Electroanalytical Determination Of Some Phenolic Acids By High‐Performance Liquid Chromatography At Gold Electrodes
I. G. Casella, C. Colonna, M. Contursi
Published 2007 · Chemistry
Download PDFAnalyze on Scholarcy
The electrochemical and amperometric behavior of a gold electrode was investigated towards the oxidation of several common phenolic acids in neutral phosphate solutions. Au electrodes show an appreciable stability and reproducibility of the amperometric signals by using a constant applied potential of 1.0 V vs. Ag/AgCl. Separations of selected phenolic acids using a reverse phase C18 analytical column with a mobile phase containing 10 mM NaH2PO4 plus 10 mM Na2HPO4 (pH 7) and methanol as organic modifier, are achieved isocratically in less than 30 min. The detection limits at the level of nmol/L and linear ranges of four-five orders of magnitude are generally achieved. The proposed chromatographic strategy coupled with the electrochemical detection at the Au electrode was successful tested for the quantitative determination of phenolic acids in beer, red wine and brandy with good sensitivity and recovery.
This paper references
Separation and determination of organic acids and phenolic compounds in fruit juices and drinks by high-performance liquid chromatography.
Guanghou Shui (2002)
Determination of hydroxycinnamic acids and volatile phenols in wort and beer by isocratic high-performance liquid chromatography using electrochemical detection.
N. Vanbeneden (2006)
Determination of phenolic acids in fruit juices by isocratic column liquid chromatography.
Y. Amakura (2000)
Pulsed amperometric detection of carbohydrates, amines and sulfur species in ion chromatography —the current state of research
D. C. Johnson (1993)
Determination of free phenolic acids in wort and beer by coulometric array detection.
S. Floridi (2003)
Determination of phenolic constituents of biological interest in red wine by capillary electrophoresis with electrochemical detection.
Y. Peng (2004)
Microwave-accelerated derivatization processes for the determination of phenolic acids by gas chromatography-mass spectrometry.
T. Chu (2001)
Determination of some pharmacologically active phenolic acids in juices by high-performance liquid chromatography.
S. Shahrzad (1996)
Analysis of flavonoids and other phenolic compounds using high-performance liquid chromatography with coulometric array detection: relationship to antioxidant activity.
K. Aaby (2004)
Validated application of a new high-performance liquid chromatographic method for the determination of selected flavonoids and phenolic acids in human plasma using electrochemical detection.
Adrian Bolarinwa (2005)
Oxidation of caffeic acid and related hydroxycinnamic acids
P. Hapiot (1996)
Gas chromatographic-mass spectrometric analysis of acids and phenols in distilled alcohol beverages. Application of anion-exchange disk extraction combined with in-vial elution and silylation.
L. Ng (2000)
Antimutagenic effects of natural phenolic compounds in beans.
E. D. de Mejia (1999)
Analysis of old brandy and oak extracts by capillary electrophoresis
M. Bronze (1997)
Separation of phenolic compounds by high-performance liquid chromatography with absorbance and fluorimetric detection.
M. A. Rodríguez-Delgado (2001)
Capillary electrophoretic separation of phenolic acids
G. Cartoni (1995)
Determination of free and bound phenolic acids in beer
M. Nardini (2004)
Comparative investigation of UV, electrochemical and particle beam mass spectrometric detection for the high-performance liquid chromatographic determination of benzoic and cinnamic acids and of their corresponding phenolic acids
C. Bocchi (1996)
Assessment of potential prooxidant and antioxidant actions
O. Aruoma (1996)
Pulsed Electrochemical Detection in High-Performance Liquid Chromatography
W. Lacourse (1997)
Phenolic acids in foods: an overview of analytical methodology.
R. Robbins (2003)
Inhibitory effect of curcumin, chlorogenic acid, caffeic acid, and ferulic acid on tumor promotion in mouse skin by 12-O-tetradecanoylphorbol-13-acetate.
M. Huang (1988)
Carbohydrate analyses with high-performance anion-exchange chromatography
Y. Lee (1996)
Evaluation of the antioxidant properties of free and bound phenolic acids from native and malted finger millet (ragi, Eleusine coracana Indaf-15).
M. V. S. Subba Rao (2002)
Determination of phenolic acids and flavonoids of apple and pear by high-performance liquid chromatography.
A. Schieber (2001)
Determination of Phenolic Acids and Flavones in Lonicera japonica Thumb. by Capillary Electrophoresis with Electrochemical Detection
Y. Peng (2005)
This paper is referenced by
Improving Detection Selectivity: MC-CE Device Integrated with Dual Opposite Carbon-Fiber Microdisk Electrodes Detection for Determining Polyphenols in Wine
Fuyou Du (2015)
Electrochemical Sensor Based on Carbon Nanotubes for the Simultaneous Detection of Phenolic Pollutants
M. Govindhan (2015)
Electrochemical sensor based on rhodium nanoparticles stabilized in zwitterionic surfactant for p-coumaric acid analysis
Larissa Moreira Ferreira (2017)
Determination of Phenolic Antioxidants in Amazonian Medicinal Plants by HPLC with Pulsed Amperometric Detection
G. D. da Silveira (2015)
Determination of tetracycline residues by liquid chromatography coupled with electrochemical detection and solid phase extraction.
Innocenzo Giuseppe Casella (2009)
Point-of-use electroanalytical platform based on homemade potentiostat and smartphone for multivariate data processing
Gabriela Furlan Giordano (2016)
Electrochemical detection of estrus specific phenolic compound p-cresol to assess the reproductive phase of certain farm animals
N. Sudhan (2017)
Enhancing Detection Versatility: MC-CE Device with Serial Dual-electrode Detection for Determinating Glutathione Disulfide and Glutathione in Pharmaceutical Supplement
Fuying Du (2015)
Electron transfer reactions of osmium(II) complexes with phenols and phenolic acids
Angusamy Rajeswari (2016)
HPLC in natural product analysis: the detection issue.
J. Wolfender (2009)
Determination of caffeic acid in red wine by voltammetric method
Luiz Fernando da Silva (2008)
Pulsed Amperometric Detection of Pharmacologic Adulterants in Dietary Supplements using a Gold Electrode coupled to HPLC Separation
Diana Tomazi Muratt (2018)
Evaluation of phenolic antioxidant capacity in beverages based on laccase immobilized on screen-printed carbon electrode modified with graphene nanoplatelets and gold nanoparticles
Ivana Zrinski (2020)
Determination of Gallic acid by differential pulse polarography: Application to fruit juices
Ümmihan Taşkoparan Yilmaz (2013)
Chitosan Stabilized Gold Nanoparticle‐Modified Au Electrodes for the Determination of Polyphenol Index in Wines: a Preliminary Study
Antonella Curulli (2012)
Determination of caffeic acid in wine using PEDOT film modified electrode.
Claudio Bianchini (2014)
A novel Laccase Biosensor based on Laccase immobilized Graphene-Cellulose Microfiber Composite modified Screen-Printed Carbon Electrode for Sensitive Determination of Catechol
S. Palanisamy (2017)
A Simple and Rapid Estimation of Totals Polyphenols Based On Carbon Paste Electrode Modified with Ruthenium Oxo‐Complex
Paulo A. Raymundo-Pereira (2015)
Determination of Phenolic Acids in Sugarcane Vinasse by HPLC with Pulse Amperometry
Pedro Augusto V. de Freitas (2018)
Assessment of the Polyphenol Indices and Antioxidant Capacity for Beers and Wines Using a Tyrosinase-Based Biosensor Prepared by Sinusoidal Current Method
Juan José García-Guzmán (2019)
Chromatographic separations and liquid phase extraction/concentration of some polyphenolic compounds: a comparison between reverse phase and cation-exchange chromatography.
I. G. Casella (2011)
The role of electroanalytical techniques in analysis of polyphenols in wine
A. S. Arribas (2012)