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Extended Fluorochromism Of Anthracene Trimers With A Meta-substituted Triphenylamine Or Triphenylphosphine Core.

Zhiou Li, Hiromi Ishizuka, Y. Sei, M. Akita, M. Yoshizawa
Published 2012 · Chemistry, Medicine

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Combining meta-triphenylamine or triphenylphosphine with three anthracene fluorophores gives rise to fluorescent non-planar triskelions 1 and 2. The emissive properties of 1 are highly solvatochromic, yielding blue to pale green and even pale yellow fluorescence, whereas the blue emission of 2 is solvent-insensitive. Anthracene trimers 1 and 2 are both emissive in the solid state, displaying yellow and pale green fluorescence, respectively, with moderate quantum yields.
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