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A Nano-fibrillated Mesoporous Carbon As An Effective Support For Palladium Nanoparticles In The Aerobic Oxidation Of Alcohols "on Pure Water".

Babak Karimi, Hesam Behzadnia, Mihnea Bostina, H. Vali
Published 2012 · Chemistry, Medicine

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A novel nano-fibrillated mesoporous carbon (IFMC) was successfully prepared via carbonization of the ionic liquid 1-methyl-3-phenethyl-1H-imidazolium hydrogen sulfate (1) in the presence of SBA-15. The material was shown to be an efficient and unique support for the palladium nanoparticle (PdNP) catalyst Pd@IFMC (2) in aerobic oxidation of heterocyclic, benzylic, and heteroatom containing alcohols on pure water at temperatures as low as 40 °C for the first time and giving almost consistent activities and selectivities within more than six reaction runs. The catalyst has also been employed as an effective catalyst for the selective oxidation of aliphatic and allylic alcohols at 70-80 °C. The materials were characterized by X-ray photoelectron spectroscopy (XPS), N(2) adsorption-desorption analysis, transmission electron microscopy (TEM), and electron tomography (ET). Our compelling XPS and ET studies showed that higher activity of 2 compared to Pd@CMK-3 and Pd/C in the aerobic oxidation of alcohols on water might be due to the presence of nitrogen functionalities inside the carbon structure and also the fibrous nature of our materials. The presence of a nitrogen heteroatom in the carboneous framework might also be responsible for the relatively uniform and nearly atomic-scale distribution of PdNPs throughout the mesoporous structure and the inhibition of Pd agglomeration during the reaction, resulting in high durability, high stability, and recycling characteristics of 2. This effect was clearly confirmed by comparing the TEM images of the recovered 2 and Pd@CMK-3.
This paper references
Handbook of X-Ray Photoelectron Spectroscopy
J. Moulder (1992)
10.1002/ANIE.200300593
Endo- and exotemplating to create high-surface-area inorganic materials.
F. Schüth (2003)
10.1016/J.CATTOD.2006.11.007
Oxidation of primary alcohols with air on carbon-supported platinum catalysts for the synthesis of aldehydes or acids
P. Korovchenko (2007)
B ckvall, Modern Oxidation Methods, Wiley-VCH, Weinheim
a J.-E (2004)
10.1039/B412747C
Spherical carbon capsules with hollow macroporous core and mesoporous shell structures as a highly efficient catalyst support in the direct methanol fuel cell.
G. S. Chai (2004)
10.1039/b908451g
A simple and efficient oxidation of alcohols with ruthenium on carbon.
S. Mori (2009)
10.1021/CM031095H
Synthesis of Polyacrylonitrile-Based Ordered Mesoporous Carbon with Tunable Pore Structures
A. Lu (2004)
10.1021/CM102187A
Decoration, Migration, and Aggregation of Palladium Nanoparticles on Graphene Sheets
Z. Jin (2010)
10.1002/ADFM.200601230
Sulfur‐Functionalized Mesoporous Carbon
Y. Shin (2007)
10.1021/ja900686d
Facile ionothermal synthesis of microporous and mesoporous carbons from task specific ionic liquids.
J. S. Lee (2009)
10.1002/ANIE.200390076
Catalytic oxidation of alcohols in water under atmospheric oxygen by use of an amphiphilic resin-dispersion of a nanopalladium catalyst.
Y. Uozumi (2003)
Microporous Mesoporous Mater
A. B. Fuertes (2004)
10.1002/ANGE.200300593
Endo‐ und Exotemplate zur Erzeugung von anorganischen Materialien mit großer spezifischer Oberfläche
F. Schüth (2003)
10.1002/adma.200900965
Ionic liquids as precursors for nitrogen-doped graphitic carbon.
J. Paraknowitsch (2010)
10.1038/359710A0
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
C. Kresge (1992)
10.1016/J.JCAT.2004.01.010
Structure sensitivity and kinetics of d-glucose oxidation to d-gluconic acid over carbon-supported gold catalysts
Y. Önal (2004)
10.1021/CM049164V
Facile Template Synthesis of Ordered Mesoporous Carbon with Polypyrrole as Carbon Precursor
Chia-Min Yang (2005)
10.1039/B610862H
Water-soluble diruthenium complexes bearing acetate and carbonate bridges: highly efficient catalysts for aerobic oxidation of alcohols in water.
N. Komiya (2006)
10.1039/B805824E
Aerobic oxidation of alcohols using various types of immobilized palladium catalyst: the synergistic role of functionalized ligands, morphology of support, and solvent in generating and stabilizing nanoparticles
B. Karimi (2009)
10.1002/ANIE.200504359
Highly efficient aerobic oxidation of alcohols using a recoverable catalyst: the role of mesoporous channels of SBA-15 in stabilizing palladium nanoparticles.
Babak Karimi (2006)
10.1016/J.CARBON.2007.05.004
Nitrogen-containing carbon spheres with very large uniform mesopores: The superior electrode materials for EDLC in organic electrolyte
W. Li (2007)
10.1002/adma.200903403
Fluidic carbon precursors for formation of functional carbon under ambient pressure based on ionic liquids.
J. S. Lee (2010)
10.1021/JA002261E
Synthesis of New, Nanoporous Carbon with Hexagonally Ordered Mesostructure
S. Jun (2000)
10.1016/J.APCATA.2007.12.004
p-Aminophenol synthesis in an organic/aqueous system using Pt supported on mesoporous carbons
Kyung-Il Min (2008)
10.1021/JA052161E
Size-specific catalytic activity of polymer-stabilized gold nanoclusters for aerobic alcohol oxidation in water.
H. Tsunoyama (2005)
10.1021/CM070278R
Sulfonated Ordered Mesoporous Carbon as a Stable and Highly Active Protonic Acid Catalyst
Xiqing Wang (2007)
10.1002/ANIE.200603900
A nanoplatinum catalyst for aerobic oxidation of alcohols in water.
Y. Yamada (2007)
10.1016/J.MOLCATA.2003.10.044
Enantioselective hydrogenations with highly mesoporous carbon supported Pd catalysts
E. Sipos (2004)
10.1002/ADMA.200501576
Recent Progress in the Synthesis of Porous Carbon Materials
J. Lee (2006)
10.1002/ADFM.200700067
Sandwiched ruthenium/carbon nanostructures for highly active heterogeneous hydrogenation
F. Su (2007)
10.1021/la9027755
Functionalized poly(ethylene glycol)-stabilized water-soluble palladium nanoparticles: property/activity relationship for the aerobic alcohol oxidation in water.
Bo Feng (2010)
10.1002/3527603689
Modern Oxidation Methods: BAECKVALL:MOD.OXIDAT.METH O-BK
Jan-Erling Bäckvall (2004)
10.1039/b803912g
An efficient and reusable carbon-supported platinum catalyst for aerobic oxidation of alcohols in water.
Y. H. Ng (2008)
10.1021/CM070657K
Three-Dimensional Cage Type Mesoporous CN-Based Hybrid Material with Very High Surface Area and Pore Volume
A. Vinu (2007)
For more recent leading references on aerobic oxidation of alcohols
N. Komiya (2003)
10.1007/s11244-006-0020-y
New approaches to designing selective oxidation catalysts: Au/C a versatile catalyst
G. Hutchings (2006)
10.1021/CR0200116
Oxidation of alcohols with molecular oxygen on solid catalysts.
T. Mallát (2004)
10.1021/ja108039j
Efficient metal-free oxygen reduction in alkaline medium on high-surface-area mesoporous nitrogen-doped carbons made from ionic liquids and nucleobases.
Wen Yang (2011)
10.1021/JA00053A020
A new family of mesoporous molecular sieves prepared with liquid crystal templates
J. S. Beck (1992)
10.1016/J.MICROMESO.2003.11.012
Synthesis of ordered nanoporous carbons of tunable mesopore size by templating SBA-15 silica materials
A. Fuertes (2004)
B ckvall, Modern Oxidation Methods, Wiley-VCH, Weinheim
a J.-E (2004)
10.1016/s1351-4180(05)00822-6
Modern oxidation methods
Jan-Erling Bäckvall (2010)
10.1039/B703569A
Aminated hydrophilic ordered mesoporous carbons
Maria-Magdalena Titirici (2007)
10.1126/SCIENCE.279.5350.548
Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores
Y Zhao (1998)
10.1021/JA0488683
Hydroxyapatite-supported palladium nanoclusters: a highly active heterogeneous catalyst for selective oxidation of alcohols by use of molecular oxygen.
K. Mori (2004)
10.1039/B205708P
Porous materials via nanocasting procedures: innovative materials and learning about soft-matter organization.
S. Polarz (2002)
10.1021/JP991673A
Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation
R. Ryoo (1999)
10.1039/B613834A
Molecular level dispersed Pd clusters in the carbon walls of ordered mesoporous carbon as a highly selective alcohol oxidation catalyst.
A. Lu (2007)
10.1016/0920-5861(94)80187-8
Oxidation of alcohols with molecular oxygen on platinum metal catalysts in aqueous solutions
T. Mallát (1994)
10.1039/B815948C
Applications of a high performance platinum nanocatalyst for the oxidation of alcohols in water
Prasenjit Maity (2009)
10.1039/B821586C
Basic metal carbonate supported gold nanoparticles: enhanced performance in aerobic alcohol oxidation
J. Yang (2009)
10.1038/35084046
Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles
S. Joo (2001)
10.1021/JP072246X
Synthesis of Graphitic Carbon Nanostructures from Sawdust and Their Application as Electrocatalyst Supports
M. Sevilla (2007)
10.1002/anie.200705347
Highly efficient organic reactions "on water", "in water", and both.
Nelly Shapiro (2008)
10.1039/b209344h
A convenient palladium-catalyzed aerobic oxidation of alcohols at room temperature.
Mitchell J. Schultz (2002)
10.1126/SCIENCE.287.5458.1636
Green, catalytic oxidation of alcohols in water
ten Brink GJ (2000)
10.1016/S0926-860X(96)00252-9
Modification of supported Pt catalysts by preadsorbed phosphines: enhanced selectivity in the oxidation ofl-sorbose
T. Mallát (1997)



This paper is referenced by
10.1021/ACSCATAL.5B00237
Palladium Nanoparticles Supported in the Nanospaces of Imidazolium-Based Bifunctional PMOs: The Role of Plugs in Selectivity Changeover in Aerobic Oxidation of Alcohols
B. Karimi (2015)
10.1021/am5001757
Mesoporous polyoxometalate-based ionic hybrid as a triphasic catalyst for oxidation of benzyl alcohol with H(2)O(2) on water.
G. Chen (2014)
10.1039/C5NJ00451A
Ionic liquid-derived nano-fibrillated mesoporous carbon based on solid-phase microextraction fiber for the analysis of volatile organic compounds from aqueous solutions
M. Abolghasemi (2015)
10.1016/J.ELECTACTA.2018.02.158
Stabilization of 4-phenylurazole by electrografting on a nano-fibrillated mesoporous carbon modified electrode. Reactivity of anchored triazolinedione groups against Michael-type addition at electrode/electrolyte interface
F. Varmaghani (2018)
10.1039/c8cc00475g
Au-Pd bimetallic nanoparticles supported on a high nitrogen-rich ordered mesoporous carbon as an efficient catalyst for room temperature Ullmann coupling of aryl chlorides in aqueous media.
B. Karimi (2018)
10.1021/acsomega.8b02382
Facile Synthesis of Magnetically Recoverable Pd and Ru Catalysts for 4-Nitrophenol Reduction: Identifying Key Factors
Lennon Gregor (2018)
10.1038/s41598-020-59003-5
Preparation of palladated porous nitrogen-doped carbon using halloysite as porogen: disclosing its utility as a hydrogenation catalyst
S. Sadjadi (2020)
10.1007/s10008-014-2490-3
High-performance supercapacitors based on an ionic liquid-derived nanofibrillated mesoporous carbon
S. Kazemi (2014)
10.1039/c9ra10941b
Palladium supported on a novel ordered mesoporous polypyrrole/carbon nanocomposite as a powerful heterogeneous catalyst for the aerobic oxidation of alcohols to carboxylic acids and ketones on water
N. Ganji (2020)
10.4018/978-1-4666-9975-5.CH011
Catalysis with Room Temperature Ionic Liquids Mediated Metal Nanoparticles
Y. Deng (2016)
10.1007/s13738-017-1237-3
Heteropolyacid immobilized on polymer/magnetic zeolite nanocomposite as a new and recyclable catalyst for the selective oxidation of alcohols
M. Maleki (2017)
10.1039/C5RA16923B
Manganese dioxide nanoparticles incorporated within ionic liquid derived fibrillated mesoporous carbon: electrode material for high-performance supercapacitors
S. Kazemi (2015)
10.1002/cctc.201300893
Palladium on Ionic Liquid Derived Nanofibrillated Mesoporous Carbon: A Recyclable Catalyst for the Ullmann Homocoupling Reactions of Aryl Halides in Water
B. Karimi (2014)
10.1039/C2RA22829G
Development of a multifunctional catalyst for a “relay” reaction
A. Ganai (2013)
10.1002/aoc.5384
Cost‐effective bio‐derived mesoporous carbon nanoparticles‐supported palladium catalyst for nitroarene reduction and Suzuki–Miyaura coupling by microwave approach
S Supriya (2020)
10.1002/chem.201202698
Conjugate addition versus cycloaddition/condensation of nitro compounds in water: selectivity, acid-base catalysis, and induction period.
Luca Guideri (2013)
10.1021/acsami.5b03985
Novel Ordered Mesoporous Carbon Based Sulfonic Acid as an Efficient Catalyst in the Selective Dehydration of Fructose into 5-HMF: the Role of Solvent and Surface Chemistry.
B. Karimi (2015)
10.1039/c4mh00141a
Carbon materialization of ionic liquids
S. Zhang (2015)
10.1039/C3GC40110C
Aqueous oxidation of alcohols catalysed by recoverable iron oxide nanoparticles supported on aluminosilicates
F. Rajabi (2013)
10.3390/catal10040374
Highly Dispersed Pt Nanoparticles on N-Doped Ordered Mesoporous Carbon as Effective Catalysts for Selective Hydrogenation of Nitroarenes
S. Yao (2020)
10.1039/C9RA00230H
Three-dimensional N-doped graphene aerogel-supported Pd nanoparticles as efficient catalysts for solvent-free oxidation of benzyl alcohol
Qiuli Wei (2019)
10.1002/chem.201300825
Molecular-level understanding of the carbonisation of polysaccharides.
P. Shuttleworth (2013)
10.1021/am5067223
Fabrication of magnetically recoverable catalysts based on mixtures of Pd and iron oxide nanoparticles for hydrogenation of alkyne alcohols.
Rosemary Easterday (2014)
10.1039/C4RA14947E
Aerobic flow oxidation of alcohols in water catalyzed by platinum nanoparticles dispersed in an amphiphilic polymer
T. Osako (2015)
10.1021/acsami.6b07909
Synthesis of Spherical Carbon Nitride-Based Polymer Composites by Continuous Aerosol-Photopolymerization with Efficient Light Harvesting.
Jalal Poostforooshan (2016)
10.1016/J.ELECTACTA.2013.06.100
Facile-green synthesis of nitrogen-doped carbon-supported ultrafine silver catalyst with enhanced electrocatalytic property
Y. Wang (2013)
10.1016/J.APCATA.2017.05.036
Palladium Nanoparticles Supported on Mesoporous Carbon Nitride for Efficiently Selective Oxidation of Benzyl Alcohol with Molecular Oxygen
J. Xu (2017)
10.1016/J.APCATA.2018.07.009
Magnetic crosslinked copoly(ionic liquid) nanohydrogel supported palladium nanoparticles as efficient catalysts for the selective aerobic oxidation of alcohols
M. Gholinejad (2018)
10.1002/9783527693030.CH2
Functionalized Ionic Liquid‐based Catalytic Systems with Diversified Performance Enhancements
S. Zhang (2018)
10.1002/CHIN.201245040
A Nano-Fibrillated Mesoporous Carbon as an Effective Support for Palladium Nanoparticles in the Aerobic Oxidation of Alcohols “on Pure Water”.
B. Karimi (2012)
10.1002/ELAN.201400266
Electrochemical Behavior of Glucose Oxidase Immobilized on Pd-Nanoparticles Decorated Ionic Liquid Derived Fibrillated Mesoporous Carbon
B. Haghighi (2014)
10.1016/J.MICROMESO.2018.02.037
Nanofiber-like mesoporous alumina supported palladium nanoparticles as a highly active catalyst for base-free oxidation of benzyl alcohol
Lijuan Chen (2018)
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