Online citations, reference lists, and bibliographies.
← Back to Search

Hyperbranched Fluoropolymers And Their Hybridization Into Complex Amphiphilic Crosslinked Copolymer Networks

J. Bartels, C. Cheng, K. Powell, J. Xu, K. L. Wooley
Published 2007 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Share
This feature article highlights three types of hyperbranched fluoropolymers (HBFPs) with different structural features, which were synthesized by either polycondensation of fluorinated AB x monomers or self-condensing vinyl (co)polymerization of fluorinated inimers and/or fluorinated comonomers. Amphiphilic crosslinked networks with hybridization of these hydrophobic HBFPs and linear hydrophilic poly(ethylene glycol)s are also discussed. As microphase-segregated materials with nanoscale surface heterogeneities, these networks possessed unusual anti-biofouling abilities, atypical sequestration and release behaviors for guest molecules, and special mechanical properties.
This paper references
10.1002/POLA.20987
Hyperbranched fluorocopolymers by atom transfer radical self-condensing vinyl copolymerization
C. Cheng (2005)
10.1002/POLA.20898
Novel materials for bioanalytical and biomedical applications: Environmental response and binding/release capabilities of amphiphilic hydrogels with shape‐persistent dendritic junctions
C. Zhu (2005)
10.1002/(SICI)1099-0518(19980430)36:6<955::AID-POLA11>3.0.CO;2-K
Importance of active‐site reactivity and reaction conditions in the preparation of hyperbranched polymers by self‐condensing vinyl polymerization: Highly branched vs. linear poly[4‐(chloromethyl)styrene] by metal‐catalyzed “living” radical polymerization
Marc W. Weimer (1998)
10.1002/POLA.20466
Hyperbranched fluoropolymer and linear poly(ethylene glycol) based amphiphilic crosslinked networks as efficient antifouling coatings: An insight into the surface compositions, topographies, and morphologies
C. Gudipati (2004)
10.1021/JP050125W
Nanophase segregation and water dynamics in the dendrion diblock copolymer formed from the Fréchet polyaryl ethereal dendrimer and linear PTFE.
S. Jang (2005)
10.1021/LA052978L
Anti-biofouling properties of comblike block copolymers with amphiphilic side chains.
S. Krishnan (2006)
10.1126/science.269.5227.1080
Self-Condensing Vinyl Polymerization: An Approach to Dendritic Materials
Jean M. J. Fr�chet (1995)
10.1021/MA0217229
A Hyperbranched Aromatic Fluoropolyester for Photonic Applications
S. Kang (2003)
10.1021/MA9921293
Hyperbranched Polyimides for Gas Separation Applications. 1. Synthesis and Characterization
J. Fang (2000)
10.1021/LA961016Z
Inhibition of Electrochemical Reactions at Gold Surfaces by Grafted, Highly Fluorinated, Hyperbranched Polymer Films
M. Zhao (1997)
10.1021/LA010552A
Self-Assembled Monolayers That Resist the Adsorption of Proteins and the Adhesion of Bacterial and Mammalian Cells
E. Ostuni (2001)
10.1016/S0040-4020(03)00465-4
Surface, core, and structure modifications of phosphorus-containing dendrimers. Influence on the thermal stability
C. Turrin (2003)
10.1002/ADMA.200304551
Charge Transfer Complex Inimer: A Facile Route to Dendritic Materials
W. Wang (2003)
10.1002/MAME.200500048
Synthesis of Fluorinated Hyperbranched Polymers and Their Use as Additives in Cationic Photopolymerization
M. Sangermano (2005)
10.1002/POLA.10968
Amphiphilic and hydrophobic surface patterns generated from hyperbranched fluoropolymer/linear polymer networks: Minimally adhesive coatings via the crosslinking of hyperbranched fluoropolymers
D. Gan (2003)
10.1021/MA971201Z
Synthesis, Characterization, and Derivatization of Hyperbranched Polyfluorinated Polymers
A. Mueller (1998)
10.1021/CM990759D
Inclusion in Microporous β-Bis(1,1,1-trifluoro-5,5-dimethyl-5- methoxyacetylacetonato)copper(II), an Organic Zeolite Mimic†
D. Soldatov (2000)
10.1021/MA992111S
Surface Stability in Liquid-Crystalline Block Copolymers with Semifluorinated Monodendron Side Groups
M. Xiang (2000)
10.1002/MARC.200400249
Highly Fluorinated and Crosslinkable Dendritic Polymer for Photonic Applications
H. Ma (2004)
10.1002/POLA.20978
Ideal tetrafunctional amphiphilic PEG/PDMS conetworks by a dual‐purpose extender/crosslinker. I. Synthesis
G. Erdődi (2005)
10.1021/MA060521S
Synthesis of Hyperbranched Poly(arylene ether) from Monomer Containing Nitro Group: Kinetically Controlled Growth of Polymer Chain through Dynamic Exchange of End Functional Groups
Y. J. Kim (2006)
10.1016/S0927-7765(02)00160-1
Interactions of phospholipid- and poly(ethylene glycol)-modified surfaces with biological systems: Relation to physico-chemical properties and mechanisms
Patrick Vermette (2003)
10.1080/08927010410001655533
The Influence of Natural Surface Microtopographies on Fouling
A. Bers (2004)
10.1002/POLA.20977
Ideal tetrafunctional amphiphilic PEG/PDMS conetworks by a dual‐purpose extender/crosslinker. II. Characterization and properties of water‐swollen membranes
G. Erdődi (2005)
10.1021/LA034610Z
PAMAM dendrimer-induced cross-linking modification of polyimide membranes.
T. Chung (2004)
10.1002/1521-4095(200110)13:19<1483::AID-ADMA1483>3.0.CO;2-D
Functionalized fluorinated hyperbranched polymers for optical waveguide applications
C. Pitois (2001)
10.1002/POLA.21576
Complex amphiphilic networks derived from diamine-terminated poly(ethylene glycol) and benzylic chloride-functionalized hyperbranched fluoropolymers
K. Powell (2006)
10.1021/MA034326E
Preparation, Characterization, and Thermal and Surfactant Studies of Polyfluorinated Amphiphilic Carbosilane Dendrimers
B. Omotowa (2003)
Modern fluoropolymers : high performance polymers for diverse applications
J. Scheirs (1997)
10.1021/JA067986I
Unusual mechanical performance of amphiphilic crosslinked polymer networks.
Jinqi Xu (2007)
10.1002/ANIE.200351804
Transformation of a spherical supramolecular dendrimer into a pyramidal columnar supramolecular dendrimer mediated by the fluorophobic effect.
V. Percec (2003)
10.1021/MA991569R
Processability of Hyperbranched Poly(ether ketone)s with Different Degrees of Branching from Viewpoints of Molecular Mobility and Comparison with Their Linear Analogue
Seung-Yeop Kwak and (2000)
10.1021/MA021510B
Effect of Core Reactivity on the Molecular Weight, Polydispersity, and Degree of Branching of Hyperbranched Poly(arylene ether phosphine oxide)s
David P. Bernal (2003)
10.1021/MA9513877
Synthesis of branched and hyperbranched polystyrenes
S. Gaynor (1996)
10.1007/978-1-4899-0703-5
Poly(Ethylene Glycol) Chemistry
J. M. Harris (1992)
10.1039/b511555h
Design, synthesis, and characterization of linear fluorinated poly(benzyl ether)s: A comparison study with isomeric hyperbranched fluoropolymers
K. Powell (2005)
10.1021/LA049060Z
Surface characterization, modification chemistry, and separation performance of polyimide and polyamidoamine dendrimer composite films.
Youchang Xiao (2004)
10.1021/LA960693Q
Synthesis of hyperbranched, hydrophilic fluorinated surface grafts
Y. Zhou (1996)
10.1021/JA00029A034
Synthesis and characterization of a series of monodisperse, 1,3,5-phenylene-based hydrocarbon dendrimers including C276H186 and their fluorinated analogs
T. Miller (1992)
10.1021/LA048015O
The antifouling and fouling-release performance of hyperbranched fluoropolymer (HBFP)-poly(ethylene glycol) (PEG) composite coatings evaluated by adsorption of biomacromolecules and the green fouling alga Ulva.
C. Gudipati (2005)
10.1021/MA991710W
Molecular Orientation of Single and Two-Armed Monodendron Semifluorinated Chains on ``Soft'' and ``Hard'' Surfaces Studied Using NEXAFS
J. Genzer (2000)
10.1021/JA9739547
CYCLIZATION IN HYPERBRANCHED POLYMER SYNTHESES : CHARACTERIZATION BY MALDI-TOF MASS SPECTROMETRY
J. K. Gooden (1998)
10.1016/J.POLYMER.2004.08.010
Amelioration of mechanical brittleness in hyperbranched polymer. 1. Macroscopic evaluation by dynamic viscoelastic relaxation
S. Kwak (2004)
10.1002/POLA.21735
Third‐generation amphiphilic conetworks. I. Synthesis and swelling behavior of poly(N,N‐dimethyl acrylamide)/polydimethylsiloxane conetworks
G. Erdődi (2007)
10.1021/MA0628937
COMPLEX AMPHIPHILIC HYPERBRANCHED FLUOROPOLYMERS BY ATOM TRANSFER RADICAL SELF-CONDENSING VINYL (CO)POLYMERIZATION.
K. Powell (2007)
10.1002/POLB.20810
Individual and simultaneous swelling of amphiphilic conetworks in water and n‐heptane
Chunju He (2006)
10.1021/JA00054A057
Dendritic analogues of engineering plastics : a general one-step synthesis of dendritic polyaryl ethers
T. Miller (1993)
10.1021/JA0534405
Unusual, promoted release of guests from amphiphilic cross-linked polymer networks.
G. O. Brown (2005)
10.1021/MA9801669
Segmental dynamics in dendrimers with perfluorinated end groups: A study using quasielastic neutron scattering
B. Stark (1998)
10.1038/NMAT1004
Fluorine makes a difference
D. Tomalia (2003)
10.1021/LA034870G
A new interpretation of serum albumin surface passivation.
B. Sweryda-Krawiec (2004)
10.1016/J.POLYMER.2005.08.020
Geometrical influence of ABn monomer structure on the thermal properties of linear-hyperbranched ether–ketone copolymers prepared via an AB+ABn route
Eric Fossum (2005)
10.1021/MA020935V
Amphiphilic Hydrogels Constructed by Poly(ethylene glycol) and Shape-Persistent Dendritic Fragments1
I. Gitsov (2002)
10.1002/POLA.21757
Synthesis, characterization and properties of novel highly oxygen permeable amphiphilic membranes
R. Karunakaran (2007)
10.1021/JA0345625
Novel functionally grafted pseudo-semi-interpenetrating networks constructed by reactive linear-dendritic copolymers.
I. Gitsov (2003)
10.1007/S00289-004-0322-9
Physical and Gas Transport Properties of Novel Hyperbranched Polyimide – Silica Hybrid Membranes
T. Suzuki (2005)
10.1002/POLB.20692
Characterization of 6FDA‐based hyperbranched and linear polyimide–silica hybrid membranes by gas permeation and 129Xe NMR measurements
T. Suzuki (2006)
10.1021/LA011662K
Interaction of a bacterial endotoxin with different surfaces investigated by in situ fourier transform infrared attenuated total reflection spectroscopy
G. Reiter (2002)
10.1002/POLA.10475
Synthesis and characterization of hyperbranched polyimides with good organosolubility and thermal properties based on a new triamine and conventional dianhydrides
H. Chen (2002)
10.1021/MA0524777
Contact Angle Analysis, Surface Dynamics, and Biofouling Characteristics of Cross-Linkable, Random Perfluoropolyether-Based Graft Terpolymers
J. Yarbrough (2006)



This paper is referenced by
10.1021/ACSAMI.6B11112
Amphiphilic Cross-Linked Liquid Crystalline Fluoropolymer-Poly(ethylene glycol) Coatings for Application in Challenging Conditions: Comparative Study between Different Liquid Crystalline Comonomers and Polymer Architectures.
J. S. Zigmond (2016)
10.1021/bm201791p
Amphiphilic polybetaines: the effect of side-chain hydrophobicity on protein adsorption.
S. Çolak (2012)
10.1002/MACP.200700554
Change is the Only Constant
M. Staffilani (2008)
10.1021/MA202021Y
Synthesis, Characterization and Thermolysis of Hyperbranched Homo- and Amphiphilic Co-Polymers Prepared Using an Inimer Bearing a Thermolyzable Acylal Group
Maria Rikkou-Kalourkoti (2012)
10.1021/la202509m
A general approach to controlling the surface composition of poly(ethylene oxide)-based block copolymers for antifouling coatings.
M. Dimitriou (2011)
10.1002/POLA.29004
An emerging post‐polymerization modification technique: The promise of thiol‐para‐fluoro click reaction
S. Ağar (2018)
10.1021/nn204431m
Noradrenaline-functionalized hyperbranched fluoropolymer-poly(ethylene glycol) cross-linked networks as dual-mode, anti-biofouling coatings.
Philip M. Imbesi (2012)
Innovations in Wood Protection in the age of Nanotechnology
C. Clausen (2014)
10.1021/am2003075
Real-time quantification of microscale bioadhesion events in situ using imaging surface plasmon resonance (iSPR).
N. Aldred (2011)
10.2737/fpl-gtr-218
Enhancing durability of wood-based composites with nanotechnology
C. Clausen (2012)
10.1039/B910899H
Approaches in designing non-toxic polymer surfaces to deter marine biofouling
Claudia M. Grozea (2009)
10.1016/J.POLYMER.2014.08.036
Synthesis and characterization of glycerol-adipic acid hyperbranched polyesters
Tracy Zhang (2014)
10.1007/s10965-012-9937-y
Erratum to: Cyclodextrin-based hyperbranched polymers by acyclic diene metathesis polymerization of an ABn monomer: molecule design, synthesis, and characterization
N. Wang (2012)
10.1002/macp.201200075
A Polyurethane Surface Modifier: Contrasting Amphiphilic and Contraphilic Surfaces Driven by block and random Soft Blocks having Trifluoroethoxymethyl and PEG Side Chains.
W. Zhang (2012)
10.1021/am200337q
Antibiofouling hybrid dendritic Boltorn/star PEG thiol-ene cross-linked networks.
J. Bartels (2011)
10.1080/00397910802419714
Convenient Preparation of Hydroxymethyl-Substituted Diaminodiphenyloxybenzenes
M. Davis (2009)
10.1039/C2PY20317K
Targeted surface nanocomplexity: two-dimensional control over the composition, physical properties and anti-biofouling performance of hyperbranched fluoropolymer–poly(ethylene glycol) amphiphilic crosslinked networks
Philip M. Imbesi (2012)
10.7936/K7Z03667
Well-defined molecular brushes: Synthesis by a "grafting through" strategy and self assembly into complicated hierarchical nanostructures
Z. Li (2011)
10.7936/K7QF8QWM
Synthesis and investigation of UV-cured, complex amphiphilic polymer films for use in anti-biofouling applications
J. Bartels (2010)
10.1021/acscentsci.6b00195
Organic Polymer Chemistry in the Context of Novel Processes
J. Desimone (2016)
10.1016/J.POLYMER.2012.08.032
Conventional and microwave-assisted synthesis of hyperbranched and highly branched polylysine towards amphiphilic core–shell nanocontainers for metal nanoparticles
C. Ho (2012)
10.1002/POLA.24175
Photo‐crosslinked fluorinated thin films from azido‐functionalized random copolymers
S. A. Akhrass (2010)
10.1039/c4cs00229f
Bioapplications of hyperbranched polymers.
D. Wang (2015)
10.1039/C2JM32005C
Thiol-ene “click” networks from amphiphilic fluoropolymers: full synthesis and characterization of a benchmark anti-biofouling surface
Philip M. Imbesi (2012)
10.1021/am505296n
Hyperbranched fluoropolymer-polydimethylsiloxane-poly(ethylene glycol) cross-linked terpolymer networks designed for marine and biomedical applications: heterogeneous nontoxic antibiofouling surfaces.
Kevin A. Pollack (2014)
10.1071/CH10011
Synthesis and Solution-state Assembly or Bulk State Thiol-ene Crosslinking of Pyrrolidinone- and Alkene-functionalized Amphiphilic Block Fluorocopolymers: From Functional Nanoparticles to Anti-fouling Coatings
J. Ma (2010)
10.1002/POLA.27800
Investigation of intricate, amphiphilic crosslinked hyperbranched fluoropolymers as anti‐icing coatings for extreme environments
J. S. Zigmond (2016)
10.1016/J.EURPOLYMJ.2017.09.019
Zwitterionic–polyurethane coatings for non-specific marine bacterial inhibition: A nontoxic approach for marine application
S. Yesudass (2017)
10.1021/MZ200137M
Model Diels–Alder Studies for the Creation of Amphiphilic Cross-Linked Networks as Healable, Antibiofouling Coatings
Philip M. Imbesi (2012)
10.1163/092050611X589329
Combinatorial Approach for Fabrication of Coatings to Control Bacterial Adhesion
S. Pedron (2012)
10.1007/S13369-013-0916-3
Advanced Techniques for the Characterization of Surface Structure in Polymer Thin Films and Coatings
M. Dimitriou (2014)
10.1039/c4cs00329b
Structure, function, self-assembly, and applications of bottlebrush copolymers.
Rafael Verduzco (2015)
See more
Semantic Scholar Logo Some data provided by SemanticScholar