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Ultrarobust Thin-Film Devices From Self-Assembled Metal-Terpyridine Oligomers.

Zoi Karipidou, B. Branchi, Mustafa Sarpasan, N. Knorr, V. Rodin, Pascal Friederich, T. Neumann, V. Meded, S. Rosselli, G. Nelles, W. Wenzel, M. A. Rampi, Florian von Wrochem
Published 2016 · Materials Science, Medicine

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Ultrathin molecular layers of Fe(II) -terpyridine oligomers allow the fabrication of large-area crossbar junctions by conventional electrode vapor deposition. The junctions are electrically stable for over 2.5 years and operate over a wide range of temperatures (150-360 K) and voltages (±3 V) due to the high cohesive energy and packing density of the oligomer layer. Electrical measurements reveal ideal Richardson-Shottky emission in surprising agreement with electrochemical, optical, and photoemission data.
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