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Morphology, Structure, And Conductivity Of Polypyrrole Prepared In The Presence Of Mixed Surfactants In Aqueous Solutions

Shuangxi Xing, G. Zhao
Published 2007 · Chemistry

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Polypyrrole (PPy) was prepared from different mixed-surfactant solutions with ammonium persulfate as an oxidant. Three types of combinations were selected, including cationic/anionic, cationic/nonionic, and anionic/nonionic mixed-surfactant solutions. The surfactants used in the experiments included cetyltrimethylammonium bromide (cationic surfactant), sodium dodecyl sulfate (anionic surfactant), sodium dodecyl sulfonic acid salt (anionic surfactant), poly(vinyl pyrrolidone) (nonionic surfactant), and poly(ethylene glycol) (nonionic surfactant). The morphology, structure, and conductivity of the resulting PPy were investigated in detail with scanning electron microscopy, Fourier transform infrared spectra, and the typical four-probe method, respectively. The results showed that the interaction between the different surfactants and the interaction between the surfactants and the polymer influenced the morphology, structure, and conductivity of the resulting polymer to different degrees. The cationic surfactant favored the formation of nanofibers, the addition of anionic surfactants produced agglomeration but enhanced the doping level and conductivity, and the presence of a nonionic surfactant weakened the interaction between the other surfactant and the polymer in the system. In comparison with the results for monosurfactant solutions, the polymerization of pyrrole in mixed-surfactant solutions could modulate the morphologies of PPy, which ranged from nanofibers of different lengths to nanoparticles showing various states of aggregation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1987–1996, 2007
This paper references
10.1021/JA0365983
Adsorbed surfactants as templates for the synthesis of morphologically controlled polyaniline and polypyrrole nanostructures on flat surfaces: from spheres to wires to flat films.
A. D. Carswell (2003)
10.1002/APP.1359
Structural, mechanical, and electrical properties of electropolymerized polypyrrole composite films
N. Bhat (2001)
10.1002/CPHC.200301217
Surfactant-directed polypyrrole/CNT nanocables: synthesis, characterization, and enhanced electrical properties.
X. Zhang (2004)
10.1021/MA051299E
Chemical Synthesis of Highly Conducting Polypyrrole Nanofiber Film
Aimei Wu (2005)
10.1016/J.POLYMER.2006.01.081
Polypyrrole micro- and nanowires synthesized by electrochemical polymerization of pyrrole in the aqueous solutions of pyrenesulfonic acid
G. Lu (2006)
10.1002/ADMA.200501621
Polypyrrole Nanowire Actuators
Y. Berdichevsky (2006)
10.1016/S0379-6779(00)00268-X
A novel conducting soluble polypyrrole composite with a polymeric co-dopant
Y. Lee (2000)
10.1016/J.ELECTACTA.2004.01.085
Nucleation, non-stoiquiometry and sensing muscles from conducting polymers
T. Otero (2004)
10.1016/J.SYNTHMET.2006.01.005
Structure–conductivity relationships in chemical polypyrroles of low, medium and high conductivity
P. Carrasco (2006)
10.1103/PHYSREVB.39.5872
Conductivity as a function of conjugation length: Theory and experiment for conducting polymer complexes.
Baughman (1989)
10.1021/JP054335K
Controllable synthesis of conducting polypyrrole nanostructures.
X. Zhang (2006)
10.1002/(SICI)1521-4095(199908)11:11<953::AID-ADMA953>3.0.CO;2-H
Surprising Volume Change in PPy(DBS): An Atomic Force Microscopy Study
E. Smela (1999)
10.1016/S0379-6779(02)00498-8
Synthesis and structural study of polypyrroles prepared in the presence of surfactants
M. Omastová (2003)
10.1016/J.EURPOLYMJ.2005.05.029
Solid phase photopolymerization of pyrrole in poly(vinylchloride) matrix
A. W. Rinaldi (2005)
10.1016/S1567-1739(02)00217-1
Prospects of conducting polymers in molecular electronics
V. Saxena (2003)
10.1016/J.SYNTHMET.2003.12.013
Synthesis and characterization of water soluble polypyrrole doped with functional dopants
Kwan Sik Jang (2004)
10.1002/CHEM.200305211
Nanostructured polyaniline sensors.
J. Huang (2004)
10.1039/A809874C
A study of polypyrrole/poly(N-isopropylacrylamide-co-acrylamide) dispersions : Electrically conducting polymer dispersions stabilised by copolymers with lower critical solution temperatures
B. Saunders (1999)
10.1002/ADMA.200501756
Low-Temperature Synthesis of Star-Shaped PbS Nanocrystals in Aqueous Solutions of Mixed Cationic/Anionic Surfactants†
Nana Zhao (2006)
10.1002/1521-3773(20010716)40:14<2581::AID-ANIE2581>3.0.CO;2-2
"Synthetic Metals": A Novel Role for Organic Polymers (Nobel Lecture).
A. MacDiarmid (2001)



This paper is referenced by
10.15376/BIORES.5.4.2348-2361
Polypyrrole synthesis via carboxymethylcellulose-iron complexes.
C. Sasso (2010)
10.1016/J.ELECTACTA.2016.06.080
Investigation of pharmaceutically active ionic liquids as electrolyte for the electrosynthesis of polypyrrole and active component in controlled drug delivery
S. Carquigny (2016)
10.1016/J.JELECHEM.2012.01.023
Electropolymerization of pyrrole: Dendrimers, nano-sized patterns and oscillations in potential in presence of aromatic and aliphatic surfactants
Ishwar Das (2012)
10.1007/s10965-018-1500-z
In situ chemical deposition of PPy/NDSA and PPy/DBSA layers on QCM electrodes: synthesis, structural, morphological and ammonia sensing performances study
B. Mettai (2018)
10.1002/anie.201601476
Fast Quantitation of Target Analytes in Small Volumes of Complex Samples by Matrix-Compatible Solid-Phase Microextraction Devices.
Hamed Piri-Moghadam (2016)
10.1007/s10570-013-9945-z
Microstructure, distribution and properties of conductive polypyrrole/cellulose fiber composites
Haihua Wang (2013)
10.1002/PAT.1417
Synthesis and characterization of polypyrrole nanofibers with different dopants
Shubhra Goel (2010)
10.1016/j.matpr.2020.02.023
Galvanostatically Deposited Polypyrrole Thin Films for Supercapacitor Application: Effect of Surfactant
Vishal K. Pandit (2020)
10.1002/PAT.1516
Synthesis and characterization of poly (indene‐co‐pyrrole) nanofibers
Shubhra Goel (2010)
10.1039/C8NJ00936H
3D structured polypyrrole/reduced graphene oxide (PPy/rGO)-based electrode ionic soft actuators with improved actuation performance
H. Rasouli (2018)
10.1246/CL.2007.1210
Surface Grafting of Polypyrrole onto Silicon Wafers
D. Sohn (2007)
10.1039/d0ra05199c
Highly flexible reduced graphene oxide@polypyrrole-polyethylene glycol foam for supercapacitors
Chaoyue Cai (2020)
10.1039/d0nr02950e
Polaron and bipolaron induced charge carrier transportation for enhanced photocatalytic H2 production.
T. R. Naveen Kumar (2020)
10.1016/J.SNB.2015.10.032
Simultaneous electrochemical determination of ascorbic acid and uric acid using poly(glyoxal-bis(2-hydroxyanil)) modified glassy carbon electrode
E. Ergün (2016)
10.15376/BIORES.6.3.3585-3620
POLYPYRROLE AND POLYPYRROLE/WOOD-DERIVED MATERIALS CONDUCTING COMPOSITES: A REVIEW
D. Beneventi (2011)
10.1007/s42452-020-2338-7
Influence of clay modification process in polypyrrole-layered silicate nanocomposite
L. Mrah (2020)
The physical properties of the conductive polymers depend on the type of dopants and doping levels. Dendrimer and hyperbranched conductive polymers
(2018)
10.1016/J.MATCHEMPHYS.2015.06.022
Investigation of corrosion protection performance of poly(N-methylpyrrole)-dodecylsulfate/multi-walled carbon nanotubes composite coatings on the stainless steel
Bülent Zeybek (2015)
10.1007/s12221-015-5456-x
Photocatalytic activity of ZnO composites against rhodamine B and rhodamine 6G
Keyte N S Nascimento (2015)
10.1002/APP.39467
Impact of p‐toluenesulfonate on polypyrrole–cobalt catalyst for oxygen reduction reaction
A. Kumar (2013)
10.1016/j.colsurfa.2020.124877
Synergistic effect of Zr/Cl dual-ions mediated pyrrole polymerization and development of superhydrophobic melamine sponges for oil/water separation
Love Dashairya (2020)
Development of a Novel Drug Delivery System Based on Conducting Polymers
D. Svirskis (2010)
10.1016/J.ELECTACTA.2011.08.003
Electrochemical synthesis of bilayer coatings of poly(N-methylaniline) and polypyrrole on mild steel and their corrosion protection performances
Bülent Zeybek (2011)
10.1039/C4CE01551G
Manipulation on ZnO heterostructures: from binary ZnO–Ag to ternary ZnO–Ag–polypyrrole
J. Li (2014)
10.1007/978-3-319-95378-6_1
Introduction and Literature Review
A. Mirabedini (2018)
10.1016/J.JPHOTOCHEM.2015.04.013
Synthesis and characterization of branched polypyrrole/titanium dioxide photocatalysts
Ericleiton R. Macedo (2015)
10.1016/J.PORGCOAT.2014.03.026
The electrochemical copolymerization of pyrrole and bithiophene on stainless steel in the presence of SDS in aqueous medium and its anticorrosive performance
Nuran Özçiçek Pekmez (2014)
10.1007/S11998-009-9186-0
A structural and morphological comparative study between chemically synthesized and photopolymerized poly(pyrrole)
Subramanyam V. Kasisomayajula (2010)
10.1002/MAME.201000148
Highly Conducting Polypyrrole/Cellulose Nanocomposite Films with Enhanced Mechanical Properties
C. Sasso (2010)
10.1016/J.PORGCOAT.2014.12.011
Electrodeposition of poly(N-methylpyrrole) on stainless steel in the presence of sodium dodecylsulfate and its corrosion performance
Bülent Zeybek (2015)
10.1002/APP.42729
Controlled electrochemical synthesis of conductive nanopolypyrrole and its application in the design of a solid‐state ion sensor
Ishwar Das (2015)
10.1007/S10854-010-0102-2
Chemical synthesis and low temperature electrical transport in polypyrrole doped with sodium bis(2-ethylhexyl) sulfosuccinate
M. Taunk (2011)
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