Online citations, reference lists, and bibliographies.
← Back to Search

Coordination Chemistry At Carbon: The Patchwork Family Comprising (Ph3P)2C, (Ph3P)C(C2H4), And (C2H4)2C.

Hubert Schmidbaur, Annette Schier
Published 2013 · Chemistry, Medicine

Cite This
Download PDF
Analyze on Scholarcy
Share
The revitalized concept of "coordination at carbon" allows relationships between seemingly unrelated families of carbon-centered compounds to be discovered generating fascinating patchwork families of compounds. It is shown how olefins and cyclopropanes can be regarded as donors for carbon acceptors C(1), C(2), and C(3). Through this approach, hydrocarbons such as spiropentane and dicyclopropylidene are found to be counterparts of the bis-ylidic carbodiphosphoranes and the corresponding mixed mono-ylidic systems.
This paper references
10.1515/znb-1976-0604
Ein gemischt methyl/phenyl-substituiertes Carbodiphosphoran. Darstellung, Reaktionen und verwandte Verbindungen / A Mixed Methyl-/Phenyl-substituted Carbodiphosphorane. Synthesis, Reactions, and Related Compounds
M. Hussain (1976)
10.1002/chem.200701392
Divalent carbon(0) chemistry, part 2: Protonation and complexes with main group and transition metal Lewis acids.
R. Tonner (2008)
10.1039/A708439K
Synthesis and characterization of Ag2C2·2AgClO4·2H2O: a novel layer-type structure with the acetylide dianion functioning in a µ6-η1,η1:η2,η2:η2,η2 bonding mode inside an octahedral silver cage
G. Guo (1998)
10.1002/CBER.19761090730
Untersuchungen über kleine Ringsysteme, XXXV: Neue 1,1′‐Bicyclopropane und ein verbesserter Zugang zu 1,1′‐Bicyclopropyliden
A. Schmidt (1976)
10.1021/OM2010113
Gold Chemistry Guided by the Isolobality Concept
H. Raubenheimer (2012)
10.1002/ANIE.200602552
Carbodiphosphoranes: the chemistry of divalent carbon(0).
R. Tonner (2006)
10.1002/ANGE.19830951203
Elektronenreiche Halbsandwich‐Komplexe — Metall‐Basen par excellence
H. Werner (2006)
10.1021/ja00854a077
Bis(trimethylphosphoranylidene)methane, (CH3)3PCP(CH3)3
O. Gasser (1975)
10.1039/JR9620002460
471. Diarsine complexes of quadrivalent-metal halides
R. Clark (1962)
10.1002/ANGE.200800846
Carbodicarbene: Verbindungen mit zweibindigem Kohlenstoff(0)‐Atom
O. Kaufhold (2008)
10.1002/HLCA.19970800816
Neue Bi(cyclopropylidene) durch CuCl2‐katalysierte ‘Carben‐Dimerisieiung’ von 1‐Bromo‐1‐lithiocyclopropanen
M. Borer (1997)
10.1002/ANIE.197904081
Problem of the Structure of Carbodiphosphoranes, R3PCPR3: New Aspects
H. Schmidbaur (1979)
Soc
J. J. Daly (1703)
10.1002/anie.200705620
Synthesis of an extremely bent acyclic allene (a "carbodicarbene"): a strong donor ligand.
C. Dyker (2008)
10.1080/03086648308075993
Ylide Chemistry: An Account of Structural, Conformational and Redox Investigations
H. Schmidbaur (1983)
10.1017/cbo9780511809224.005
Chemistry of the elements
N. N. Greenwood (1984)
10.1021/ja00471a017
An ab initio molecular orbital study of structures and energies of spiro compounds: spiropentane, spiropentene, spiropentadiene, spiro[2.4]hepta-4,6-diene, spiro[2.4]heptatriene, and spiro[4.4]nonatetraene
J. Kao (1978)
10.1002/anie.201107815
Lewis base stabilized dicarbon: predictions from theory.
J. L. Dutton (2012)
10.1038/nchem.248
Coordination chemistry at carbon.
Manuel Alcarazo (2009)
THE MOLECULAR AND ELECTRONIC STRUCTURE OF PHOSPHONIUM CYCLOPROPYLIDE H3P=C(CH2)2: A THEORETICAL STUDY
M. A. Vincent (1982)
10.1016/B978-0-12-610508-7.50007-4
Recent Developments in the Chemistry of Transition Metal Carbides and Nitrides
H. Johansen (1977)
10.1002/CBER.19951280209
Hypercoordinate Carbon in Trigoldbis(silyl)methanium Cations
S. Bommers (1995)
10.1002/ANIE.197605021
The Ambident Ligand Properties of Bis(trimethylphosphoranylidene)methane
H. Schmidbaur (1976)
10.1021/JO00054A040
A new general approach to bicyclopropylidenes
A. D. Meijere (1993)
10.1021/JA00186A058
Spiropentane as a tensile spring
R. Boese (1989)
10.1002/ANIE.198700791
Synthesis of Nitriles via the Ylide Anion of Sodium Cyanotriphenylphosphoranylidenemethanide
H. J. Bestmann (1987)
10.1002/ANGE.19770890628
„Carbodiphosphorane”︁ durch eine neue Umlagerung von Phosphor‐Yliden
Anette Wohlleben (1977)
10.1021/ic300686n
Are N-heterocyclic carbenes "better" ligands than phosphines in main group chemistry? A theoretical case study of ligand-stabilized E2 molecules, L-E-E-L (L = NHC, phosphine; E = C, Si, Ge, Sn, Pb, N, P, As, Sb, Bi).
David J D Wilson (2012)
Chem
A. P. Krapcho (1650)
10.1016/0010-8545(83)85001-2
The coordination chemistry of ylides
W. C. Kaska (1983)
10.1002/anie.201201959
A combined gas-phase photoelectron spectroscopic and theoretical study of Zeise's anion and its bromine and iodine analogues.
Gao-Lei Hou (2012)
10.1002/ANIE.199312051
1,3‐Bis(triphenylphosphoranylidene)allene and Tribenzyl(4‐methyldiphenylphosphonio‐butadiynyl)borate, Stabilized C3 and C4: Confirmation of a Hypothesis
H. J. Bestmann (1993)
10.1002/ANIE.198309271
Electron‐Rich Half‐Sandwich Complexes—Metal Bases par excellence
H. Werner (1983)
10.1002/ANIE.198312410
Tricyclo[4.1.0.0.1,3]hept‐4‐ene als Zwischenstufen
U. H. Brinker (1983)
Organometallic compounds of arsenic, antimony, and bismuth
G. O. Doak (1970)
10.1002/ANIE.197704171
“Carbodiphosphoranes” by a New Rearrangement of Phosphorus Ylides
Anette Wohlleben (1977)
10.1002/CBER.19811140420
Cyclische Doppel‐Ylide und ihre korrespondierenden Diphosphonium‐triple‐ylid‐Anionen: Synthese, Struktur und komplexchemisches Verhalten
H. Schmidbaur (1981)
10.1021/JA00704A003
Photoelectron spectra of molecules. III. Ionization potentials of some cyclic hydrocarbons and their derivatives, and heats of formation and ionization potentials calculated by the MINDO[minimum neglect of differential overlap]SCF MO method
N. Bodor (1970)
10.1002/ANIE.198912191
Phosphonioboratoacetylenes: C2 Stabilized by Donor and Acceptor Molecules
H. J. Bestmann (1989)
10.1016/S0277-5387(00)00467-8
Gold(I) complexes containing the cationic ylide ligand bis(methyldiphenylphosphonio)methylide
I. Romeo (2000)
Soc
E. Ōsawa (1209)
10.1016/0022-2860(84)87229-4
Bonding properties of bicyclopropylidene: gas phase electron diffraction study and X-ray crystal structure analysis
M. Trætteberg (1984)
10.1002/anie.200803200
Carbenes stabilized by ylides: pushing the limits.
A. Fürstner (2008)
10.1016/S0040-4039(01)91576-X
Über die darstellung und eine neue umlagerungsreaktion von (trialkylphosphoranyliden)(triphenylphosphoranyliden)-methanen (carbodiphosphoranen)
R. Appel (1978)
10.1002/ANGE.19931050810
1,3‐Bis(triphenylphosphoranyliden)allen und Tribenzyl(4‐methyldiphenylphosphoniobutadiinyl)‐borat, stabilisiertes C3 und C4 ‐die Bestätigung einer Hypothese
H. J. Bestmann (1993)
10.1002/ANGE.19650771633
Die termische Zersetzung von Alkoxycarbonylmethyl‐triphenylphosphonium‐halogeniden
H. Hartung (1965)
10.1021/ja301333f
Synthesis of a uranium(VI)-carbene: reductive formation of uranyl(V)-methanides, oxidative preparation of a [R2C═U═O]2+ analogue of the [O═U═O]2+ uranyl ion (R = Ph2PNSiMe3), and comparison of the nature of U(IV)═C, U(V)═C, and U(VI)═C double bonds.
David P Mills (2012)
10.1002/RECL.19680870805
Electron diffraction by gases: The molecular structure of spiropentane
G. Dallinga (2010)
10.1016/S0040-4020(01)86460-7
Reaction OF E-1,2-bis[triphenyl(trifluoromethanesulfonyloxy)phospho]ethylene, Ph3PCHCHPPh3·20Tfwith bases: Unusual products and evidence for C2-dlylide, Ph3PCCPPh3, formation
P. Stang (1991)
10.1002/chem.201001779
A new class of singlet carbene ligands.
Manuel Alcarazo (2010)
10.1021/JO00225A057
Structures and energies of the tricyclo[4.1.0.01,3]heptanes and the tetracyclo[4.2.1.02,905,9]nonanes. Extended group equivalents for converting ab initio energies to heats of formation
K. Wiberg (1985)
10.1002/ANGE.19881001130
„Aurophilie”︁ als Konsequenz relativistischer Effekte: Das Hexakis(triphenylphosphanaurio)methan‐Dikation [(Ph3PAu)6C]2⊕
F. Scherbaum (1988)
10.1002/CBER.19841171206
Synthesen unsymmetrischer Methyl/Phenylcarbodiphosphorane durch Aufbau oder Umlagerung
H. Schmidbaur (1984)
10.1002/1521-3765(20010917)7:18<4021::AID-CHEM4021>3.0.CO;2-E
Spirocyclopropanated bicyclopropylidenes: straightforward preparation, physical properites, and chemical transformations.
A. de Meijere (2001)
10.1002/ANIE.198309071
Phosphorus Ylides in the Coordination Sphere of Transition Metals: An Inventory
H. Schmidbaur (1983)
10.1021/AR50073A002
From diyls over ylides to my idyll
G. Wittig (1974)
10.1021/AR50086A003
Inorganic chemistry with ylides
H. Schmidbaur (1975)
10.1002/CBER.19691020605
Reaktionen mit Phosphinalkylenen, XXII. Eine neue Ringschlußreaktion
H. J. Bestmann (1969)
10.1021/JA00421A026
Electronic states of organic molecules. I. Potential functions for the deformation of methane
K. Wiberg (1976)
10.1016/S0040-4039(01)82833-1
Darstellung und reaktionen des triphenylphosphin-cyclopropylidens.
H. Bestmann (1966)
10.1007/3-540-48255-5_3
Bicyclopropylidene — A Unique Tetrasubstituted Alkene and a Versatile C6-Building Block
A. D. Meijere (2000)
10.1038/nchem.1263
Quadruple bonding in C2 and analogous eight-valence electron species.
S. Shaik (2012)
10.1002/CBER.19811140715
Präparative und NMR‐spektroskopische Beiträge zum Isomerieproblem der Carbodiphosphorane
H. Schmidbaur (1981)
10.1002/CBER.19791120214
Doppel‐Ylide, VI. Ylidbildung und Umlagerung bei 1,3‐Diphosphoniumsalzen
H. Schmidbaur (1979)
10.1021/JA00062A078
A NEW FORM OF COORDINATED CARBON: AN UNSUPPORTED LINEAR C3 CHAIN SPANNING TWO DIFFERENT TRANSITION METALS
Weiqing Weng (1993)
10.1021/CR00098A005
Carbon molecules, ions, and clusters
W. Weltner (1989)
10.1038/2011322A0
Four-co-ordinate Complexes of Carbon
R. N. Collinge (1964)
10.1016/0040-4020(78)88380-X
An ab initio molecular orbital study of structures and energies of spirocompounds: spiro[3.3]heptane and spiro[3.3]hepta-1,5-diene
J. Kao (1978)
10.1002/anie.201103197
Synthesis, structure, and reactivity of a dihydrido borenium cation.
B. Inés (2011)
10.1002/anie.200705798
Coordination chemistry of ene-1,1-diamines and a prototype "carbodicarbene".
A. Fürstner (2008)
10.1021/CR00095A001
Small ring propellanes
K. Wiberg (1989)
10.1515/znb-1982-0601
Synthese eines Doppel-Carbodiphosphorans und seiner Vorstufen / Synthesis of a Double-Carbodiphosphorane and its Precursors
H. Schmidbaur (1982)
10.1021/JA01000A050
New type of stable tetrapolar phosphorus ylide
F. Ramírez (1967)
10.1002/ANIE.196509572
Formation of Ylides on Thermal Decomposition of P-(α-Alkoxycarbonylalkyl)triphenylphosphonium Salts
H. Bestmann (1965)
10.1021/JA01477A052
HEXAPHENYLCARBODIPHOSPHORANE, (C6H5)3PCP(C6H5)3
F. Ramírez (1961)
10.1021/CR00029A008
No d Orbitals but Walsh Diagrams and Maybe Banana Bonds: Chemical Bonding in Phosphines, Phosphine Oxides, and Phosphonium Ylides.
D. Gilheany (1994)
10.1021/OM00011A001
Hypercoordinate Carbon in Protonated Tetraauriomethane Molecules
H. Schmidbaur (1995)
10.1016/S0040-4039(01)98029-3
Etude des rotanes (III) le bicyclopropylidène et sa dimérisation thermique en tétracyclopropylidène.
P. L. Perchec (1970)
10.1002/ANIE.200501754
Reactions of gold(III) oxo complexes with cyclic alkenes.
M. A. Cinellu (2005)
10.1016/J.JORGANCHEM.2005.09.024
Phosphorus-substituted carbene complexes: Chelates, pincers and spirocycles
N. D. Jones (2005)
10.1002/CBER.19811140913
Ein cyclisches Carbodiphosphoran und eine offenkettige Vergleichsverbindung
H. Schmidbaur (1981)
10.1021/JO00365A008
Electronic structure of spiropentane and some derivatives
R. Gleiter (1986)
10.1063/1.1724867
High-Resolution Infrared Determination of the Structure of Carbon Suboxide
W. J. Lafferty (1964)
10.1002/ANIE.199405471
Novel Carbon Compounds with “Naked” Cn Units
H. Lang (1994)
10.1021/IC950946N
Isolation and Structural Characterization of [P(AuPPh(3))(5)][BF(4)](2) via Cleavage of a P-P Bond by Cationic Gold Fragments: Direct Evidence of the Structure of the Elusive Tetrakis[phosphineaurio(I)]phosphonium(+) Cation.
R. Bachman (1996)
10.1039/B610657A
Synthesis and properties of gold alkene complexes. Crystal structure of [Au(bipyoXyl)(η2-CH2CHPh)](PF6) and DFT calculations on the model cation [Au(bipy)(η2-CH2CH2)]+
M. A. Cinellu (2006)
10.1002/ANIE.200704071
Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C=SR2.
S. Pascual (2007)
10.1002/CBER.19831160618
Darstellung und Molekülstruktur aminosubstituierter Carbodiphosphorane
R. Appel (1983)
10.1021/OM00121A026
Synthesis of the first carbodiarsorane and related arsenic ylides
H. Schmidbaur (1985)
10.1002/ANIE.198308691
Tricyclo[4.1.0.01,3] hept‐4‐enes as Intermediates
U. H. Brinker (1983)
10.1021/ja00797a042
Crystal structure of 2,2,3,3,4,4-hexafluoro(triphenylphosphoranylidene)cyclobutane
Marlys A. Howells (1973)
10.1039/J19660001703
Structure of triphenylphosphoranylideneketen
J. J. Daly (1966)
10.1002/ANGE.19891010410
Synthese, Struktur und Diskussion der Bindungsverhältnisse des Kations [{(C6H5)3PAu}5C]⊕
F. Scherbaum (1989)
10.1021/JA00022A039
Ruthenium/zirconium complexes containing C2 bridges with bond orders of 3, 2, and 1. Synthesis and structures of Cp(PMe3)2RuCHnCHnZrClCp2 (n = 0, 1, 2)
F. R. Lemke (1991)
10.1021/IC00066A017
Gold(I)-clustering at a primary arylphosphine with bulky substituents: [2,4,6-(Me3C)3C6H2P(AuPR3)n](n-2)+ (R = tert-Bu, Ph; n = 2-4) complexes and crystal structure of the species with n = 3 and R = phenyl
Edgar Zeller (1993)
10.1002/ANGE.200602552
Carbodiphosphorane: die Chemie von zweibindigem Kohlenstoff(0)
R. Tonner (2006)
10.1021/JO052053A
Tetracoordinate carbon as a nucleophile? Interconversion of carbenium ions with carbonium ions possessing nearly square-pyramidal pentacoordinate carbons.
M. Siebert (2006)
10.1002/ANIE.200504396
Cyclic Carbodiphosphoranes: Strongly Nucleophilic σ‐Donor Ligands
Sébastien Marrot (2006)
10.1002/CBER.19831160522
Gerüstumlagerungen der Methyltrimesitylphosphonium‐ und Methylenbis(methyldimesitylphosphonium)‐Kationen bei der Basenbehandlung
H. Schmidbaur (1983)
10.1002/ANIE.197703491
Phosphacumulene Ylides and Phosphaallene Ylides [New synthetic methods (19)]
H. J. Bestmann (1977)
10.1002/anie.200800846
Carbodicarbenes: divalent carbon(0) compounds.
O. Kaufhold (2008)
10.1021/OM020753P
New Ylide-, Alkynyl-, and Mixed Alkynyl/Ylide-Gold(I) Complexes
J. Vicente (2002)
10.1002/ANIE.200701632
C(NHC)2: divalent carbon(0) compounds with N-heterocyclic carbene ligands-theoretical evidence for a class of molecules with promising chemical properties.
R. Tonner (2007)
10.1038/345140A0
Electron-deficient bonding at pentacoordinate nitrogen
A. Grohmann (1990)
10.1007/978-3-642-04722-0_3
Carbodiphosphoranes and Related Ligands
W. Petz (2010)
10.1002/CBER.19911240720
Synthesis, structure, and electronic properties of bis(tetramethylcyclopropylidene)methane and bis(cyclopropylidene)methane
M. Eckert-Maksić (1991)
10.1021/JA00238A004
Theoretical analysis of hydrocarbon properties. 1. Bonds, structures, charge concentrations, and charge relaxations
K. Wiberg (1987)
10.1021/ja00407a001
Structure of spiropentane: an NMR study
W. Bechtold (1981)
10.1021/jp905368b
Ab initio calculations on the formation and rearrangement of spiropentane.
B. Carpenter (2009)
10.1016/S0166-1280(00)00442-5
Analytical representations of high level ab initio potential energy curves of the C 2 molecule
M. Boggio-Pasqua (2000)
10.1016/0040-4039(93)85052-X
Is a CC quadruple bond possible
Paul von RaguéSchleyer (1993)
10.1002/ANGE.19830951205
Phosphor-Ylide in der Koordinationssphäre von übergangsmetallen: Eine Bestandsaufnahme†
H. Schmidbaur (2006)
10.1002/ANIE.198904631
Synthesis, Structure, and Bonding of the Cation [{(C6H5)3PAu}5C]⊕†
F. Scherbaum (1989)
10.1002/CBER.19921251124
Substituenteneffekte auf die Struktur von Spiropentan
H. Irngartinger (1992)
10.1002/CBER.19821150232
Triphenylphosphonium‐cyclopropylid: Röntgenbeugungsanalyse eines pyramidalen Carbanions
H. Schmidbaur (1982)
10.1002/ANIE.196902161
O‐Alkylation of Alkoxycarbonylalkylidenetriphenylphosphoranes
H. Bestmann (1969)
10.1073/PNAS.19.9.860
The Electron-Diffraction Investigation of the Structure of Molecules of Methyl Azide and Carbon Suboxide.
L. Brockway (1933)
10.1016/0166-1280(88)80003-4
Structural variations in small ring hydrocarbons bridged by allenic double bonds
M. Eckert-Maksić (1988)
10.1107/S0108270186093101
(Hexaphenylcarbodiphosphorane)copper(I) chloride: A mononuclear organocopper complex
G. Mueller (1986)
10.1002/ANGE.19891010941
Phosphonioboratoacetylene, durch Donor- und Acceptormoleküle stabilisiertes C2†
H. J. Bestmann (1989)
10.1002/ANGE.19870990112
Synthese von Nitrilen über das Ylidanion von Natriumcyantriphenylphosphoranylidenmethanid
H. J. Bestmann (1987)
10.1002/CHIN.197602326
Neutron diffraction study of the structure of Zeise's salt, KPtCl3(C2H4).H2O
R. A. Love (1976)
10.1002/ANGE.19690810610
O‐Alkylierung von Alkoxycarbonylalkyliden‐triphenylphosphoranen
H. Bestmann (1969)
10.1002/ANGE.19901020331
Synthese und Struktur des neuen μ2‐Carbido‐Komplexes [(TPP)Fe C Re(CO)4Re(CO)5]
W. Beck (1990)
10.1002/ANGE.200701632
C(NHC)2: zweibindige Kohlenstoff(0)‐Verbindungen mit N‐heterocyclischen Carbenliganden – theoretische Belege für eine Molekülklasse mit vielversprechenden Eigenschaften
R. Tonner (2007)
10.1002/chem.201000174
Carbodicarbenes and related divalent carbon(0) compounds.
S. Klein (2010)
Chem
K. B. Wiberg (1212)
10.1002/ANIE.198815441
“Aurophilicity” as a Consequence of Relativistic Effects: The Hexakis(triphenylphosphaneaurio)methane Dication [(Ph3PAu)6C]2⊕
F. Scherbaum (1988)
10.1021/JA00493A035
Structure and triboluminescence of polymorphs of hexaphenylcarbodiphosphorane
G. E. Hardy (1978)
10.1002/CBER.19811140914
Molekül‐ und Kristallstrukturen zweier Carbodiphosphorane mit PCP‐Bindungswinkeln nahe 120°
U. Schubert (1981)
10.1002/ANGE.19770890605
Phosphacumulenylide und Phosphaallenylide
H. J. Bestmann (1977)
10.1021/JO00903A017
Synthesis of bicyclobutylidene, 1,3-bis(trimethylene) propadiene, and 1,4-bis(trimethylene)butatriene
L. K. Bee (1975)
10.1002/CBER.19691020606
Reaktionen mit Phosphinalkylenen, XXIII. Reaktionen von Phosphinalkylenen mit Nitriloxiden. Eine neue Synthesemöglichkeit für Azirine, Ketenimine und α.β-ungesättigte Oxime
H. J. Bestmann (1969)
10.1002/CBER.19681010229
Reindarstellung und Eigenschaften von Trialkyl-alkyliden-phosphoranen
Hubert Schmidaur (1968)
Chem
D. B. Boyd (1064)
10.1016/S0065-3055(03)50004-1
Transition Metal Complexes Containing All-Carbon Ligands
M. Bruce (2004)
10.1021/JA0265310
The theoretical design of neutral planar tetracoordinate carbon molecules with C(C)(4) substructures.
Z. Wang (2002)
10.1055/S-1987-27926
Preparative-Scale Syntheses of Bicyclobutylidene, Methylenecyclobutane and Cyclobutanone
L. Fitjer (1987)
10.1002/CBER.19831160611
Reindarstellung, NMR‐Spektren und Kristallstruktur von Triphenylphosphonium‐cyclobutylid, (C6H5)3PC[CH2]3
H. Schmidbaur (1983)
10.1515/znb-1982-1206
Derivate und Koordinationsverbindungen des Triphenylphosphoniumcyclopropylids (C6H5)3P =C(CH2)2 / Derivatives and Coordination Compounds of Triphenylphosphonium Cyclopropylide (C6H5)3P =C(CH2)2
A. Schier (1982)
10.1021/JA00797A034
Preparation of cyclopropyldiphenylsulfonium and 2-methylcyclopropyldiphenylsulfonium fluoroborate and their ylides. Stereochemistry of sulfur ylides
B. Trost (1973)
10.1016/S0022-328X(00)81750-7
Transition metal complexes of hexaphenylcarbodiphosphorane
W. C. Kaska (1973)
10.1002/ANGE.19650772208
Bildung von Yliden bei der thermischen Zersetzung vor Triphenyl‐α‐alkoxycarbonylalkyl‐phosphoniumsalzen
H. Bestmann (1965)
10.1002/chem.200701390
Divalent carbon(0) chemistry, part 1: Parent compounds.
R. Tonner (2008)
10.1002/1521-3765(20011217)7:24<5382::AID-CHEM5382>3.0.CO;2-Y
Synthesis, spectroscopic, and structural properties of spirocyclopropanated bicyclobutylidenes and their radical cations.
A. de Meijere (2001)
10.1016/0022-2852(86)90239-0
The infrared spectrum of carbon suboxide in the ν6 fundamental region: Experimental observation and semirigid bender analysis
P. Jensen (1986)
10.1021/JA00006A068
Synthesis and Structure of [{Ru(CO)2(Cp)}2(μ-C=C)]: An Ethynediyl Complex Formed during Tungsten-Catalyzed Alkyne Metathesis
G. Koutsantonis (1991)
10.1002/ANIE.199003181
Synthesis and Structure of the Novel μ2-Carbido Complex [(TPP)FeCRe(CO)4 Re(CO)5]†‡
W. Beck (1990)
10.1002/ANGE.19790910520
Neue Aspekte zum Strukturproblem der Carbodiphosphorane R3PCPR3
H. Schmidbaur (1979)
10.1002/CBER.19771101104
The Molecular Structure of Trimethyl(methylene)phosphorane in the Gas Phase, Determined by Electron Diffraction
E. Ebsworth (1977)
10.1021/JA00734A003
Structural effects of 3d orbitals in alkylidene phosphoranes
D. Boyd (1971)
10.1002/ANGE.19030161804
Über neue Fortschritte auf dem Gebiete der Metallvergoldung
Christian Göttig (1903)
10.1002/HLCA.19950780509
Kupfer(II)‐chlorid‐katalysierte ‘Carben‐Dimerisierung’ von 1‐Halogeno‐1‐Lithiocyclopropanen: Ein einfacher Zugang zu Bi(cyclopropylidenen)
T. Loosli (1995)
10.1002/ANGE.19941060506
Neuartige Kohlenstoffverbindungen mit „nackten”︁ Cn‐Einheiten
H. Lang (1994)
10.1002/CBER.19871201122
Notizen. Synthese eines unsymmetrischen Carbodiphosphorans durch Gerüstumlagerung einer Cyclopropyliden‐Vorstufe
H. Schmidbaur (1987)
10.1080/00268976900100951
A nuclear magnetic resonance study of spiropentane dissolved in a nematic solvent
A. D. Buckingham (1969)
10.1039/DT9720000617
Crystal structure of bis(triphenylphosphoranylidene)methane [hexaphenylcarbodiphosphorane, Ph3P:C:PPh3]
A. Vincent (1972)
10.1039/b708845k
A briefing on aurophilicity.
H. Schmidbaur (2008)
10.1021/OM900900U
Gold η2-Coordination to Unsaturated and Aromatic Hydrocarbons: The Key Step in Gold-Catalyzed Organic Transformations
H. Schmidbaur (2010)
10.1002/CBER.19811141019
Das Tetra(cyclopropyl phosphonium‐Kation und das Tri 9Cyclopropyl) phosphonium‐cyclopropylid
H. Schmidbaur (1981)
10.1002/ANIE.198005551
Ring‐Strained Carbodiphosphoranes
H. Schmidbaur (1980)
10.1038/192222A0
Eight-Co-Ordinate Diarsine Complexes of Quadrivalent Metal Halides
R. Clark (1961)
10.1021/JA00816A030
Interaction of phosphorus ylides with transition metal carbonyl compounds. Triphenylphosphinemethylene and bis(triphenylphosphine)carbon. Comparative chemistry
W. C. Kaska (1974)
10.1002/ANGE.19760881612
Die ambidenten Ligandeigenschaften des Bis(trimethylphosphoranyliden)methans
H. Schmidbaur (1976)
10.1002/chem.201101213
Distinguishing carbones from allenes by complexation to AuCl.
C. Esterhuysen (2011)
10.1039/P29830001209
Applications of potential energy calculations to organic chemistry. Part 17. Calculations of highly strained cyclopropane derivatives. Evaluation of several solar energy storage systems involving valence isomerization of cyclopropane rings
E. Ōsawa (1983)
Dust, Carbanion Chemistry
J.M.E. Buncel (2003)
Ostoja Starzewski: Transition Metal Complexes with Ylides in Ylides and Imines of Phosphorus
K.A.W.C. Kaska (1993)
Sulfur ylids
B. M. Trost (1975)
10.1016/S0009-2614(00)00237-2
An ab initio study on the equilibrium structure and CCC bending energy levels of carbon suboxide
J. Koput (2000)
10.1002/ANGE.201103197
Synthese, Struktur und Reaktivität eines Dihydridoboreniumkations†
B. Inés (2011)
10.1021/CR00095A003
Synthesis and chemistry of cubanes
G. Griffin (1989)
10.1021/JO00925A010
General synthetic route to cycloalkylidenecycloalkanes. Reactions of .alpha.-anions of cycloalkanecarboxylic acid salts with cycloalkanones
A. Krapcho (1974)
10.1002/CBER.19771101106
An Electron Diffraction Determination of the Molecular Structure of Hexamethylcarbodiphosphorane in the Gas Phase
E. Ebsworth (1977)
10.1021/ja00436a030
Nuclear magnetic resonance studies. 5. Properties of phosphorus-carbon ylides
T. A. Albright (1976)
10.1002/CBER.19831161106
Carbodiphosphorane isomers based on a 1,3-diphosphaindane skeleton, and their precursors
G. A. Bowmaker (1983)



This paper is referenced by
10.1007/430_2017_18
Reactivity and Applications of α-Metalated Ylides
V. H. Gessner (2017)
10.1021/jacs.5b02203
Cyclic bent allene hydrido-carbonyl complexes of ruthenium: highly active catalysts for hydrogenation of olefins.
Conor Pranckevicius (2015)
10.1021/acs.inorgchem.7b00099
Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties
Lennart T. Scharf (2017)
10.1002/anie.201702858
Donor-Stabilized Silylene/Phosphine-Supported Carbon(0) Center with High Electron Density.
Thibault Troadec (2017)
10.1007/430_2015_206
The Covalent Bond Classification Method and Its Application to Compounds That Feature 3-Center 2-Electron Bonds
M. Green (2016)
10.1002/chem.201502166
Synthesis, Structure, and Reactivities of Iminosulfane- and Phosphane-Stabilized Carbones Exhibiting Four-Electron Donor Ability.
Tomohito Morosaki (2015)
10.1007/430_2017_19
Synthesis, Structure, and Reactivity of Carbodiphosphoranes, Carbodicarbenes, and Related Species
Manuel Alcarazo (2017)
10.1002/chem.201700863
Synthesis, Electronic Structure, and Reactivities of Two-Sulfur-Stabilized Carbones Exhibiting Four-Electron Donor Ability.
Tomohito Morosaki (2017)
10.1021/ACS.ORGANOMET.6B00452
Syntheses and Structural Characterization of Mono-, Di-, and Tetranuclear Silver Carbone Complexes
Tomohito Morosaki (2016)
10.1021/acs.inorgchem.7b00381
Flexibility of the Carbodiphosphorane, (Ph3P)2C: Structural Characterization of a Linear Form.
Patrick J. Quinlivan (2017)
10.1039/d0dt00941e
Bulky 1,1'-bisphosphanoferrocenes and their coordination behaviour towards Cu(i).
Subhayan Dey (2020)
10.1002/chem.201302715
Recent advances in the field of main-group mono- and diatomic "allotropes" stabilised by neutral ligands.
David J D Wilson (2013)
10.1039/c6cc02747d
Zwitterionic phosphonium ligands: synthesis, characterization and application in telomerization of 1,3-butadiene.
A. Pews-Davtyan (2016)
10.1002/chem.201805421
Isolation of the Metalated Ylides [Ph3P−C−CN]M (M=Li, Na, K): Influence of the Metal Ion on the Structure and Bonding Situation
Christopher M. Schwarz (2019)
10.1039/c9dt00678h
Reactivity of the carbodiphosphorane, (Ph3P)2C, towards main group metal alkyl compounds: coordination and cyclometalation.
Patrick J. Quinlivan (2019)
10.1039/c7cc02525d
An unexpected rearrangement of pyrazolium halides based on N-N bond cleavage: synthesis of 1,2-dihydropyrimidines.
Qian Chen (2017)
10.1021/ACSCATAL.6B00587
BH3 Activation by Phosphorus-Stabilized Geminal Dianions: Synthesis of Ambiphilic Organoborane, DFT Studies, and Catalytic CO2 Reduction into Methanol Derivatives
Mathieu Lafage (2016)
10.1002/anie.201311022
Dative bonds in main-group compounds: a case for more arrows!
G. Frenking (2014)
10.2147/RTC.S87013
N -heterocyclic carbone: computational prediction of a divalent carbon (0) compound
Ankur Kanti Guha (2015)
10.1002/cphc.201800453
Boron Centres Allow Design, Control and Systematic Tuning of Neutral Homoaromatics for Functionalization Purposes.
James D. Mattock (2018)
10.1002/chem.201705812
The Pentagonal‐Pyramidal Hexamethylbenzene Dication: Many Shades of Coordination Chemistry at Carbon
Johannes E M N Klein (2018)
10.1002/chem.201501948
Identification of a Lead Candidate in the Search for Carbene-Stabilised Homoaromatics.
James D. Mattock (2015)
10.1021/ACS.ORGANOMET.6B00700
Carbon(0)-Bridged Pt/Ag Dinuclear and Tetranuclear Complexes Based on a Cyclometalated Pincer Carbodiphosphorane Platform
K. Kubo (2017)
10.1039/c5cs00672d
Reactive p-block cations stabilized by weakly coordinating anions
Tobias A. Engesser (2016)
10.1002/anie.201300461
Dative bonds in main-group compounds: a case for fewer arrows!
D. Himmel (2014)
10.1007/430_2015_210
Structure and Bonding Patterns in Large Molecular Ligated Metal Clusters
J. Saillard (2016)
Selective Hydrogen Bonding as a Driving Force for Nanoparticle Self-assembly
Haoyun Zhang (2019)
10.1002/ANGE.201300461
Dative Bindungen bei Hauptgruppenelementverbindungen: ein Plädoyer für weniger Pfeile
D. Himmel (2014)
10.1016/J.MOLSTRUC.2018.02.095
Pseudo-conformer models for linear molecules: Joint treatment of spectroscopic, electron diffraction and ab initio data for the C 3 O 2 molecule
Yury I. Tarasov (2018)
10.1021/ic401817g
Relationship between gallium pyramidalization in L·GaCl3 complexes and the electronic ligand properties.
Ahmad El‐Hellani (2013)
10.1002/ejic.201800179
2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry: 2-Phospha- and 2-Arsaethynolates - Versatile Building Blocks in Modern Synthetic Chemistry
L. Weber (2018)
10.1039/c9dt01784d
Hexaphenyl carbodiphosphorane adducts of heavier group 15 element trichlorides: syntheses, properties and reactivities.
Jörn E Münzer (2019)
See more
Semantic Scholar Logo Some data provided by SemanticScholar