Online citations, reference lists, and bibliographies.
Please confirm you are human
(Sign Up for free to never see this)
← Back to Search

A Study Of Polypyrrole Synthesized With Oxidative Transition Metal Ions

T. Chao, J. March
Published 1988 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Polypyrrole powder and films were chemically synthesized by the reaction of AgNO3, FeCl3, Fe(NO3)3, Cu(NO3)2, or Cu(NO3)2-AlCl3 with pyrrole in an aqueous solution or a water—toluene two-phase system. Products were characterized by elemental analysis, IR, scanning electron microscopy with energy dispersive x-ray analysis (SEM with EDAX), and conductivity measurements. The polypyrrole synthesized from pyrrole with FeCl3 had a composition of C4.00H3.05N0.99Cl0.25. The pressed powder had a conductivity of 2.7 × 10−2 S/cm and the film 2.8 S/cm. All the other metal salts produced films that had the same organic backbone, morphology, and conductivity as the polymer synthesized using Fe(III) salts, regardless of the considerable differences in the reduction potentials of the metal ions. The nature of the anions of the transition metal salts had no effect on the reaction. Anions, however, were retained as the counterions of the cationic polypyrrole backbone and could be easily exchanged with other anions.



This paper is referenced by
10.1016/0379-6779(91)91799-G
Polypyrroles prepared by chemical oxidative polymerization at different oxidation potentials
Y. Whang (1991)
10.1002/MASY.19971170124
Mineralization of gold in block copolymer micelles
M. Möller (1997)
10.1039/C1PY00311A
Preparation of hierarchical porous polypyrrole nanoclusters and their application for removal of Cr(VI) ions in aqueous solution
T. Yao (2011)
10.1002/PC.21247
Electrical actuation of ionic hydrogels based on polyvinyl alcohol grafted with poly(2-acrylamido-2-methyl-1-propanesulfonic acid-co-acrylonitrile) chains
R. Mahloniya (2012)
10.1007/978-3-319-99602-8_4
Nanomaterials: Electromagnetic Wave Energy Loss
G. J. H. Melvin (2019)
10.1039/JM9910100525
Characterization of conducting polymer–quartz composites
S. P. Armes (1991)
10.1007/s12221-013-0345-7
Studies on electro-conductive fabrics prepared by in situ chemical polymerization of mixtures of pyrrole and thiophene onto polyester
D. Das (2013)
10.1016/J.MOLSTRUC.2017.12.013
Delocalization of π electrons and trapping action of ZnO nanoparticles in PPY matrix for hybrid solar cell application
R. Singh (2018)
10.1007/BF03214903
Gold-catalysed synthesis of polypyrrole
C. D. Pina (2009)
Design and Fabrication of conducting polymer/Platinum nanoparticles nanocomposites and the study of their physicochemical, morphological and linear actuation properties
A. Costa (2013)
10.1007/BF00297897
Preparation and morphology of electrically conductive and transparent poly(vinylchloride)-polypyrrole composite films
T. J. Kang (1993)
10.1016/J.POLYMER.2003.11.014
Synthesis and nitrosation of processible copolymers from pyrrole and ethylaniline
Xingui Li (2004)
10.1088/0957-4484/23/33/335603
Controlled synthesis of transition metal/conducting polymer nanocomposites.
Z. Liu (2012)
10.1002/ADFM.201800502
Remarkable Acid Stability of Polypyrrole‐MoS4: A Highly Selective and Efficient Scavenger of Heavy Metals Over a Wide pH Range
L. Xie (2018)
10.1201/9780203911488.ch10
Synthesis, characterization, and biomedical applications of conducting polymer particles
M. Chehimi (2003)
10.1002/PEN.11844
Conductive polymer blends prepared by in situ polymerization of pyrrole: A review
M. Jesus (1997)
10.1007/BF00582447
The influence of unusual counterions on the electrochemistry and physical properties of polypyrrole
K. M. Cheung (1990)
10.1246/CL.1990.1369
New Catalytic Polymerization of Pyrrole
N. Toshima (1990)
10.1002/APP.1944
Soluble polypyrrole copolymers
Belkıs Ustamehmetoğlu (2001)
10.1016/J.SNB.2003.12.077
Sensing characteristics of polypyrrole–poly(vinyl alcohol) methanol sensors prepared by in situ vapor state polymerization
L. Jiang (2005)
10.1246/BCSJ.67.539
Preparation of polypyrrole from pyrrole by using the catalytic system of VO(acac)2-AlCl3-O2
Seishi Izumi (1994)
10.1007/978-3-642-78759-1_26
Highly Electrically Conductive Polymer Composites and Blends
T. J. Kang (1994)
10.1007/978-94-011-3476-7_1
Conjugated Polymers: The Interplay Between Synthesis, Structure, and Properties
C. Gorman (1991)
10.1007/s13738-013-0371-9
Composites of polyaniline and lead dioxide: preparation, characterization, and catalytic activity
R. Elsharkawy (2013)
10.1295/POLYMJ.25.91
Preparation of Polypyrrole-Poly(vinyl chloride) Composite Films by Interphase Oxidative Polymerization
Masakazu Nakata (1993)
10.1080/00914030490498270
ELECTROCHEMICAL COPOLYMERIZATION OF N-METHYL PYRROLE WITH CARBAZOLE
A. S. Saraç (2004)
10.1002/PC.21237
Electrical conductivity studies on water-soluble polypyrrole–graphene oxide composites
C. Basavaraja (2011)
10.1080/10236660304882
Oxidative Copolymerization of Pyrrole and N-Methyl Pyrrole
Belkıs Ustamehmetoğlu (2003)
10.1246/BCSJ.62.1908
The preparation of poly(3-methoxy-2,5-thiophenediyl) with iron(III) chloride and its properties.
S. Tanaka (1989)
10.1016/j.jcis.2018.06.033
Easy-handling bamboo-like polypyrrole nanofibrous mats with high adsorption capacity for hexavalent chromium removal.
Y. Zhan (2018)
10.1021/am400059t
Imine-linked polymer-derived nitrogen-doped microporous carbons with excellent CO2 capture properties.
J. Wang (2013)
10.1002/SIA.3489
Synthesis of polypyrrole coatings on surface of iron particles
R. Oriňaková (2010)
See more
Semantic Scholar Logo Some data provided by SemanticScholar