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Synthesis And Photochemical Transformations Of An Anthracene Containing Methacrylic Copolymer

C. Bratschkov, Pluma Karpuzova, K. Müllen, M. Klapper, I. Schopov
Published 2001 · Chemistry

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Summary : A new methacrylate monomer containing anthracene moiety connected with long flexible spacer was prepared and copolymerized with n-butyl methacrylate. It has been found that upon illumination in inert atmosphere photodimerization of the anthracene rings takes place to a considerable extend. The reverse decomposition of the photodimers by thermal treatment is also facilitated by the long flexible spacer. In ambient air the only photoreaction is endoperoxide formation.



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