catalytic Carbonylation of Dichloromethane and Chlorobenzene
M. Huser (1989)
10.1016/S0040-4020(01)81100-5
A new palladium catalyzed synthesis of ,-2,3-diarylsubstituted bicyclo[2.2.1]heptanes or bicyclo [2.2.1] hept-2-enes
M. Catellani (1989)
10.1021/JA00191A037
On the mechanism of the metal-mediated vinylic cross-coupling reactions. II. Reductive elimination: preparation, molecular structure, and thermal chemistry of (.sigma.-alkynyl-.sigma.-vinyl)platinum(II) complexes
P. Stang (1989)
10.1016/S0040-4039(01)80380-4
Regiospecific palladium catalysed tandem cyclisation-anion capture processes. Stereospecific group transfer from organozinc and organoboron reagents
Barry Burns (1989)
10.1016/S0040-4039(01)80273-2
A new palladium catalyst for intramolecular carbametalations of enynes
Barry M. Trost (1989)
10.1016/S0040-4039(00)99147-0
Palladium catalyzed double heck arylation of cyclopentene
M. Prashad (1989)
10.1021/JA00191A066
Metal-promoted cyclization. 25. Palladium-catalyzed cascade carbometalation of alkynes and alkenes as an efficient route to cyclic and polycyclic structures
Y. Zhang (1989)
10.1021/CR00098A001
Synthetic applications of enantioselective organotransition-metal-mediated reactions
S. Blystone (1989)
10.1021/JO00272A006
Metal-promoted cyclization. 26. Palladium-catalyzed cyclization of benzyl halides and related electrophiles containing alkenes and alkynes as a novel route to carbocycles
Guang Zhong Wu (1989)
10.1016/0022-328X(89)85320-3
Palladium-catalyzed preparation of exo-aryl derivatives of the norbornane skeleton
A. Arcadi (1989)
10.1021/JO00281A007
Catalytic asymmetric carbon-carbon bond formation: asymmetric synthesis of cis-decalin derivatives by palladium-catalyzed cyclization of prochiral alkenyl iodides
Y. Sato (1989)
10.1016/S0040-4039(00)99295-5
Palladium-catalyzed synthesis of dienic α-amino acids from allenes
N. Kopola (1989)
10.1021/CR00091A007
Enantioselective homogeneous catalysis involving transition-metal-allyl intermediates
G. Consiglio (1989)
10.1016/0022-328X(89)87132-3
Stabilization of bis(triphenylphosphine)palladium(0) by chloride ions. Electrochemical generation of highly reactive zerovalent palladium complexes
C. Amatore (1989)
10.1016/S0040-4039(00)99420-6
Highly stereoselective synthesis of di- and trisubstituted homoallylic alcohols via palladium(O)-catalyzed nucleophilic opening of vinylic oxetanes
R. Larock (1989)
10.3987/COM-88-S21
Synthesis of benzofurans, tetrahydrobenzopyrans, and related cyclic ethers via cyclic carbopalladation
E. Negishi (1989)
10.1016/0022-328X(89)85347-1
Preparation and reactions of bis(triphenylphosphine)palladium(0)
H. Urata (1989)
10.1016/S0040-4039(01)80381-6
Regiospecific palladium catalysed tandem cyclisation-anion capture processes. Carbon-, nitrogen- and oxygen-centred nucleophiles
R. Grigg (1989)
10.1021/JO00271A006
Hydroxy group as a regio- and stereochemical control element for sequential metal-catalyzed and thermal cyclizations
B. Trost (1989)
10.1016/S0040-4039(00)99075-0
Improved procedures for the palladium-catalyzed intermolecular arylation of cyclic alkenes
R. Larock (1989)
10.1002/CHIN.198921325
Enantioselective Synthesis of Organic Compounds with Optically Active Transition Metal Catalysts in Substoichiometric Quantities
H. Brunner (1989)
10.1016/S0040-4020(01)85124-3
Preparation of 5-bromotetronates [4-alkoxy-5-bromo-2(5H)-furanones] and a new concept for the synthesis of aflatoxins and related structure types. Tributyltin hydride versus palladium-promoted intramolecular hydroarylation.
H. R. Martin (1989)
10.1002/ANGE.19891010906
Cyclisierungsreaktionen über Palladium‐katalysierte allylische Alkylierungen
B. Trost (1989)
10.1007/BF00962156
Synthesis of diaryls from phenylboric acid and aryl iodides in an aqueous medium
N. A. Bumagin (1989)
10.1016/S0040-4039(01)80456-1
Palladium-catalysed coupling of aryl and vinyl triflates or halides with 2-ethynylaniline: An efficient route to functionalized 2-substituted indoles
A. Arcadi (1989)
10.1021/JO00268A006
Palladium-catalyzed vinylation of alkyl vinyl ethers with enol triflates. A convenient synthesis of 2-alkoxy 1,3-dienes
C. Andersson (1989)
10.1016/S0040-4020(01)89159-6
Recent advances in catalytic asymmetric reactions promoted by transition metal complexes
I. Ojima (1989)
10.1021/JO00286A009
Palladium-catalyzed polyene cyclizations of trienyl triflates
N. E. Carpenter (1989)
10.1016/S0040-4039(01)80634-1
Synthesis of the core enediyne structure of esperamicin-calichemicin class of antitumor antibiotics
K. Tomioka (1989)
10.1021/JO00276A023
Convergent and efficient palladium-effected synthesis of 5, 10-dideaza-5,6,7,8-tetrahydrofolic acid (DDATHF)
E. Taylor (1989)
10.1021/IC00306A034
Oxidative addition of phenols to bis(tricyclohexylphosphine)palladium. Synthesis and structural characterization of trans-[Pd(PCy3)2(H)(OC6H5)].C6H5OH (1) and trans-[Pd(PCy3)2(H)(OC6F5)].C6F5OH (2)
C. D. Bugno (1989)
10.1021/JO00278A029
Palladium-catalyzed reactions in the synthesis of 3- and 4-substituted indoles. 4
L. Hegedus (1989)
10.1002/ANIE.198911731
Cyclizations via Palladium-Catalyzed Allylic Alkylations [New Synthetic Methods (79)]
B. Trost (1989)
10.1021/JA00191A036
The mechanism of the metal mediated vinylic cross-coupling reactions. 1. Oxidative addition: the reaction of vinyl triflates with zerovalent platinum. Kinetics, stereochemistry and molecular structure
P. Stang (1989)
10.1016/S0040-4020(01)81034-6
The synthesis of spirocyclic compounds by regiospecific palladium catalysed cyclisation reactions
R. Grigg (1989)
10.1016/S0040-4039(01)89016-X
Palladium- and platinum-catalyzed reaction of siloxycyclopropanes with acid chlorides. A homoenolate route to 1,4-dicarbonyl compounds
S. Aoki (1989)
10.1021/JO00278A018
Studies of vitamin D (calciferol) and its analogs. 35. Synthesis and biological activity of 9,11-dehydrovitamin D3 analogs: stereoselective preparation of 6.beta.-vitamin D vinylallenes and a concise enynol synthesis for preparing the A-ring
W. Okamura (1989)
10.1080/00397919008051600
A Facile Approach to 2-Arylethylamines Via Polymeric Palladium Catalyst
Zhang Zhuangyu (1990)
10.1016/S0040-4020(01)87897-2
ß-aryl and ß-vinyl-αß-didehydro-α-aminoacid derivatives through the palladium-catalysed reaction of aryl and vinyl triflates with methyl α-acetamidoacrylate
A. Arcadi (1990)
10.1021/JO00289A002
Palladium-catalyzed synthesis of trans-2,5-diaryltetrahydrofurans, potent platelet-activating factor antagonists
R. Larock (1990)
10.1021/JO00298A050
Ligand-controlled .alpha.-regioselectivity in palladium-catalyzed arylation of butyl vinyl ether
W. Cabri (1990)
10.1021/AR00174A006
C-glycoside synthesis by palladium-mediated glycal-aglycon coupling reactions
Jr. G. Doyle Daves (1990)
10.1016/0022-328X(90)85036-X
Conformational effects in elementary steps in catalytic reactions. Oxidative addition of 3-bromoprop-1-ene to a palladium(II) metallacyclic complex
M. Catellani (1990)
10.1016/S0040-4039(00)98060-2
Palladium-catalyzed tandem assembly of norbornene, vinylic halides, and cyanide nucleophile leading to cis-exo-2,3-disubstituted norbornanes
S. Torii (1990)
10.1021/JA00179A058
ONE-STEP CONSTRUCTION OF FUSED TRICYCLIC AND TETRACYCLIC STRUCTURES FROM ACYCLIC PRECURSORS VIA CYCLIC CARBOPALLADATION
Y. Zhang (1990)
10.1021/AR00170A004
Palladium-catalyzed cycloisomerizations of enynes and related reactions
B. Trost (1990)
10.1016/S0040-4039(00)89029-2
Asymmetric induction in the creation of tri- and tetra-substituted carbon stereocentres by the intramolecular heck reaction
R. Grigg (1990)
10.1021/JO00309A020
Chelation-controlled, palladium-catalyzed vinylic substitution reactions of vinyl ethers. 2-Arylethanal equivalents from aryl halides
C. Andersson (1990)
Cycloaddition reactions in organic synthesis
W. Carruthers (1990)
10.1126/science.248.4960.1194
Chiral Metal Complexes as Discriminating Molecular Catalysts
R. Noyori (1990)
10.1021/OM00158A026
Mechanism of oxidative addition of palladium(0) with aromatic iodides in toluene, monitored at ultramicroelectrodes
C. Amatore (1990)
Dienes in the Diels-Alder reaction
F. Fringuelli (1990)
10.1021/AR00178A005
BINAP: an efficient chiral element for asymmetric catalysis
R. Noyori (1990)
10.1021/JO00303A017
Stereoselective cyclization of (2-bromophenyl)- and (2-iodophenyl)alkynes catalyzed by palladium(O) complexes
R. Wang (1990)
10.1016/S0040-4039(00)88802-4
Palladium-catalysed polycyclisation-anion capture processes
R. Grigg (1990)
10.1021/JO00298A011
Palladium-catalyzed heteroannulation of 1,3-dienes by functionally substituted aryl halides
R. Larock (1990)
10.1021/JO00288A013
Palladium-catalyzed alkenylation and alkynylation of polyhaloarenes
W. Tao (1990)
10.1021/JO00304A013
Vinylphosphonium salts: stereoselective palladium-catalyzed vinylation of triphenylphosphine with vinyl triflates
R. Hinkle (1990)
10.1016/S0040-4039(00)94503-9
Palladium-catalyzed synthesis of flavones and chromones via carbonylative coupling of o-Iodophenols with terminal acetylenes
V. Kalinin (1990)
10.1021/JA00171A040
Palladium-catalyzed carboannulation of 1,3-dienes by aryl halides
R. Larock (1990)
10.1021/JA00175A033
Construction of quaternary carbon centers by palladium-catalyzed intramolecular alkene insertions. Total synthesis of the Amaryllidaceae alkaloids (.+-.)-tazettine and (.+-.)-6a-epipretazettine
M. M. Abelman (1990)
10.1016/S0040-4039(00)88842-5
A novel single pot reaction for substitution and cross-coupling of vinylacetate to trans-stilbenes by interlamellar montmorillonite palladium catalyst
B. M. Choudary (1990)
10.1016/S0040-4039(00)97135-1
Palladium-catalysed reaction of vinylic halides with primary allylic alcohols : regio and stereocontrolled synthesis of 4-enals.
T. Jeffery (1990)
10.1021/JO00298A014
A new five-membered ring annulation method based on palladium(0)-catalyzed intramolecular coupling of vinyl iodide and enolate anion functions
E. Piers (1990)
10.1016/S0040-4039(00)97630-5
Effects of organometals on the palladium-catalyzed tandem carbopalladation-cross coupling for preparing stereodefined exocyclic alkenes
E. Negishi (1990)
10.1002/9783527621385
Organic Synthesis Highlights
J. Mulzer (1990)
10.1021/OM00116A010
Mapping the reaction pathway in palladium-catalyzed cross-coupling reactions
J. Brown (1990)
10.1007/BF00958884
Palladium-catalyzed phenylation and vinylation of aryl halides in aqueous media
N. A. Bumagin (1990)
10.1016/0022-328X(90)80248-X
A new palladium-catalyzed synthesis of indoxyl derivatives
Z. An (1990)
10.1021/JO00295A041
Regioselective palladium-catalyzed tandem .alpha.-arylation/isomerization of cyclic enamides
K. Nilsson (1990)
10.1016/S0040-4039(00)97120-X
The effect of thallium (I) salts on palladium catalysed tandem cyclisation-anion capture processes.
R. Grigg (1990)
10.1016/S0040-4039(00)97827-4
Stereospecific synthesis of arylidene and allylidene cyclopentanes by a palladium-catalyzed cylisation
G. Fournet (1990)
10.1016/0022-328X(90)80183-Z
An interesting chloride ion effect in the Heck reaction
C. Merlic (1990)
10.1021/OM00162A029
C-glycoside synthesis by palladium-catalyzed iodoaglycon-glycal coupling
Roger N. Farr (1990)
10.1016/S0040-4039(00)97958-9
A novel molecular recognition in montmorillonite in the arylation of acrylates
B. M. Choudary (1990)
10.1021/JA00167A032
Palladium-catalyzed alkylations in aqueous media
A. Casalnuovo (1990)
10.1016/S0040-4039(00)97390-8
An efficient route for the stereoselective conversion of ketones into three-carbons homologated primary E-allylamines : the palladium-catalysed reaction of vinyl triflates with N,N-di-tert-butoxycarbonyl-N-allylamine
A. Arcadi (1990)
10.1021/JA00169A025
Multistep electron transfer in palladium-catalyzed aerobic oxidations via a metal macrocycle-quinone system
Jan-E. Baeckvall (1990)
10.1021/JA00174A021
Synthesis and subsequent rearrangement of chloro(pentafluorophenyl)-1,5-cyclooctadienepalladium(II), an illustrative example of endo attack on a coordinated double bond
A. Albéniz (1990)
10.1021/JA00178A065
Convergent synthesis of vineomycinone B2 methyl ester
M. A. Tius (1990)
10.1016/S0040-4039(00)79396-8
Alkylpalladium(II) species. Reactive intermediates in a bis-cyclisation route to strained polyfused ring systems.
R. Grigg (1991)
10.1016/S0040-4039(00)74377-2
Palladium catalysed tandem cyclisation-anion capture processes initiated by alkyl- and π-allyl-palladium species
R. Grigg (1991)
10.1021/JO00008A043
Synthesis of 1,4-keto esters and 1,4-diketones via palladium-catalyzed acylation of siloxycyclopropanes. Synthetic and mechanistic studies
T. Fujimura (1991)
10.1016/0040-4039(91)80766-Y
Intramolecular Heck reaction with substrates possessing an allylic alcohol moiety
J. Gaudin (1991)
10.1021/JA00002A043
ACTIVATION IN TRANSITION-METAL CATALYSIS BY CATALYST RELAY. A SYNTHETIC APPROACH TO (-)-DENDROBINE
B. Trost (1991)
10.1016/S0040-4039(00)78898-8
Palladium(0)-Catalyzed Substitution of Allylic Substrates in a Two-Phase Aqueous-Organic Medium
M. Safi (1991)
10.1021/JO00011A049
Palladium-mediated coupling of a 3-deoxy pyranoid glycal: stereochemistry of C-glycosyl bond formation
Daw Long Kwok (1991)
10.1016/S0040-4039(00)74321-8
Palladium-catalyzed α-arylation of vinyl butyl ether with aryl halides
W. Cabri (1991)
10.1016/0040-4039(91)80215-R
Synthesis of ethynylidene cyclopentanes by a cyclisation catalyzed by the simultaneous presence of palladium (0) and copper (I)
D. Bouyssi (1991)
10.1016/S0040-4039(00)79919-9
Control of stereoselectivity in samarium metal induced cyclopropanations. Synthesis of 1,25-dihydroxycholecalciferol
M. Kabat (1991)
10.1016/S0040-4039(00)93501-9
Stereoselective synthesis of 1α-hydroxyvitamin D3 A-ring synthons by palladium-catalyzed cyclization
K. Nagasawa (1991)
10.1021/JO00023A023
Preparation of N-substituted phthalimides by the palladium-catalyzed carbonylation and coupling of o-dihalo aromatics and primary amines
R. Perry (1991)
10.1021/JO00008A007
Regioselective, palladium-catalyzed hetero- and carboannulation of 1,2-dienes using functionally substituted aryl halides
R. Larock (1991)
10.1021/JA00020A083
Organopalladium approaches to prostaglandins. 11. Synthesis of PGF2.alpha. and 12-epi PGF2.alpha. by the controlled, one step, palladium-promoted, intermolecular coupling of three different alkenes
R. C. LaRock (1991)
10.1016/S0040-4039(00)74860-X
Suppression of alkene isomerisation in products from intramolecular heck reactions by addition of Tl(1) salts.
R. Grigg (1991)
10.1016/0022-328X(91)86321-G
Changing selectivity in palladiu-catalyzed reactioins involving oxidation state IV. A new synthesis from iodobenzene and norbornene
M. Catellani (1991)
10.1016/S0040-4039(00)92354-2
An approach to the A ring of neocarzinostatin chromophore via sequential carbometalation/anion capture
J. M. Nuss (1991)
10.1016/S0040-4039(00)74294-8
Cyclisation of ω-unsaturated β-dicarbonylcompounds catalyzed by a palladium hydride species
N. Monteiro (1991)
10.1126/SCIENCE.1962206
The atom economy--a search for synthetic efficiency.
B. Trost (1991)
10.1021/JO00001A049
Palladium-catalyzed coupling reactions of aryl triflates or halides with ketene trimethylsilyl acetals. A new route to alkyl 2-arylalkanoates
C. Carfagna (1991)
10.1021/JA00005A034
RATES AND MECHANISM OF THE REVERSIBLE OXIDATIVE ADDITION OF (Z)- AND (E)-1,2-DICHLOROETHYLENE TO LOW-LIGATED ZEROVALENT PALLADIUM
C. Amatore (1991)
10.1016/S0040-4039(00)74829-5
Palladium-catalyzed synthesis of quinolines from allylic alcohols and o-iodoaniline
R. Larock (1991)
10.1016/0040-4039(91)80864-3
Palladium-catalyzed carbonylation to form 2-substituted 1,4-dihydro-4-oxo-quinoline
S. Torii (1991)
10.1021/JO00023A003
Palladium-catalyzed polycyclization of dienynes: surprisingly facile formation of tetracyclic systems containing a three-membered ring
F. E. Meyer (1991)
10.1016/S0040-4039(00)74277-8
Palladium-catalyzed β-vinylation of vinyl acetate with enol triflates. An entry to 1-acetoxy-1,3-dienes
P. G. Ciattini (1991)
10.1016/S0040-4039(00)74293-6
Palladium-mediated cyclopentanation of alkenes bearing a nucleophilic substituent. Stereochemistry and mechanism.
D. Bouyssi (1991)
10.1021/JA00016A083
Palladium-catalyzed coupling of alkenyl iodonium salts with olefins : a mild and stereoselective heck-type reaction using hypervalent iodine
R. Moriarty (1991)
10.1016/0040-4039(91)80486-P
Acenaphth[1,2-a]acenaphthylene: a semi-benzenoid hydrocarbon with dienophilic central double bond
G. Dyker (1991)
10.1016/S0040-4039(00)79397-X
Palladium catalysed intramolecular coupling of aryl and benzylic halides and related tandem cyclisations. A simple synthesis of hippadine.
R. Grigg (1991)
10.1021/JA00022A026
Role and effects of halide ions on the rates and mechanisms of oxidative addition of iodobenzene to low-ligated zerovalent palladium complexes Pd0(PPh3)2
C. Amatore (1991)
10.1016/0022-328X(91)80026-G
Palladium-catalyzed reactions of vinyl bromides with disubstituted alkynes: a new synthesis of fulvenes
L. J. Silverberg (1991)
10.1021/JO00020A023
Palladium-catalyzed intramolecular addition of amines to acetylenes. Synthesis of cyclic imines
Y. Fukuda (1991)
10.1016/S0040-4039(00)74306-1
A general solution to the synthesis of 2-azabicyclo[3.3.1]nonane unit of Strychnos alkaloids
V. Rawal (1991)
10.1016/S0040-4039(00)92695-9
Palladium catalyzed synthesis of annelated indoles
A. Kozikowski (1991)
10.1021/JA00002A064
A palladium-catalyzed zipper reaction
B. Trost (1991)
10.1016/S0040-4020(01)86427-9
β-Vinyl-γ-butyrolactones via the palladium-catalysed reaction of vinyl triflates with Z-2-buten-1,4-diol
A. Arcadi (1991)
10.1021/JA00015A035
C-glycosylanthraquinone synthesis : total synthesis of vineomycinone B2 methyl ester
M. A. Tius (1991)
10.1016/S0040-4039(00)79424-X
Synthesis of carbacyclins via palladium-promoted, tandem alkene insertion
R. Larock (1991)
10.1016/S0040-4020(01)91034-8
The synthesis of bridged-ring carbo- and hetero-cycles via palladium catalysed regiospecific cyclisation reactions ☆
R. Grigg (1991)
10.1021/JO00013A004
Asymmetric Heck reaction: a catalytic asymmetric synthesis of the key intermediate for .DELTA.9(12)-capnellene-3.beta.,8.beta.,10.alpha.-triol and .DELTA.9(12)-capnellene-3.beta.,8.beta.,10.alpha.,14-tetrol
K. Kagechika (1991)
10.1021/JA00017A059
Synthesis of indoles via palladium-catalyzed heteroannulation of internal alkynes
R. Larock (1991)
10.1016/S0040-4039(00)79893-5
Palladium-catalyzed tandem bond forming reaction leading to aromatic ring through diene-yne system
S. Torii (1991)
10.1016/S0040-4039(00)92119-1
Use of the carbopalladation of 1,2-propadiene in a two step synthesis of steroids
V. Gauthier (1991)
10.1016/0040-4039(91)80030-A
Stereoselective total synthesis of (+)-lycoricidine
N. Chida (1991)
10.1016/S0040-4020(01)86561-3
Synthese de (e)-arylidene et allylidene cyclopentanes par une annelation catalysee par un complexe de palladium(0)
G. Fournet (1991)
10.1021/JO00022A002
Efficient free-radical and palladium-catalyzed tandem alkene insertions: a new approach to benzoprostacyclins
R. Larock (1991)
10.1021/JA00004A056
Catalytic asymmetric arylation of 2,3-dihydrofuran with aryl triflates
F. Ozawa (1991)
10.1016/S0040-4039(00)71252-4
Palladium-catalysed arylation of allylic alcohols: Highly selective synthesis of β-aromatic carbonyl compounds or β-aromatic α,β-unsaturated alcohols.
T. Jeffery (1991)
10.1016/0040-4039(91)80579-U
Palladium catalyzed synthesis of a chromenes and chromenols
Xavier Garcías (1991)
10.1021/JO00043A016
Palladium-mediated arylation of acetylated enones derived from glycals. 4. Synthesis of aryl-2-deoxy-.beta.-D-C-glycopyranosides
R. Benhaddou (1992)
10.1016/S0040-4039(00)92252-4
A catalytic asymmetric synthesis of hydrindans
Y. Sato (1992)
10.1016/S0040-4020(01)88131-X
A highly active and stereoselective montmorillonite catalyst for arylation of conjugated alkenes
B. M. Choudary (1992)
10.1021/JO00036A025
Synthesis of 2-arylbenzoxazoles via the palladium-catalyzed carbonylation and condensation of aromatic halides and o-aminophenols
R. Perry (1992)
10.1016/S0040-4039(00)61791-4
The palladium-catalyzed arylation of 4H-1,3-dioxin
T. Sakamoto (1992)
10.1016/S0040-4020(01)88492-1
Palladium-catalyzed heck couplings of L-vinylglycine derivatives with vinyl and aryl halides and triflates.
G. Crisp (1992)
10.1016/S0040-4039(00)91703-9
A palladium-catalyzed intramolecular arene-triflate coupling for the synthesis of fluoranthenes and benzofluoranthenes
J. E. Rice (1992)
10.1016/S0040-4039(00)92674-1
Asymmetric multipoint control by palladium-catalyzed diastereoselective tandem carbon-carbon bond formation
S. Torii (1992)
10.1002/CBER.19921250143
Regiocontrol in Pd(0)-mediated couplings of a bis(enol triflate) with alkynes : stereoselective syntheses of monocyclic dienediynes related to the neocarzinostatin chromophore
S. W. Scheuplein (1992)
10.1021/JA00030A060
Oxidative addition of palladium(0) to the anomeric center of carbohydrate electrophiles
G. S. Jones (1992)
10.1016/S0040-4039(00)61307-2
A total asymmetric synthesis of the isolactarane sesquiterpene (−)-merulidial
B. Trost (1992)
10.1021/JA00050A079
A short synthesis of (+)-Lycoricidine
T. Hudlicky (1992)
10.1351/pac199264030323
Zipper-mode cascade carbometallation for construction of polycyclic structures
E. Negishi (1992)
10.1016/S0040-4039(00)77687-8
New practical synthesis of spirocyclopentenones
F. Camps (1992)
10.1021/JO00035A006
A palladium-mediated approach to construction of nitrogen heterocycles
G. Harris (1992)
10.1016/S0040-4039(00)79603-1
Palladium-catalysed vinylation of allylic alcohols with enol triflates. A convenient synthesis of conjugated dienols
E. Bernocchi (1992)
10.1021/JA00051A069
Apparent endo-mode cyclic carbopalladation with inversion of alkene configuration via exo-mode cyclization-cyclopropanation rearrangement
Z. Owczarczyk (1992)
10.1016/S0040-4020(01)92256-2
Influence of functional substitution of allyl halides on their ni(co)4 promoted carbonylative cycloaddition with acetylenes
F. Camps (1992)
10.1016/S0040-4039(00)61788-4
Intramolecular aminopalladation and cross coupling of acetylenic amines
Fen-Tair Luo (1992)
10.1002/ANIE.199210231
Palladium‐Catalyzed C ? H Activation of Methoxy Groups: A Facile Synthesis of Substituted 6H‐Dibenzo[b,d]pyrans
G. Dyker (1992)
10.1002/ANGE.19921040830
Palladium-katalysierte CH-Aktivierung von Methoxygruppen: einfache Synthese substituierter 6H-Dibenzo[b,d]pyrane†
G. Dyker (1992)
10.1016/0022-328X(92)83236-B
Catalytic asymmetric arylation of N-substituted 2-pyrrolines with aryl triflates
F. Ozawa (1992)
10.1021/OM00042A008
Palladium-catalyzed vinylation of aryl chlorides. Chelate effect in catalysis
Y. Ben-David (1992)
10.5059/YUKIGOSEIKYOKAISHI.50.826
Catalytic Asymmetric Synthesis of Polycylic Compounds by Asymmetric Heck Reaction.
M. Shibasaki (1992)
10.1016/0040-4039(93)88047-M
Palladium catalysed cascade cyclisation - carbonylation processes. Rate enhancement by Tl(I) salts.
R. Grigg (1992)
10.1016/S0040-4039(00)74711-3
Palladium-catalyzed polycyclizations of substituted dienynes: Stereoselective routes to highly complex polycycles
F. E. Meyer (1992)
10.5860/choice.30-3282
Tandem Organic Reactions
T. Ho (1992)
10.1021/JO00031A029
.alpha.-Regioselectivity in palladium-catalyzed arylation of acyclic enol ethers
W. Cabri (1992)
10.1016/0022-328X(92)85082-8
Palladium-catalyzed norbornene-carbon monoxide co-oligomerization initiated by aryl groups and terminated by double bond formation
E. Dalcanale (1992)
10.1016/S0957-4166(00)82091-1
Selectivity in palladium catalysed allylic substitution
C. Frost (1992)
10.1016/S0040-4020(01)89040-2
Formation de derives cyclopentaniques assistee par une espece hydrure de palladium : aspects synthetiques et mecanisme
N. Monteiro (1992)
10.1021/AR00014A005
Development of organopalladium(IV) chemistry: fundamental aspects and systems for studies of mechanism in organometallic chemistry and catalysis
A. Canty (1992)
10.1016/S0040-4020(01)90372-2
Palladium-catalysed intramolecular cyclisation of 7-halo-N-allyl-indoles
D. Black (1992)
10.1016/S0040-4039(00)92673-X
Asymmetric multipoint control by diastereo-differentiative assembly of three components with palladium catalyst
S. Torri (1992)
10.1016/S0040-4039(00)74261-4
A short, efficient route to 1-hydroxylated vitamin D ring A fragments
J. L. Mascareñas (1992)
10.1351/pac199264121813
Palladium-catalyzed, polyene cyclizations
L. E. Overman (1992)
10.1021/JA00031A039
Enantiomerically pure dihydropyrimidinones as reagents and auxiliaries for asymmetric synthesis
K. Chu (1992)
10.1016/S0040-4039(00)60208-3
A new palladium-catalyzed synthesis of 3-substituted 2-aryliden-2,3-dihydro-1H-inden-1-ones
E. Brocato (1992)
10.1016/S0040-4039(00)78865-4
Easy access to 5-(E)-alkynylidene tetrahydro-2 furanones by a palladium catalyzed process
D. Bouyssi (1992)
10.1016/S0040-4039(00)91654-X
Palladium-catalyzed asymmetric arylation of 2,3-dihydrofuran: 1,8-Bis(dimethylamino)naphthalene as an efficient base
F. Ozawa (1992)
10.1021/JA00053A049
A 10-step, asymmetric synthesis of (S)-camptothecin
D. L. Comins (1992)
10.1021/JO00039A011
Palladium-catalyzed arylation of unsymmetrical olefins. Bidentate phosphine ligand controlled regioselectivity
W. Cabri (1992)
10.1016/S0040-4039(00)74824-6
Palladium-catalysed hydroxycarbonylation of vinyl and aryl triflates: synthesis of α,β-unsaturated and aromatic carboxylic acids
S. Cacchi (1992)
10.1016/S0040-4039(00)74818-0
A versatile approach to 2,3-disubstituted indoles through the palladium-catalysed cyclization of o-alkynyltrifluoroacetanilides with vinyl triflates and aryl halides
Arcadi Antonio (1992)
10.1021/JA00028A074
Cycloisomerization for atom economy. Polycycle construction via tandem transition metal catalyzed electrocyclic processes
B. Trost (1992)
10.1351/pac199264030421
Catalytic asymmetric arylation of olefins
T. Hayashi (1992)
10.1021/JA00051A016
New strategies for the synthesis of vitamin D metabolites via palladium-catalyzed reactions
B. Trost (1992)
10.1016/S0040-4039(00)61217-0
Controlling stereoselection in intramolecular heck reactions by tailoring the palladium catalyst
A. Madin (1992)
10.1021/JO00043A005
Catalytic asymmetric synthesis of quarternary carbon centers. Palladium-catalyzed formation of either enantiomer of spirooxindoles and related spirocyclics using a single enantiomer of a chiral diphosphine ligand
A. Ashimori (1992)
10.1016/S0040-4039(00)77686-6
Fused bicyclic systems through a ni-mediated intermolecular cyclopentenone annulation
F. Camps (1992)
10.1016/S0040-4039(00)92060-4
Cyclic cascade carbopalladation reactions as a route to benzene and fulvene derivatives
E. Negishi (1992)
10.1016/S0040-4020(01)88469-6
Formation de cyclopentanes a partir de malonates δ-ethyleniques par un processus catalytique en palladium(O) stereochimie et mecanisme
G. Balme (1992)
10.1016/S0040-4039(00)92251-2
Further studies on a catalytic asymmetric synthesis of decalin derivatives
Y. Sato (1992)
10.1021/JA00052A047
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