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Fullerene–ferrocene Dyad Linked By Rigid Bilinkage: Synthesis, Photophysical Properties And Application As Copper Ion Sensor

Anish Kumar, S. Menon
Published 2009 · Chemistry

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A novel fullerene–ferrocene based donor–bridge–acceptor dyad was synthesized and characterized by elemental analysis, FT-IR, 1H NMR, 13C NMR and FAB-MS. The dyad with a bilinker comprising of azomethine and ester group was studied for its photo physical properties using absorption spectra and steady-state fluorescence spectra as a function of dielectric constant of the medium. Fluorescence spectra of the dyad studied with excitation at 449 nm showed a weak emission at 742 nm, which got weaker on increasing the dielectric constant of the medium, indicating efficient electron transfer from ferrocene to fullerene. By designing a bilinked structure between the two redox moieties, we obtained a chelating structure which was found to coordinate copper ion efficiently and hence found application as a metal ion sensor. Copyright © 2008 John Wiley & Sons, Ltd.
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