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Übergangsmetallkatalysierte C‐C‐Kupplungen Mit Ethylen Im Labormaßstab

Vaneet Saini, B. Stokes, M. Sigman
Published 2013 ·

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Ethylen ist das (volumenbezogen) in groster Menge synthetisierte organische Molekul. Es lasst sich leicht in ubergangsmetallkatalysierte C-C-Kupplungsreaktionen einbinden, und zwar durch migratorische Insertion in Alkylmetall-Intermediate. Wegen der D2h-Symmetrie des Ethylens kann die Insertion nur einen einzigen Verlauf nehmen, was die Nebenproduktbildung limitiert und die Produktanalyse auserordentlich vereinfacht. Wie in diesem Kurzaufsatz beschrieben wird, wird bei vielen C-C-Kupplungen das Ethylenmolekul (oder mehrere) bei Umgebungsdruck und -temperatur eingefugt. Auch sind viele Reaktionen bekannt, bei denen ein in geeigneter Weise substituiertes Alken in das Produkt eingefuhrt wird.
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