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Synthesis Of Poly(Vinyl Alcohol-Graft-Hyperbranched Glycerol)

P. King, E. Khosravi, O. M. Musa
Published 2017 · Chemistry

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We report the first example of grafting hyperbranched polyglycerol onto poly(vinyl alcohol) via ring-opening polymerisation of glycidol to prepare poly(vinyl alcohol-graft-hyperbranched glycerol) (P[(VA)-g-(hPG)]). The effects of catalyst, molecular weight of PVA, reaction temperature, water content, moles of reagent, and addition time of reagent were also investigated. P[(VA)-g-(hPG)] with various mole fractions of hPG were prepared and the degrees of substitution and branching were determined. P[(VA)-g-(hPG)] displayed decreased degree of crystallinity and also increased solubility in water, compared to PVA. P[(VA)-g-(hPG)] is shown to be a superior hair styling polymer with a curl retention value of 85% after 4 h. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017
This paper references
Polymer Data Handbook
J. Mark (2009)
Synthesis and characterization of isocyanate‐functionalized PVA‐based polymers with applications as new additives in lubricant formulations
Gabriel Á. Martos Moreno (2012)
Multi-arm star block copolymers based on ɛ-caprolactone with hyperbranched polyglycerol core
A. Burgath (2000)
Preparation and characterization of cationic poly vinyl alcohol with a low degree of substitution
P. Fatehi (2011)
Controlled branching of polyglycidol and formation of protein-glycidol bioconjugates via a graft-from approach with "PEG-like" arms.
Benjamin R. Spears (2013)
Controlled Synthesis of Hyperbranched Polyglycerols by Ring-Opening Multibranching Polymerization
A. Sunder (1999)
Linear-Hyperbranched Graft-Copolymers via Grafting-to Strategy Based on Hyperbranched Dendron Analogues and Reactive Ester Polymers
C. Schuell (2012)
Chemical modification of hydroxyl functions : Introduction of hydrolyzable ester function and bactericidal quaternary ammonium groups
F. Baudrion (1998)
Surface-initiated hyperbranched polyglycerol as an ultralow-fouling coating on glass, silicon, and porous silicon substrates.
Eli K Moore (2014)
Quantitative Poly(vinyl alcohol) Modification in Ionic Liquids: Esterification and Urethanation with Low Surface Tension Producing Reagents
S. A. Eastman (2010)
Hyperbranched polyglycerols: from the controlled synthesis of biocompatible polyether polyols to multipurpose applications.
D. Wilms (2010)
Biodegradation of poly(vinyl alcohol) based materials
E. Chiellini (2003)
Assessment of styling performance in hair gels and hair sprays by means of a new two-point stiffness test.
P. Hoessel (2010)
Effect of molecular architecture on single polymer adhesion.
S. Kienle (2014)
Multi‐Arm Star Polyglycerol‐block‐poly(tert‐butyl acrylate) and the Respective Multi‐Arm Poly(acrylic acid) Stars
Z. Shen (2006)
High-resolution solid-state carbon-13 NMR of poly(vinyl alcohol): enhancement of tacticity splitting by intramolecular hydrogen bonds
T. Terao (1983)
Synthesis of poly(glycerol)‐block‐poly(methyl acrylate) multi‐arm star polymers
Steffen Maier (2000)
Linear‐Hyperbranched Amphiphilic AB Diblock Copolymers Based on Polystyrene and Hyperbranched Polyglycerol
E. Barriau (2005)
Mulhaupt, Macromol
S. Maier (2000)
Controlled Synthesis of Linear Polymers with Highly Branched Side Chains by “Hypergrafting”: Poly(4-hydroxy styrene)-graft-hyperbranched Polyglycerol
C. Schuell (2012)

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