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Hexavalent Chromium Reduction With Zero-Valent Iron (ZVI) In Aquatic Systems
Published 2011 · Chemistry
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Hexavalent chromium is a heavy metal used in a variety of industrial applications which is highly toxic to humans, animals, plants and microorganisms. Moreover, it is a well-established human carcinogen by the inhalation route of exposure and a possible human carcinogen by the oral route of exposure. Therefore, it should be removed from contaminated waters. Its reduction to trivalent chromium can be beneficial because a more mobile and more toxic chromium species is converted to a less mobile and less toxic form. During the last two decades, there has been important interest in using zero-valent iron (ZVI) as a Cr(VI)-reducing agent. A considerable volume of research has been carried out in order to investigate the mechanism and kinetics of Cr(VI) reduction with ZVI, as well as the influence of various parameters controlling the reduction efficiency. Therefore, the purpose of this review was to provide updated information regarding the developments and innovative approaches in the use of ZVI for the treatment of Cr(VI)-polluted waters.
This paper references
The application of in situ permeable reactive (zero-valent iron) barrier technology for the remediation of chromate-contaminated groundwater: a field test
R. W. Puls (1999)
Removal of hexavalent chromium from aqueous solution by agricultural waste biomass.
U. Garg (2007)
Zero-Valent Iron Nanoparticles for Abatement of Environmental Pollutants: Materials and Engineering Aspects
Xiao-qin Li (2006)
Stoichiometry of Cr(VI) Immobilization Using Nanoscale Zerovalent Iron (nZVI): A Study with High-Resolution X-Ray Photoelectron Spectroscopy (HR-XPS)
X. Li (2008)
Removal of chromium from synthetic plating waste by zero-valent iron and sulfate-reducing bacteria.
S. Guha (2005)
Kinetics of soluble chromium removal from contaminated water by zerovalent iron media: corrosion inhibition and passive oxide effects.
N. Melitas (2001)
Serum chromium of human subjects: effects of chromium supplementation and glucose.
R. Anderson (1985)
Reduction of chromate by granular iron in the presence of dissolved CaCO3
L. Gui (2009)
Chromium occurrence in the environment and methods of its speciation.
J. Kotas (2000)
Long-Term Performance of Zero-Valent Iron Permeable Reactive Barriers: A Critical Review
A. Henderson (2007)
Entrapment of nanoscale zero-valent iron in chitosan beads for hexavalent chromium removal from wastewater.
T. Liu (2010)
Chromium in parenteral nutrition: too little or too much?
A. Moukarzel (2009)
Removal of Hexavalent Chromium-Contaminated Water and Wastewater: A Review
M. Owlad (2009)
First results of operating and monitoring an innovative design of a permeable reactive barrier for the remediation of chromate contaminated groundwater.
Bettina Flury (2009)
Reduction of aqueous transition metal species on the surfaces of Fe(II) -containing oxides
A. White (1996)
Effects of pH and dissolved oxygen on the reduction of hexavalent chromium by dissolved ferrous iron in poorly buffered aqueous systems.
M. Schlautman (2001)
Influence of various organic molecules on the reduction of hexavalent chromium mediated by zero-valent iron.
Mario Rivero-Huguet (2009)
Nano-scale metallic iron for the treatment of solutions containing multiple inorganic contaminants.
T. Scott (2011)
Reduction of hexavalent chromium by human cytochrome b5: generation of hydroxyl radical and superoxide.
Griselda R Borthiry (2007)
Batch and continuous biosorption of chromium(VI) by Rhizopus arrhizus
B. Preetha (2007)
Chromium picolinate induced apoptosis of lymphocytes and the signaling mechanisms thereof.
M. Jana (2009)
Hydrogen Sulfide Gas Treatment of Cr(VI)-Contaminated Sediment Samples from a Plating-Waste Disposal SiteImplications for in-Situ Remediation
E. C. Thornton (1999)
Coarse atmospheric aerosol: size distributions of trace elements
K. Eleftheriadis (2001)
Characteristics of two types of stabilized nano zero-valent iron and transport in porous media.
Yu-Hao Lin (2010)
Chromium speciation in rainwater: temporal variability and atmospheric deposition.
R. J. Kieber (2002)
Toxic and mutagenic effects of chromium(VI)
M. Cieślak-Golonka (1996)
Effects of Cr3+, Cr6+ and tannery sludge on C and N mineralization and microbial activity in semi-arid soils.
M. B. Aceves (2007)
The removal and recovery of Cr(VI) by Li/Al layered double hydroxide (LDH).
L. C. Hsu (2007)
Effects and mechanism of humic acid on chromium(VI) removal by zero-valent iron (Fe0) nanoparticles
Qian Wang (2011)
Removal of hexavalent chromium from aqueous solutions by D301, D314 and D354 anion-exchange resins.
Taihong Shi (2009)
Chromium Isotopes and the Fate of Hexavalent Chromium in the Environment
A. Ellis (2002)
A Critical Assessment of Chromium in the Environment
D. Kimbrough (1999)
Treatment of hexavalent chromium in chromite ore processing solid waste using a mixed reductant solution of ferrous sulfate and sodium dithionite.
C. Su (2005)
Kinetics of hexavalent chromium removal from water by chitosan-Fe0 nanoparticles.
Bing Geng (2009)
Characterization of zero-valent iron nanoparticles.
Yuan-Pang Sun (2006)
Calcium polysulfide remediation of hexavalent chromium contamination from chromite ore processing residue.
M. Graham (2006)
Preconcentration and speciation of chromium by the determination of total chromium and chromium(III) in natural waters by flame atomic absorption spectrometry with a chelating ion-exchange flow injection system
R. M. Cespón-Romero (1996)
EFFECT OF PH ON REJECTION OF HEXAVALENT CHROMIUM BY NANOFILTRATION
M. Muthukrishnan (2008)
Spectroscopic investigation of Cr(III)- and Cr(VI)-treated nanoscale zerovalent iron.
B. Manning (2007)
Innovative measures for subsurface chromium remediation: Source zone, concentrated plume, and dilute plume. Environmental research brief
D. Sabatini (1997)
Biological chromium(VI) reduction using a trickling filter.
E. Dermou (2005)
In Situ Redox Manipulation by Dithionite Injection: Intermediate-Scale Laboratory Experiments.
J. Istok (1999)
Acute toxicity impacts of hexavalent chromium on behavior and histopathology of gill, kidney and liver of the freshwater fish, Channa punctatus (Bloch).
A. Mishra (2008)
Chromium-induced biochemical, genotoxic and histopathologic effects in liver and kidney of goldfish, carassius auratus.
V. Velma (2010)
Stabilization of highly concentrated suspensions of iron nanoparticles using shear-thinning gels of xanthan gum.
S. Comba (2009)
Natural occurrence of hexavalent chromium in the Aromas Red Sands Aquifer, California.
A. R. Gonzalez (2005)
Determination of chromium in blood and serum: evaluation of quality control procedures and estimation of reference values in Danish subjects.
J. Christensen (1993)
Nanoscale Iron Particles for Environmental Remediation: An Overview
W. Zhang (2003)
Effects of chromium on the immune system.
Richa Shrivastava (2002)
Assessment of long-term performance and chromate reduction mechanisms in a field scale permeable reactive barrier.
Ibettina Flury (2009)
Microcalorimetric study the toxic effect of hexavalent chromium on microbial activity of Wuhan brown sandy soil: an in vitro approach.
Jun Yao (2008)
Chromium content of selected Greek foods.
M. Bratakos (2002)
Particulate and soluble hexavalent chromium are cytotoxic and genotoxic to human lung epithelial cells.
S. Wise (2006)
Mechanistic evidence and efficiency of the Cr(VI) reduction in water by different sources of zerovalent irons.
J. Yang (2007)
In-Situ Remediation of Cr(VI)-Contaminated Groundwater Using Permeable Reactive Walls: Laboratory Studies
D. Blowes (1997)
Chromium(III) induces oxidative stress in goldfish liver and kidney.
O. Lushchak (2009)
Mineral precipitation and porosity losses in granular iron columns.
P. D. Mackenzie (1999)
Speciation of Cr(III) and Cr(VI) in environmental samples determined by selective separation and preconcentration on silica gel chemically modified with niobium(V) oxide.
Edmar Martendal (2009)
Removal of hexavalent chromium from groundwater by granular activated carbon
I. Han (2000)
A method for the preparation of stable dispersion of zero-valent iron nanoparticles
Yuan-Pang Sun (2007)
Cytotoxicity and oxidative mechanisms of different forms of chromium.
D. Bagchi (2002)
Heavy metal concentrations in soils as determined by laser-induced breakdown spectroscopy (LIBS), with special emphasis on chromium.
G.S. Senesi (2009)
Assessment of calcium polysulfide for the remediation of hexavalent chromium in chromite ore processing residue (COPR).
Mahmoud Wazne (2007)
Chemistry and Microbiology of Permeable Reactive Barriers for In Situ Groundwater Clean up
M. Scherer (2000)
Aqueous geochemistry of chromium: A review
F. Richard (1991)
Longevity of granular iron in groundwater treatment processes: corrosion product development.
T. Kohn (2005)
Five years of air chemistry observations in the Canadian Arctic
L. A. Barrie (1985)
Carbothermal synthesis of carbon-supported nanoscale zero-valent iron particles for the remediation of hexavalent chromium.
L. Hoch (2008)
Insight into the phenomenology of the Cr(VI) reduction by metallic iron using an electron probe microanalyzer.
A. Vega (2010)
Chromium(III) hydrolysis constants and solubility of chromium(III) hydroxide
D. Rai (1987)
Advanced Inorganic Chemistry
F. Cotton (1999)
Investigation of thermochromism in a series of side-chain, liquid-crystalline, azobenzene-containing polymers
S. Freiberg (2004)
Elements in the hair of non-mining workers of a lignite open mine in Neyveli.
A. Sukumar (2003)
Chromium toxicity in plants.
A. Shanker (2005)
Influence of plants on the reduction of hexavalent chromium in wetland sediments.
J. Zazo (2008)
Possible association between nickel and chromium and oral cancer: a case-control study in central Taiwan.
Tzu-Hsuen Yuan (2011)
Speciation of hexavalent chromium in waters by liquid–liquid extraction and GFAAS determination
Áron Béni (2007)
Effect of chromium supplementation on hair chromium concentration and diabetic status
Alice E. Hunt (1985)
Iron-mediated reductive transformations : investigation of reaction mechanism
E. Weber (1996)
Metal Pollution Assessment of Sediment and Water in the River Hindon, India
C. K. Jain (2005)
Performance evaluation of a zerovalent iron reactive barrier: Mineralogical characteristics
D. Phillips (2000)
Reduction of hexavalent chromium in aqueous medium with zerovalent iron.
Ratnadeepa Dutta (2010)
Mechanism of oxide film formation on iron in simulating groundwater solutions: Raman spectroscopic studies
M. Odziemkowski (1998)
REMOVAL OF CR 6+ IONS FROM WASTEWATER IN PRESENCE OF QUATERNARY AMMONIUM SALTS
D. Salem (2006)
Kinetics of nitrate, nitrite, and Cr(VI) reduction by iron metal.
Michael J Alowitz (2002)
An evaluation of steel scrap as a reducing agent in the galvanic stripping of iron from D2EHPA
J. Sun (2002)
Competitive Effects of Trichloroethylene on Cr(VI) Removal by Zero-Valent Iron
I. Lo (2005)
Bactericidal effect of zero-valent iron nanoparticles on Escherichia coli.
C. Lee (2008)
Understanding chromate reaction kinetics with corroding iron media using Tafel analysis and electrochemical impedance spectroscopy.
N. Melitas (2002)
Pyrite oxidation by hexavalent chromium: investigation of the chemical processes by monitoring of aqueous metal species.
F. Demoisson (2005)
Proton Generation by Dissolution of Intrinsic or Augmented Aluminosilicate Minerals for in Situ Contaminant Remediation by Zero-Valence-State Iron
R. Powell (1997)
Effects of chromium (VI) addition on the activated sludge process.
A. Stasinakis (2003)
Long-term performance monitoring for a permeable reactive barrier at the U.S. Coast Guard Support Center, Elizabeth City, North Carolina.
R. W. Puls (1999)
Determination of lead, chromium and zinc in sediments from an urbanized river in Mauritius.
R. Ramessur (2002)
Dimensioning metallic iron beds for efficient contaminant removal.
C. Noubactep (2010)
Electrically regenerated ion exchange for removal and recovery of Cr(VI) from wastewater.
Yunqing Xing (2007)
Nanoporous zero-valent iron
J. Cao (2005)
Enhanced reduction of chromate and PCE by pelletized surfactant-modified zeolite/zerovalent iron
Z. Li (1999)
Kinetics of hexavalent chromium reduction by iron metal
Huijing Qian (2008)
Risk-based classification system of nanomaterials
Tommi Tervonen (2009)
The kinetics of hexavalent chromium reduction by metallic iron
J. Gould (1982)
The hydrolysis of cations
C. Baes (1976)
Arsenic and chromate removal from water by iron chips—Effects of anions
Ruihua Zhang (2008)
Use of Remotely Sensed Data to Evaluate the Relationship between Living Environment and Blood Pressure
M. G. Estes (2009)
Hexavalent Chromium in the Ground Water in Paradise Valley, Arizona
F. N. Robertson (1975)
Capacity of Cr(VI) reduction in an aqueous solution using different sources of zerovalent irons
J. Yang (2006)
Zerovalent irons: styles of corrosion and inorganic control on hydrogen pressure buildup.
E. Reardon (2005)
Remediation of chromate-contaminated ground water using zero-valent iron: Field test at USCG Support Center, Elizabeth City, North Carolina
R. W. Puls (1996)
Chromium speciation and distribution in the great lakes.
Stan Beaubien (1994)
Root uptake and reduction of hexavalent chromium by aquatic macrophytes as assessed by high-resolution X-ray emission.
F. Espinoza-Quiñones (2009)
Heavy metal removal and cyanide destruction in the metal plating industry: an integrated approach from egypt
S. I. Abou-Elela (2008)
Microbiological Characteristics in a Zero-Valent Iron Reactive Barrier
B. Gu (2002)
Chromium(VI) reduction by hydrogen sulfide in aqueous media: stoichiometry and kinetics.
C. Kim (2001)
Hexavalent chromium reduction with scrap iron in continuous-flow system Part 1: effect of feed solution pH.
M. Gheju (2008)
Metals recycling in the United States
S. F. Sibley (1995)
The fundamental mechanism of aqueous contaminant removal by metallic iron
C. Noubactep (2010)
Kinetics of chromate reduction by ferrous iron
S. Fendorf (1996)
Metals recycling: economic and environmental implications
R. Ayres (1997)
A quantitative assessment of the carcinogenicity of hexavalent chromium by the oral route and its relevance to human exposure.
A. H. Stern (2010)
Transport of hexavalent chromium through anion-exchange membranes
Y. Çengeloğlu (2003)
Zero-Valent Iron Removal Rates of Aqueous Cr(VI) Measured Under Flow Conditions
D. Kaplan (2004)
Kinetic Analysis and Mathematical Modeling of Cr(VI) Removal in a Differential Reactor Packed with Ecklonia Biomass
D. Park (2006)
Products of Chromate Reduction on Proposed Subsurface Remediation Material
A. Pratt (1997)
Use of iron-based technologies in contaminated land and groundwater remediation: a review.
A. Cundy (2008)
Biological activation of hydrous ferric oxide for reduction of hexavalent chromium in the presence of different anions
A. Vázquez-Morillas (2006)
Reduction of hexavalent chromium by carboxymethyl cellulose-stabilized zero-valent iron nanoparticles.
Qian Wang (2010)
Extraction of Hexavalent Chromium from Aqueous Solution by Emulsion Liquid Membrane
D. Singh (2002)
Natural hexavalent chromium in groundwaters interacting with ophiolitic rocks
D. Fantoni (2002)
The impact of zero-valent iron nanoparticles on a river water bacterial community.
R. H. Barnes (2010)
Hexavalent chromium reduction with scrap iron in continuous-flow system. Part 2: Effect of scrap iron shape and size.
M. Gheju (2010)
Treatment of inorganic contaminants using permeable reactive barriers 1 1 Disclaimer: The U. S. Envi
D. Blowes (2000)
Potential hazards of hexavalent chromate in our drinking water.
M. Costa (2003)
Removal of co-present chromate and arsenate by zero-valent iron in groundwater with humic acid and bicarbonate.
T. Liu (2009)
Reductive immobilization of chromate in water and soil using stabilized iron nanoparticles.
Y. Xu (2007)
Particulate and soluble hexavalent chromium are cytotoxic and genotoxic to Steller sea lion lung cells.
S. Wise (2009)
Factors affecting chromium(VI) reduction by Thiobacillus ferrooxidans
M. QuiIntana (2001)
Hexavalent chromium removal from near natural water by copper-iron bimetallic particles.
Ching-Yao Hu (2010)
The Chemical Transformations of Chromium in Natural Waters – A Model Study
Che-Jen Lin (2002)
Chemical Reduction of Hexavalent Chromium and Its Immobilisation Under Batch Conditions Using a Slurry Reactor
D. Franco (2009)
Survey of trace elements in human nails: An international comparison
Y. Takagi (1988)
Remediation of Cr(VI) and Pb(II) aqueous solutions using supported, nanoscale zero-valent iron
S. Ponder (2000)
Stabilization of aqueous nanoscale zerovalent iron dispersions by anionic polyelectrolytes: adsorbed anionic polyelectrolyte layer properties and their effect on aggregation and sedimentation
T. Phenrat (2008)
Recommended dietary allowances.
N. Board. (1953)
Removal of Cr(VI) from aqueous solution by two Lewatit-anion exchange resins.
F. Gode (2005)
Zero-Valent Iron for Water Treatment
T. Bigg (2000)
Effect of amorphous silica and silica sand on removal of chromium(VI) by zero-valent iron.
Y. Oh (2007)
Removal of hexavalent chromium from solutions by mackinawite, tetragonal FeS
M. Mullet (2004)
Comparative study of analytical methods for the determination of chromium in groundwater samples containing iron
A. R. Kumar (2009)
Zero-valent iron and iron oxide-coated sand as a combination for removal of co-present chromate and arsenate from groundwater with humic acid.
M. S. Mak (2011)
Analytical chemistry of chromium.
C. Veillon (1989)
An analysis of the evolution of reactive species in Fe0/H2O systems.
C. Noubactep (2009)
Preferential flow path development and its influence on long-term PRB performance: column study.
W. Kamolpornwijit (2003)
Interactions of chromium with microorganisms and plants.
C. Cervantes (2001)
Degradation of TCE, Cr(VI), sulfate, and nitrate mixtures by granular iron in flow-through columns under different microbial conditions.
Sumeet Gandhi (2002)
Extraction of chromium (VI) from sulphuric acid aqueous solutions by a liquid surfactant membrane (LSM)
M. Chiha (2006)
Potential application of highly reactive Fe(0)/Fe3O4 composites for the reduction of Cr(VI) environmental contaminants.
Flávia Dos Santos Coelho (2008)
Preparation of chitosan-stabilized Fe(0) nanoparticles for removal of hexavalent chromium in water.
Bing Geng (2009)
The reduction of chromium (VI) by iron (II) in aqueous solutions
Maurizio Pettine (1998)
Zero-valent iron for the in situ remediation of selected metals in groundwater
K. Cantrell (1995)
Draft toxicological profile for chromium
H. Abadin (2008)
Removal of chromium ions from aqueous solutions by polymer-enhanced ultrafiltration.
M. K. Aroua (2007)
Design and Installation
R. Tricker (2009)
Chemical kinetic mechanism for atmospheric chromium.
C. Seigneur (1995)
A new technique for removing hexavalent chromium from waste water and energy generation via galvanic reduction with scrap iron
M. Abdo (1998)
Anaerobic corrosion of granular iron: measurement and interpretation of hydrogen evolution rates.
E. Reardon (1995)
Microbial Characterization of Groundwater Undergoing Treatment with a Permeable Reactive Iron Barrier
M. B. D. Silva (2007)
The amelioration of acid mine drainage by anin situ electrochemical method—I. Employing scrap iron as the sacrificial anode
G. Shelp (1995)
Metal concentrations in sediments and tilapia collected from inland waters of Hong Kong
H. Zhou (1998)
Chromium(VI) reduction by sulphur(IV) in aqueous solutions
Maurizio Pettine (2006)
Trace elements in human hair: An international comparison
Y. Takagi (1986)
Hexavalent Chromium Removal from Water Using Chitosan- Fe 0 Nanoparticles
Li Tie-long (2009)
Processes affecting the remediation of chromium-contaminated sites.
C. Palmer (1991)
Equilibrium and kinetics of chromium(VI) extraction with Aliquat 336
E. Salazar (1992)
Reflections on hexavalent chromium: health hazards of an industrial heavyweight.
C. Pellerin (2000)
Kinetics of Cr(VI) reduction by carbonate green rust.
A. G. Williams (2001)
Environmental data for production of reinforcement bars from scrap iron and for production of steel products from iron ore in the Nordic countries
H. Krogh (2001)
Reduction of Hexavalent Chromium by Amorphous Iron Sulfide
Ronald R. Patterson and (1997)
Chromium VI administration induces oxidative stress in hypothalamus and anterior pituitary gland from male rats.
S. Nudler (2009)
Influences of humic acid, bicarbonate and calcium on Cr(VI) reductive removal by zero-valent iron.
T. Liu (2009)
Removal of chromium (VI) by acid-washed zero-valent iron under various groundwater geochemistry conditions.
K. C. Lai (2008)
Coupled iron corrosion and chromate reduction: mechanisms for subsurface remediation.
R. M. Powell (1995)
Removal of hexavalent chromium from industrial wastewater by electrocoagulation: A comprehensive comparison of aluminium and iron electrodes
Inoussa Zongo (2009)
Reference values of urinary chromium in Italy
P. Apostoli (1997)
Immobilization of Chromate from Coal Fly Ash Leachate Using an Attenuating Barrier Containing Zero-valent Iron
T. Astrup (2000)
The effect of different divalent cations on the reduction of hexavalent chromium by zerovalent iron
Meifang Hou (2008)
Surface reactions of chromium in soils and waters
S. Fendorf (1995)
Bioaccumulation and Effects of Heavy Metals in Crayfish: A Review
A. Kouba (2010)
Use of zero-valent iron nanoparticles in inactivating microbes.
M. Diao (2009)
Biosorption of nickel and total chromium from aqueous solution by gum kondagogu (Cochlospermum gossypium): A carbohydrate biopolymer.
V. P. Vinod (2010)
Enhanced Degradation of Halogenated Aliphatics by Zero‐Valent Iron
R. Gillham (1994)
The Status of Trace and Toxic Elements in Biological Samples (Scalp Hair) of Skin-Disease Patients and Normal Subjects
H. I. Afridi (2006)
Chromium Transformations in Natural Environments: The Role of Biological and Abiological Processes in Chromium(VI) Reduction
S. Fendorf (2000)
Exploring the influence of operational parameters on the reactivity of elemental iron materials.
C. Noubactep (2009)
Essentiality of chromium in humans.
R. Anderson (1989)
Elemental metals for environmental remediation: learning from cementation process.
C. Noubactep (2010)
Removal of Cr(VI) from polluted solutions by electrocoagulation: Modeling of experimental results using artificial neural network.
S. Aber (2009)
Retention of chromium (III) and cadmium (II) from aqueous solution by illitic clay as a low-cost adsorbent.
I. Ghorbel-Abid (2010)
Processing of cast iron scrap from the diesel engine manufacturing industry by powder metallurgy techniques
D. A. Karandikar (1991)
Metallic iron for safe drinking water worldwide
C. Noubactep (2010)
Relationship of Hydrogen Bioavailability to Chromate Reduction in Aquifer Sediments
T. Marsh (2001)
Investigation of pyrite oxidation by hexavalent chromium: solution species and surface chemistry.
F. Demoisson (2007)
Review sectionIARC Monographs on the evaluation of carcinogenic risks to humans: Volume 49. Chromium, nickel and welding: Lyon, 1990. pp. 677. Sw. fr. 95.00. ISBN 92 832 1249 5
J. Hopkins (1991)
The recycling of metals—I. Ferrous metals
M. Bever (1976)
Heterogeneous kinetics of the reduction of chromium (VI) by elemental iron.
António Fiúza (2010)
Reduction of hexavalent chromium mediated by micro- and nano-sized mixed metallic particles.
Mario Rivero-Huguet (2009)
Nickel, chromium and iron levels in the saliva of patients with simulated fixed orthodontic appliances.
Rodrigo Matos de Souza (2008)
Removal of contaminants in leachate from landfill by waste steel scrap and converter slag
Byung-Taek Oh (2007)
Chromium(VI) reduction kinetics by zero-valent iron in moderately hard water with humic acid: iron dissolution and humic acid adsorption.
T. Liu (2008)
A study on the Cr(VI) removal from aqueous solutions by steel wool.
A. Ozer (1997)
Chromium and manganese levels in convenience and fast foods: In vitro study of the dialyzable fraction
C. Cabrera–Vique (2009)
Speciation of aqueous chromium by use of solid-phase extractions in the field.
G. Icopini (2002)
Determination of chromium(III) and total chromium in seawater by on-line column preconcentration inductively coupled plasma mass spectrometry
S. Hirata (2000)
Seasonal and local variation of Cr, Ni and Co concentrations in Ulva rigida C. Agardh and Enteromorpha linza (Linnaeus) from Thermaikos Gulf, Greece.
S. Haritonidis (1995)
Effect of Fe0 quantity on the efficiency of integrated microbial-Fe0 treatment processes.
J. M. Fernández‐Sánchez (2004)
On the operating mode of bimetallic systems for environmental remediation.
C. Noubactep (2009)
Chromium speciation by solid phase extraction on Dowex M 4195 chelating resin and determination by atomic absorption spectrometry.
K. O. Saygi (2008)
Effect of pH and chloride concentration on the removal of hexavalent chromium in a batch electrocoagulation reactor.
M. G. Arroyo (2009)
Cr(VI) reduction in wastewater using a bimetallic galvanic reactor.
V. Lugo-Lugo (2010)
Chromium in human milk from American mothers.
Casey Ce (1984)
The Nubase evaluation of nuclear and decay properties
G. Audi (2003)
Optimization of Cr(VI) reduction by zero-valent bimetallic nanoparticles using the response surface modeling approach
K. Singh (2011)
Hexavalent Chromium Is Carcinogenic to F344/N Rats and B6C3F1 Mice after Chronic Oral Exposure
M. Stout (2009)
Determination of total chromium in environmental water samples.
J. Parks (2004)
Chromium(VI) is more toxic than chromium(III) to freshwater algae: a paradigm to revise?
D. Vignati (2010)
REDUCTION OF HEXAVALENT CHROMIUM BY FERROUS IRON
D. Sedlak (1997)
Effects of pH and dissolved oxygen on Cr(VI) removal in Fe(0)/H2O systems.
In-Ho Yoon (2011)
Chromium, glucose intolerance and diabetes.
R. Anderson (1998)
Source origin and parameters influencing levels of heavy metals in TSP, in an industrial background area of Southern Italy
M. Ragosta (2002)
Heavy metals in human hair and teeth
B. Nowak (2007)
An in situ study of the role of surface films on granular iron in the permeable iron wall technology.
K. Ritter (2002)
Hexavalent chromium reduction using a fixed bed of scrap bearing iron spheres
A. H. El-Shazly (2005)
Metallic iron for environmental remediation: learning from electrocoagulation.
C. Noubactep (2010)
Chromium Distribution in Korean Soils: A Review
Rog-Young Kim (2010)
Chromium chemistry and implications for environmental fate and toxicity
J. Barnhart (1997)
Performance evaluation of granular iron for removing hexavalent chromium under different geochemical conditions.
S. Jeen (2008)
Precipitates on granular iron in solutions containing calcium carbonate with trichloroethene and hexavalent chromium.
S. Jeen (2007)
Speciation study of chromium, copper and nickel in coastal estuarine sediments polluted by domestic and industrial effluents
M. H. Lam (1997)
Chromium removal from aqueous solution by the ferrite process.
M. Erdem (2004)
The Chromium issue in soils of the leather tannery district in Italy.
C. Bini (2006)
Hardness and carbonate effects on the reactivity of zero-valent iron for Cr(VI) removal.
I. M. Lo (2006)
Synthesis and characterization of a new resin functionalized with 2-naphthol-3,6-disulfonic acid and its application for the speciation of chromium in natural water.
B. C. Mondal (2002)
Pilot-scale removal of chromium from industrial wastewater using the ChromeBac system.
W. A. Ahmad (2010)
Biosorption of trivalent chromium on the brown seaweed biomass.
Y. Yun (2001)
Use of waste iron metal for removal of Cr(VI) from water.
T. Lee (2003)
Treatment of dissolved metals using permeable reactive barriers
D. Blowes (1998)
Nutritional chemistry of chromium.
G. Iyengar (1989)
Formation of ferrihydrite and associated iron corrosion products in permeable reactive barriers of zero-valent iron.
Yoko Furukawa (2002)
The Kinetics of Oxygen-exchange Reaction between Chromate Ions and Water
Akiko J Okumura (1980)
Reaction between chromate and thiosulfate. II. Kinetics of tetrathionate formation
I. Bâldea (1970)
Geostatistical aquifer characterization for use in flow and transport modeling
J. R. Gregory (1991)
Seasonal transport pattern of chromium(III and VI) in a stream receiving wastewater from tanneries
E. Szalinska (2010)
Cobalt, chromium, and nickel concentrations in body fluids of patients with porous‐coated knee or hip prostheses
F. Sunderman (1989)
Important process variables in chromate ion exchange.
A. K. Sengupta (1986)
The effectiveness of ferrous iron and sodium dithionite for decreasing resin-extractable Cr(VI) in Cr(VI)-spiked alkaline soils.
Chia-Jung Cheng (2009)
Nanotechnology and in Situ Remediation: A Review of the Benefits and Potential Risks
B. Karn (2009)
Chromate transport through columns packed with surfactant-modified zeolite/zero valent iron pellets.
Z. Li (2007)
Toxicity and carcinogenicity of Cr(VI) in animal models and humans.
M. Costa (1997)
Reduction of Hexavalent Chromium in Soil and Ground Water Using Zero-Valent Iron Under Batch and Semi-Batch Conditions
D. Franco (2009)
Chromium (VI) reduction in aqueous solutions by Fe3O4-stabilized Fe0 nanoparticles.
Yanjun Wu (2009)
Chromate reduction in wastewater at different pH levels using thin iron wires—A laboratory study
Li-Yang Chang (2005)
Enhanced transport of zerovalent iron nanoparticles in saturated porous media by guar gum
A. Tiraferri (2008)
Normal values for chromium (Cr) and nickel (Ni) in human pulmonary tissue
H. Raithel (1990)
Reduction of chromate from electroplating wastewater from pH 1 to 2 using fluidized zero valent iron process.
S. Chen (2007)
Investigations on the quantitative determination of nickel and chromium in human lung tissue
H. J. Raithel (1988)
The chromium content of some Australian foods
J. Ashton (2003)
Reductive removal of Cr(VI) by starch-stabilized Fe0 nanoparticles in aqueous solution
L. Alidokht (2011)
Chromate reduction by waste iron from electroplating wastewater using plug flow reactor.
S. Chen (2008)
Heavy Metals in Soils: Trace Metals and Metalloids in Soils and their Bioavailability
B. J. Alloway (2013)
Aquatic Chemical Kinetics
J. Drever (1991)
Fingernails as biological indices of metal exposure
R. Mehra (2007)
Optimization of copper cementation process by iron using central composite design experiments
W. Djoudi (2007)
Kinetic study of hexavalent Cr(VI) reduction by hydrogen sulfide through goethite surface catalytic reaction
Chulsung Kim (2007)
Efficient removal of Cr(VI) from aqueous solution with Fe@Fe2O3 core-shell nanowires.
Z. Ai (2008)
Mechanism of hexavalent chromium detoxification by microorganisms and bioremediation application potential: A review
K. H. Cheung (2007)
Nasal septum lesions and lung function in workers exposed to chromic acid in electroplating factories
H. Kuo (1997)
Determination of chromium in human milk, serum and urine by electrothermal atomic absorption spectrometry without preliminary ashing.
J. Kumpulainen (1983)
Removal of chromium (VI) from water streams: a thermodynamic study
G. P. Gallios (2008)
Acute severe chromium poisoning after dermal exposure to hexavalent chromium.
Chun-Chi Lin (2009)
Blood chromium determination in assessing reference values in an unexposed mediterranean population
M. Torra (2007)
Alternative chromium reduction and heavy metal precipitation methods for industrial wastewater
Li-Yang Chang (2003)
Biomonitoring of nickel and chromium in human pulmonary tissue
H. Raithel (1993)
Wastewater screening method for evaluating applicability of zero-valent iron to industrial wastewater.
J. Lee (2010)
Natural chromium contamination of groundwater at León Valley, México
J. Robles-Camacho (2000)
Influences of water vapor on Cr(VI) reduction by gaseous hydrogen sulfide.
Bin Hua (2003)
Influence of complex reagents on removal of chromium(VI) by zero-valent iron.
H. Zhou (2008)
Soft x-ray spectroscopic studies of the reaction of fractured pyrite surfaces with Cr(VI)-containing aqueous solutions
C. S. Doyle (2004)
Zero Valent Iron and Clay Mixtures for Removal of Trichloroethylene, Chromium(VI), and Nitrate
H. Lee (2006)
Nanotechnologies for environmental cleanup
Paul G Tratnyek (2006)
Spatial distribution of chromium in soils contaminated by chromium-containing slag
Shun-hong Huang (2009)
Environmental benefits and risks of zero-valent iron nanoparticles (nZVI) for in situ remediation: risk mitigation or trade-off?
Khara Grieger (2010)
Incorporation of Cr in the passive film on Fe from chromate solutions
H. Isaacs (2002)
Catalysis of Dissolved and Adsorbed Iron in Soil Suspension for Chromium(VI) Reduction by Sulfide
Y. Lan (2006)
Aqueous Cr(VI) reduction by electrodeposited zero-valent iron at neutral pH: acceleration by organic matters.
Junxi Liu (2009)
Effect of metals on the reduction of chromium (VI) with hydrogen sulfide
Maurizio Pettine (1998)
Effect of humic acids on heavy metal removal by zero-valent iron in batch and continuous flow column systems.
J. Dries (2005)
Remediation of chromium(VI) in the vadose zone: stoichiometry and kinetics of chromium(VI) reduction by sulfur dioxide
M. Ahn (2004)
Enhancement of electrokinetic remediation of hyper-Cr(VI) contaminated clay by zero-valent iron.
C. Weng (2007)
Synthesis, characterization and re-activation of a Fe0/Ti system for the reduction of aqueous Cr(VI).
Junxi Liu (2008)
A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron
Dong-Ik Song (2005)
In Situ Cr(VI) Reduction within Coarse-Textured, Oxide-Coated Soil and Aquifer Systems Using Fe(II) Solutions
J. Seaman (1999)
In Situ Permeable Reactive Barriers for Groundwater Contamination
J. P. Richardson (2002)
Activated carbons and low cost adsorbents for remediation of tri- and hexavalent chromium from water.
D. Mohan (2006)
Disposal of Waste Liquors from Chromium Plating
C. R. Hoover (1941)
Chromium speciation in seawater: The probable role of hydrogen peroxide
M. Pettine (1990)
Removal of chromium (VI) from aqueous solution using walnut hull.
X. S. Wang (2009)
Chromium(VI) removal with activated carbons
Manuel Pérez-Candela (1995)
Processes of Contaminant Removal in Fe0-H2O Systems Revisited: The Importance of Co-Precipitation
C. Noubactep (2007)
Adsorption of chromium(VI) on low cost adsorbents derived from agricultural waste material: a comparative study.
S. Dubey (2007)
Characterizing the reactivity of metallic iron in Fe0/EDTA/H2O systems with column experiments
C. Noubactep (2010)
A regional-scale study of chromium and nickel in soils of northern California, USA
J. M. Morrison (2009)
Removal of chromium (VI) from wastewater using bentonite-supported nanoscale zero-valent iron.
L. Shi (2011)
Long-term performance of permeable reactive barriers using zero-valent iron: geochemical and microbiological effects.
R. Wilkin (2003)
Determination of total chromium in phosphate rocks by ion chromatography.
A. W. Al-Shawi (1999)
Analysis, storage stability and reference values for urinary chromium and nickel
M. Kiilunen (1987)
Metal speciation in Jhanji River sediments
N. Baruah (1996)
Trivalent chromium induces oxidative stress in goldfish brain.
O. Lushchak (2009)
Normal concentrations of chromium in serum and urine--a TRACY project.
D. Brune (1993)
Chromium as an essential nutrient for humans.
R. Anderson (1997)
Influences of Humic Acid on Cr(VI) Removal by Zero-Valent Iron From Groundwater with Various Constituents: Implication for Long-Term PRB Performance
T. Liu (2011)
Investigating DNA damage in tannery workers occupationally exposed to trivalent chromium using comet assay.
M. Zhang (2008)
On nanoscale metallic iron for groundwater remediation.
C. Noubactep (2010)
In situ chemical reduction of Cr(VI) in groundwater using a combination of ferrous sulfate and sodium dithionite: a field investigation.
Ralph D. Ludwig (2007)
The chemistry of chromium and some resulting analytical problems.
S. Shupack (1991)
Water treatment processes. III. Removing dissolved inorganic contaminants from water
Dennis A. Clifford (1986)
Environmental chemistry of chromium.
D. Rai (1989)
Mechanisms of chromium carcinogenicity and toxicity.
M. Cohen (1993)
Chromium stress induced alterations in biochemical and enzyme metabolism in aquatic and terrestrial plants.
K. S. Ganesh (2008)
In situ remediation of ground water contaminated with chromate and chlorinated solvents using zero-valent iron: A field study
R. W. Puls (1995)
Chemical properties and toxicity of chromium(III) nutritional supplements.
A. Levina (2008)
Effect of pH on fermentation hydrogen production from heat pretreated sludge.
C. Chen (2011)
Removal of trivalent chromium from aqueous solution by zeolite synthesized from coal fly ash.
Deyi Wu (2008)
Kinetics of hexavalent chromium reduction by scrap iron.
M. Gheju (2006)
Distribution of oxides on iron materials used for remediation of organic groundwater contaminants Implications for hydrogen evolution reactions
M. Odziemkowski (2004)
Chromium content in selected convenience and fast foods in Poland
M. Krzysik (2008)
A novel kinetic determination of dissolved chromium species in natural and industrial waste water.
A. A. Mohamed (2006)
Reduction of chromium(VI) by pyrite in dilute aqueous solutions
Yao-Tung Lin (2008)
An XPS study of passive film formation on iron in chromate solutions
E. Mccafferty (1988)
Heavy metals in ryegrass species versus metal concentrations in atmospheric particulate measured in an industrial area of Southern Italy
R. Caggiano (2005)
The reduction of hexavalent chromium by sulphite in wastewater
J. Beukes (1999)
Fe0-based alloys for environmental remediation: thinking outside the box.
C. Noubactep (2009)
Iron powder from iron scrap
P. Ramakrishnan (1983)
Permeable Reactive Barriers of Iron and Other Zero-Valent Metals
Paul G Tratnyek (2004)
Toxic and mutagenic effects of chromium(VI). A review
M. Cieślak-Golonka (1996)
Removal of hexavalent chromium from aqueous solution by iron nanoparticles.
Shao-feng Niu (2005)
This paper is referenced by
Metallic iron for environmental remediation: A review of reviews.
C. Noubactep (2015)
Harmful Elements in Estuarine and Coastal Systems
M. B. Khan (2014)
Avoiding the Use of Exhausted Drinking Water Filters: A Filter-Clock Based on Rusting Iron
A. I. Ndé-Tchoupé (2018)
Reductive transformation of p-nitrotoluene by a new iron-fly ash packing.
Baizhen Yu (2015)
Enhanced sequestration of Cr(VI) by copper doped sulfidated zerovalent iron (SZVI-Cu): Characterization, performance, and mechanisms
Tiantian Jia (2019)
Comparative evaluation of five plant extracts and juices for nanoiron synthesis and application for hexavalent chromium reduction.
C. Mystrioti (2016)
Impact of MnO 2 on the efficiency of metallic iron for the removal of dissolved CrVI
Modeling the Permeability Loss of Metallic Iron Water Filtration Systems
S. Caré (2013)
Insight into Cr6+ reduction efficiency of Rhodococcus erythropolis isolated from coalmine waste water.
S. Banerjee (2017)
Electrochemically enhanced reduction of hexavalent chromium in contaminated clay: Kinetics, energy consumption, and application of pulse current
T. R. Sun (2015)
Green Synthesis of Resin Supported Nanoiron and Evaluation of Efficiency for the Remediation of Cr(VI) Contaminated Groundwater by Batch Tests
A. Toli (2018)
Weak magnetic field accelerates chromate removal by zero-valent iron.
P. Feng (2015)
Synthesis of Bimetallic Fe/Cu Nanoparticles with Different Copper Loading Ratios
May Thant Zin (2014)
Catalytic Reduction of Hexavalent Chromium Using Palladium Nanoparticles: An Undergraduate Nanotechnology Laboratory
O. Sadik (2014)
Role of pre-corrosion of Fe0 on its efficiency in remediation systems: An electrochemical study.
Marquise Touomo-Wouafo (2018)
Reductive-co-precipitated cellulose immobilized zerovalent iron nanoparticles in ionic liquid/water for Cr(VI) adsorption
A. Sharma (2018)
Removal of Cr(VI) from Water Using a New Reactive Material: Magnesium Oxide Supported Nanoscale Zero-Valent Iron
A. Siciliano (2016)
The Impact of Selected Pretreatment Procedures on Iron Dissolution from Metallic Iron Specimens Used in Water Treatment
R. Hu (2019)
Microbial fuel cells for bioelectricity generation through reduction of hexavalent chromium in wastewater: A review
Md. Jamal Uddin (2020)
Inorganic engineered nanoparticles in drinking water treatment: a critical review
K. Simeonidis (2016)
Progress in Understanding the Mechanism of CrVI Removal in Fe0-Based Filtration Systems
M. Gheju (2018)
Effect of pH, temperature, humic acid and coexisting anions on reduction of Cr(Ⅵ) in the soil leachate by nZVI/Ni bimetal material.
F. Zhu (2017)
The Application of Advanced Materials on the Water or Wastewater Treatment
Y. Zhang (2015)
Iron and Iron Oxide-Based Eco-Nanomaterials for Catalysis and Water Remediation
S. Singh (2018)
In situ carbothermal synthesis of nZVI functionalized porous carbon from Fe‐MOFs for efficient detoxification of Cr(VI)
Z. Wang (2017)
Environmental Nanotechnology Volume 3
N. Dasgupta (2020)
Synthesis of novel CO32−/Cl−-bearing 3(Mg + Zn)/(Al + Fe) layered double hydroxides for the removal of anionic hazards
Khaled S. Abou-El-Sherbini (2015)
Assessment of Polyphenol Coated Nano Zero Valent Iron for Hexavalent Chromium Removal from Contaminated Waters
C. Mystrioti (2014)
Premagnetization for Enhancing the Reactivity of Multiple Zerovalent Iron Samples toward Various Contaminants.
Jinxiang Li (2015)
Activated carbon impregnated by zero-valent iron nanoparticles (AC/nZVI) optimized for simultaneous adsorption and reduction of aqueous hexavalent chromium: Material characterizations and kinetic studies
S. Mortazavian (2018)
Transport of CMC-Stabilized nZVI in Saturated Sand Column: the Effect of Particle Concentration and Soil Grain Size
A. Saberinasr (2016)
Effect of pH, temperature and co-existing anions on the Removal of Cr(VI) in groundwater by green synthesized nZVI/Ni.
F. Zhu (2018)See more