Online citations, reference lists, and bibliographies.

Electrochemical Synthesis And In Situ Spectroelectrochemistry Of Conducting Polymer Nanocomposites. I. Polyaniline/TiO2, Polyaniline/ZnO, And Polyaniline/TiO2+ZnO

Jalal Arjomandi, Sahar Tadayyonfar
Published 2014 · Materials Science

Cite This
Download PDF
Analyze on Scholarcy
Share
The polyaniline (PAn), polyaniline/titanium dioxide (PAn/TiO2), polyaniline/zinc oxide (PAn/ZnO), and a novel conducting polymer nanocomposites, polyaniline/titanium dioxide + zinc oxide (PAn/TiO2+ZnO), were synthesized by in situ electropolymerization and potential cycling on gold electrode. The PAn and nanocomposite films were characterized by cyclic voltammetry, Fourier transform infra-red (FTIR) spectroscopy, in situ resistivity measurements, in situ UV–Visible, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The differences between cathodic and anodic peaks of three redox couples were obtained for PAn and polymeric nanocomposite films. During cathodic and anodic scans, the shift of potential was observed for polymer nanocomposite films. The characteristic FTIR peaks of PAn were found to shift to lower wavelengthsin polymer nanocomposite films. These observed effects have been attributed to interaction of TiO2, ZnO, and TiO2+ZnO particles with PAn molecular chains. Significant differences from in situ resistivity of PAn and nanocomposite films were obtained. The resistance of PAn/TiO2, PAn/ZnO, and PAn/TiO2+ZnO films were found to be smaller than the PAn film. The in situ UV–Visible spectra for Pan and polymer nanocomposite films were studied. The results show the intermediate spectroscopic properties between PAn and polymer nanocomposite films. The morphological analyses of PAn and nanocomposite films have been investigated. The nanocomposites SEM and TEM micrographs suggest that the inorganic semiconductor particles were incorporated in organic conducting polymer, which consequently modifies the morphology of the films significantly. POLYM. COMPOS., 35:351–363, 2014. © 2013 Society of Plastics Engineers
This paper references
10.1016/J.TSF.2008.01.017
Water-assisted self-assembly of polyaniline/Fe3O4 composite honeycomb structures film
Chunling Yu (2008)
10.1021/LA0495884
Reversible encapsulation of nanometer-size polyaniline and polyaniline-Au-nanoparticle composite in starch.
T. Sarma (2004)
10.1016/J.SYNTHMET.2006.03.001
In situ UV–vis spectroelectrochemical studies of the copolymerization of o-aminophenol and aniline
A. Shah (2006)
10.1016/j.bios.2008.06.025
Electrochemical synthesis of polyaniline nano-networks on p-aminobenzene sulfonic acid functionalized glassy carbon electrode Its use for the simultaneous determination of ascorbic acid and uric acid.
L. Zhang (2008)
10.1016/S0167-577X(00)00115-4
Studies on polyaniline and colloidal TiO2 composites
K. Gurunathan (2000)
10.1016/J.MATCHEMPHYS.2007.06.013
Enhanced photo-electric response of ZnO/polyaniline layer-by-layer self-assembled films
G. Paul (2007)
10.2478/s11532-008-0020-9
Electrochemical preparation and in situ characterization of poly(3-methylpyrrole) and poly(3-methylpyrrole-cyclodextrin) films on gold electrodes
Jalal Arjomandi (2008)
10.1016/J.JMMM.2007.02.195
Effect of ferrofluid concentration on electrical and magnetic properties of the Fe3O4/PANI nanocomposites
J. Alam (2007)
10.1016/J.SYNTHMET.2008.10.010
Synthesis and characterization of polyaniline–ZnO composite and its dielectric behavior
B. Sharma (2009)
10.1002/pat.1317
UV‐curing synthesis of sulfonated polyaniline‐silver nanocomposites by an in situ reduction method
Mohammad Rezaul Karim (2009)
10.1016/J.REACTFUNCTPOLYM.2008.08.006
Electrocatalytic thin films based on nordihydroguaiaretic acid-functionalyzed polyaniline
G. Milczarek (2008)
10.1016/J.MOLCATB.2008.01.011
Immobilization of d-hydantoinase in polyaniline
Juliano M. Andrade (2008)
10.1039/B511429B
Electrical properties of inorganic nanowire–polymer composites
S. Vivekchand (2005)
10.1002/MARC.200700495
Room Temperature Bulk Synthesis of Silver Nanocables Wrapped with Polypyrrole
M. Nadagouda (2007)
10.1016/J.CERAMINT.2006.01.009
Luminescence of nanosized ZnO/polyaniline films prepared by self-assembly
J. Zhang (2007)
10.1016/J.PHYSLETA.2006.09.025
Optical and electrical characterization of polyaniline–silicon dioxide nanocomposite
K. Dutta (2007)
10.1016/J.MATCHEMPHYS.2008.09.035
Performance of polyaniline/multi-walled carbon nanotubes composites as cathode for rechargeable lithium batteries
B. He (2009)
10.1016/0379-6779(93)90279-6
Structure-property relationships in polyaniline derivatives
M. Leclerc (1993)
10.1016/S0379-6779(97)80658-3
Polyaniline and polypyrrole: Where are we headed?
A. G. Macdiarmid (1997)
10.1021/JP066413P
On the origin of the so-called nucleation loop during electropolymerization of conducting polymers.
J. Heinze (2007)
10.1002/PC.22408
Synthesis and characterization of electropolymerized molecularly imprinted microporous polyaniline films for solar cell applications
Waleed E. Mahmoud (2013)
10.1021/cr900226k
Electrochemistry of conducting polymers--persistent models and new concepts.
J. Heinze (2010)
10.1088/0022-3727/42/15/155502
A novel photodiode made of hybrid organic/inorganic nanocomposite
Waleed E. Mahmoud (2009)
10.1016/J.POLYMDEGRADSTAB.2006.01.002
Preparation of PANI–TiO2 nanocomposites and their solid-phase photocatalytic degradation
L. Zhang (2006)
10.1038/357477A0
Flexible light-emitting diodes made from soluble conducting polymers
G. Gustafsson (1992)
10.1016/0379-6779(87)90083-X
Spectroscopic studies of polyaniline
D. Bloor (1987)
10.1016/J.SYNTHMET.2007.03.001
Preparation of TiO2/PANI composites in the presence of surfactants and investigation of electrical properties
A. G. Yavuz (2007)
10.1002/BBPC.19961000804
Spectroelectrochemical investigations of polyxylidines
M. Probst (1996)
10.1016/J.APSUSC.2004.11.061
A novel emulsion route to sub-micrometer polyaniline/nano-ZnO composite fibers
Y. He (2005)
10.1021/CM00041A018
Thermochemistry and Kinetics of Chemical Polymerization of Aniline Determined by Solution Calorimetry
Yueping Fu (1994)
10.1016/J.COLSURFA.2011.05.030
Adsorption kinetics of methyl violet onto TiO2 nanoparticles with different phases
Sh. Jafari (2011)
10.1016/0379-6779(90)90072-S
A method for electrochemical in situ conductivity measurements of electrochemically synthesized intrinsically conducting polymers
R. Holze (1990)
10.1016/J.CARBON.2008.07.028
Preparation of polyaniline/multiwalled carbon nanotube composite by novel electrophoretic route
C. Dhand (2008)
10.1016/J.CORSCI.2008.10.028
Corrosion characteristics of polyaniline-coated 316L stainless steel in sulphuric acid containing fluoride
Dat Phat Le (2009)
10.1007/s10008-013-2114-3
A spectroelectrochemical study of conducting pyrrole-N-methylpyrrole copolymers in nonaqueous solution
Jalal Arjomandi (2013)
10.1002/PAT.1591
Synthesis and properties of bismuth oxide nanoshell coated polyaniline nanoparticles for promising photovoltaic properties
Waleed E. Mahmoud (2011)
10.1016/j.polymer.2006.08.059
Hybrid composites of conductive polyaniline and nanocrystalline titanium oxide prepared via self-assembling and graft polymerization
Jing Li (2006)
10.1016/S0379-6779(02)00116-9
In situ UV–visible spectroelectrochemical studies on electrochromic behavior of poly(2,5-dimethoxy aniline)
Li-Ming Huang (2002)
10.1002/bbpc.198800336
The Polymerisation of Aniline and Methylsubstituted Derivatives: Electrochemical and Spectroscopic Investigations
A. Hochfeld (1988)
10.1016/J.ORGEL.2008.08.001
Polymer solar cells incorporating one-dimensional polyaniline nanotubes
M. Chang (2008)
10.1016/J.SNB.2004.09.027
CO gas sensing from ultrathin nano-composite conducting polymer film
M. Ram (2005)
10.1016/J.TCA.2005.05.020
SYNTHESIS; CHARACTERIZATION AND THERMAL ANALYSIS OF POLYANILINE (PANI)/Co3O4 COMPOSITES
S. Wang (2006)
10.1016/J.CAP.2007.10.022
Microwave absorption behaviors of polyaniline nanocomposites containing TiO2 nanoparticles
Sook Wai Phang (2008)
10.1016/S0379-6779(98)00106-4
Cyclic UV-Vis spectrovoltammetry of polyaniline
A. Malinauskas (1998)
10.1063/1.2740478
Nanocomposite Field Effect Transistors based on Zinc oxide/polymer blends
C. Che (2007)
10.1126/science.249.4973.1146
Thin Films of n-Si/Poly-(CH3)3Si-Cyclooctatetraene: Conducting-Polymer Solar Cells and Layered Structures
M. Sailor (1990)
10.1016/0022-0728(93)80230-F
Steric and electronic effects in methyl and methoxy substituted polyanilines
G. D'aprano (1993)
10.1016/J.SYNTHMET.2006.12.007
Synthesis of polyaniline/NiO nanobelts by a self-assembly process
G. Song (2007)
10.1016/J.JELECHEM.2005.01.014
Electrocatalytic behavior of Pt-modified polyaniline electrode for methanol oxidation: Effect of Pt deposition modes
L. Niu (2005)
10.1021/CM034292P
Preparation and Characterization of Novel Hybrid Materials Formed from (Ti,Sn)O2 Nanoparticles and Polyaniline
D. C. Schnitzler (2003)



This paper is referenced by
10.1007/s00396-018-4419-3
Polaron localization in polyaniline through methylene blue dye interaction for tuned charge transport and optical properties
Kamanashis Sarkar (2018)
10.1016/J.CATCOM.2018.03.009
γ-Al2O3 nanoparticle catalyst mediated polyaniline gold electrode biosensor for vitamin E
Mohammad Hadi Parvin (2018)
10.1002/PC.24091
Facile synthesis of magnetic polypyrrole composite nanofibers and their application in Cr(VI) removal
Xin Tuo (2018)
10.1016/J.ELECTACTA.2017.08.141
Spectroelectrochemistry and electrosynthesis of polypyrrole supercapacitor electrodes based on gamma aluminum oxide and gamma iron (III) oxide nanocomposites
Jalal Arjomandi (2017)
10.1016/J.PORGCOAT.2015.01.014
Nanocomposite film formations of polyaniline via TiO2, Ag, and Zn, and their corrosion protection properties
Murat Ates (2015)
10.1016/j.heliyon.2019.e01380
CoPtx/γ-Al2O3 bimetallic nanoalloys as promising catalysts for hydrazine electrooxidation
Naveeda Firdous (2019)
10.1016/J.MATCHEMPHYS.2019.121775
Fabrication of novel polycatechol/aminophenol/aluminum oxide ternary nanocomposite electrode and its electrocatalytic applications
Atefeh Mesbahi Jamshid (2019)
10.1016/J.JELECHEM.2017.12.086
Polyaniline/aluminum and iron oxide nanocomposites supercapacitor electrodes with high specific capacitance and surface area
Jalal Arjomandi (2018)
10.1002/PC.25088
Zinc ferrite @ polyindole nanocomposites: Synthesis, characterization and gas sensing applications
T. Anjitha (2019)
10.1149/2.0021511JES
Characterization, Electrosynthesis and In Situ Spectroelectro-Chemical Studies of Poly (p-nitroaniline-co-p-aminophenol) in Aqueous Media
Jalal Arjomandi (2015)
10.1002/APP.41526
Electrochemical synthesis and In situ spectroelectrochemistry of conducting NMPy‐TiO2 and ZnO polymer nanocomposites for Li secondary battery applications
Jalal Arjomandi (2015)
10.1039/C8NJ02767F
Fabrication of a novel electrochemical sensor for the determination of water in some organic solvents based on naphthalene conducting polymers
Safoura Bakhtiari Haft Lang (2018)
AC conductivity and Dielectric behavior of poly (o-phenylenediamine)/ZnO nanocomposites
Sharma Archana (2017)
10.1002/PC.24674
Synthesis and characterization of novel polyindole/metal oxide nanocomposites and its evaluation for lithium ion rechargeable battery applications
Jalal Arjomandi (2019)
10.1149/2.0781514JES
Conducting Copolymers of N-methylaniline and o-aminophenol: Electrosynthesis and In Situ Spectroelectrochemical Characterization
Jalal Arjomandi (2015)
10.1016/J.ELECTACTA.2015.10.129
Electrochemical synthesis, in situ spectroelectrochemistry of conducting indole-titanium dioxide and zinc oxide polymer nanocomposites for rechargeable batteries
Mohammad Hadi Parvin (2015)
10.1016/J.COCO.2016.07.001
Growth of ZnO nanorods on a preliminary crazed and seeded polyethylene films
I. F. Georgiu (2016)
10.1016/J.MATCHEMPHYS.2018.05.075
Surfactant-assisted titanium dioxide/graphene composite for enhanced conductivity
Lin Liu (2018)
Semantic Scholar Logo Some data provided by SemanticScholar