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Virtual Pressure And Virtual Fugacity In Catalysis And Electrocatalysis

M. Boudart
Published 1989 · Chemistry

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The generalized De Donder equation and the generalized Butler-Volmer equation can be used to understand and calculate so-called virtual pressure or virtual fugacity of reactants or products in catalytic and electrocatalytic cycles respectively. This illustrates the usefulness of general relations between kinetics and thermodynamics in sub-fields of catalysis that differ in their methodology.



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