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The Regulating Effects Of Cobalt Addition On The Catalytic Properties Of Silica-supported Ni–Co Bimetallic Catalysts For CO2 Methanation

M. Guo, G. Lu
Published 2014 · Chemistry

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Co-modified Ni/SiO2 samples were prepared by the wet co-impregnation method and characterized by X-ray photoelectron spectroscopy (XPS), hydrogen-temperature programmed reduction (H2-TPR), and X-ray diffraction (XRD) techniques. The obtained materials were used as the catalysts for the carbon dioxide methanation reaction. Methanation activities of Ni–Co/SiO2 catalysts were significantly dependent on Co/Ni molar ratios. The increase of Co loading led to the remarkable increase of CO2 conversions at temperature range from 250–350 °C. The methanation activities of bimetallic catalysts were also significantly dependent on Co/Ni molar ratios from XPS results. Based on the XRD characterization, a relationship between activities and NiCo species was observed. These NiCo species showed the typical TPR peaks at high temperatures. The higher the temperatures of these species over bimetallic catalyst were, the lower the catalytic activities were observed. In addition, the decrease of both NiCo(111) lattice constants and particle sizes corresponded the increase of catalytic activities in tested samples. A possible mechanism based on those NiCo species is proposed.
This paper references
10.1016/J.IJHYDENE.2010.02.124
Nickel versus cobalt catalysts for hydrogen production by ethanol steam reforming: Ni–Co–Zn–Al catalysts from hydrotalcite-like precursors
G. Busca (2010)
10.1016/S0166-9834(00)84115-9
Hydrogenation of carbon monoxide over SiO2-supported Fe-Co, Co-Ni and Ni-Fe bimetallic catalysts
T. Ishihara (1987)
10.1007/S11144-010-0240-9
Copper crystallite size and methanol synthesis catalytic property of Cu-based catalysts promoted by Al, Zr and Mn
G. Wang (2010)
10.1016/J.IJHYDENE.2010.04.075
Biogas reforming for hydrogen production over a Ni–Co bimetallic catalyst: Effect of operating conditions
J. Xu (2010)
10.1016/J.APCATA.2010.10.025
Effect of Ce/Zr composition and noble metal promotion on nickel based CexZr1−xO2 catalysts for carbon dioxide methanation
F. Ocampo (2011)
10.1016/J.APCATA.2011.02.007
Monodispersed and nanostructrured Ni/SiO2 catalyst and its activity for non oxidative methane activation
S. F. Moya (2011)
10.1006/JCAT.1996.0259
A Comparative Study of CO and CO2Hydrogenation over Rh/SiO2
I. A. Fisher (1996)
10.1007/s11144-012-0459-8
CO2 hydrogenation over Co/Al2O3 catalysts prepared via a solid-state reaction of fine gibbsite and cobalt precursors
Natpakan Srisawad (2012)
10.1007/s11144-011-0378-0
Ni–Al layered double hydroxides as catalyst precursors for CO2 removal by methanation
M. Gabrovska (2011)
10.1021/JP405745N
Surface Composition Changes of Redox Stabilized Bimetallic CoCu Nanoparticles Supported on Silica under H2 and O2 Atmospheres and During Reaction between CO2 and H2: In Situ X-ray Spectroscopic Characterization
S. Alayoglu (2013)
10.1016/0021-9517(92)90122-X
Effect of alloying on CO hydrogenation activity over SiO2-supported CoNi alloy catalysts
T. Ishihara (1992)
10.1016/0021-9517(78)90143-4
Hydrogenation of CO and CO2 over iron foils: Correlations of rate, product distribution, and surface composition
D. J. Dwyer (1978)
10.1007/S11244-007-0232-9
Discovery of technical methanation catalysts based on computational screening
J. Sehested (2007)
10.1007/S11144-011-0336-X
Cu/Cr2O3·3Al2O3 and Au–Cu/Cr2O3·3Al2O3 catalysts for methanol synthesis and water gas shift reactions
P. Mierczyński (2011)
10.1021/ja412447q
Evidence of highly active cobalt oxide catalyst for the Fischer-Tropsch synthesis and CO2 hydrogenation.
Gérôme Melaet (2014)
10.1016/J.JCAT.2010.12.015
CO2 methanation on Ru-doped ceria
S. Sharma (2011)
10.1039/B814009J
Inhibition of methane formation in steam reforming reactions through modification of Ni catalyst and the reactants
X. Hu (2009)
10.1016/J.CATCOM.2013.04.025
Fractional-hydrolysis-driven formation of non-uniform dopant concentration catalyst nanoparticles of Ni/CexZr1 − xO2 and its catalysis in methanation of CO2
Cai Wei (2013)
10.1007/s11144-013-0587-9
Methanol synthesis from CO2 hydrogenation over copper based catalysts
H. Ahouari (2013)
10.1016/0021-9517(86)90359-3
Effect of Support and Promoter in Fischer‐Tropsch Cobalt Catalysts
B. Viswanathan (1986)
10.1016/J.APCATA.2012.03.029
Pruning of the surface species on Ni/Al2O3 catalyst to selective production of hydrogen via acetone and acetic acid steam reforming
Xun Hu (2012)
10.1016/J.BIOMBIOE.2009.12.013
Hydrogen generation from liquid reforming of glycerin over Ni-Co bimetallic catalyst.
Nianjun Luo (2010)
10.1016/J.IJGGC.2009.09.012
CO2 recycling by reaction with renewably-generated hydrogen
S. K. Hoekman (2010)
10.1007/S11144-011-0311-6
Effect of pressure on the mechanisms of the CO2/H2 reaction on a CO-precipitated CuO/ZnO/Al2O3 catalyst
Rachid Sahki (2011)
10.1016/0926-860X(96)00143-3
Structure/activity relationships in coprecipitated nickel-alumina catalysts using CO2 adsorption and methanation
A. E. Aksoylu (1996)
10.1016/J.APCATB.2007.07.029
Effect of Co content on the catalytic activity of CoSiBEA zeolite in the selective catalytic reduction of NO with ethanol : Nature of the cobalt species
Janusz Janas (2007)
10.1016/J.APCATA.2009.09.026
Ni, Co and bimetallic Ni–Co catalysts for the dry reforming of methane
D. San-Jose-Alonso (2009)
10.1016/J.JALLCOM.2009.10.273
Magnetic field-assisted solvothermal assembly of one-dimensional nanostructures of Ni–Co alloy nanoparticles
M. Wu (2010)
10.1016/J.APCATB.2011.11.043
CO2 hydrogenation at low temperature over Rh/gamma-Al2O3 catalysts: effect of the metal particle size on catalytic performances and reaction mechanism
Alejandro Karelovic Burotto (2012)
10.1021/nl300973b
Size-controlled model Co nanoparticle catalysts for CO₂ hydrogenation: synthesis, characterization, and catalytic reactions.
Viacheslav Iablokov (2012)
10.1016/J.IJHYDENE.2010.09.053
Interaction between a bimetallic Ni–Co catalyst and micrometer-sized CaO for enhanced H2 production during cellulose decomposition
M. Zhao (2011)
10.1016/J.APCATB.2009.12.014
Supported cobalt oxide on MgO: Highly efficient catalysts for degradation of organic dyes in dilute solutions
W. Zhang (2010)
10.1016/J.JCAT.2007.05.004
Development of stable bimetallic catalysts for carbon dioxide reforming of methane
Jian-guo Zhang (2007)
10.1016/0021-9517(87)90220-X
Catalytic activation of cobalt induced by oxidizing treatments in the methanation of carbon dioxide
A. Jnioui (1987)
10.1002/AIC.14026
Catalytic Methanation of Carbon Dioxide by Active Oxygen Material CexZr1−xO2 Supported NiCo Bimetallic Nanocatalysts
H. Zhu (2013)
10.1007/S10562-004-7931-7
Carbon Monoxide Hydrogenation over Zirconia Supported Ni and Co-Ni Bimetallic Catalysts
P. C. Das (2004)
10.1016/J.CATCOM.2005.08.005
Effect of tetragonal ZrO2 on the catalytic activity of Ni/ZrO2 catalyst prepared from amorphous Ni–Zr alloys
M. Yamasaki (2006)
10.1021/CS3005242
Catalytic Conversion of Carbon Dioxide to Methane on Ruthenium–Cobalt Bimetallic Nanocatalysts and Correlation between Surface Chemistry of Catalysts under Reaction Conditions and Catalytic Performances
Y. Zhu (2012)
10.1016/S0926-860X(02)00493-3
Preparation of Ni/SiO2 catalyst with high thermal stability for CO2-reforming of CH4
S. Tomiyama (2003)
10.1016/J.APCATA.2012.01.002
Steam reforming of acetic acid over Ni/ZrO2 catalysts: Effects of nickel loading and particle size on product distribution and coke formation
Zhikun Li (2012)
10.1039/C3CY00355H
Enhanced low-temperature activity of CO2 methanation over highly-dispersed Ni/TiO2 catalyst
J. Liu (2013)
10.1016/J.JPOWSOUR.2007.10.039
Preparation and characterization of coke resistant Ni/SiO2 catalyst for carbon dioxide reforming of methane
Yun-Xiang Pan (2008)
10.1016/J.IJHYDENE.2011.01.064
Hydrogen production from carbon dioxide reforming of methane over Ni–Co/MgO–ZrO2 catalyst: Process optimization
Mun-Sing Fan (2011)
10.1016/0021-9517(84)90196-9
Hydrogenation of CO2 on group VIII metals: IV. Specific activities and selectivities of silica-supported Co, Fe, and Ru
G. D. Weatherbee (1984)
10.1007/s11144-013-0592-z
Effect of calcination temperature during the synthesis of Co/Al2O3 catalyst used for the hydrogenation of CO2
Taraknath Das (2013)
10.1021/JP106551R
Catalytic CO2 Hydrogenation on Nickel: Novel Insight by Chemical Transient Kinetics†
E. Vesselli (2011)
10.1007/s11144-012-0441-5
Effect of Zr and pH in the preparation of Cu/ZnO catalysts for the methanol synthesis by CO2 hydrogenation
Heondo Jeong (2012)
10.1016/J.JCAT.2005.03.011
Titania-supported cobalt and nickel bimetallic catalysts for carbon dioxide reforming of methane
Kazuhiro Takanabe (2005)



This paper is referenced by
10.1016/J.IJHYDENE.2019.03.259
Effective encapsulation of Ni nanoparticles in metal-organic frameworks and their application for CO2 methanation
M. Mihet (2019)
10.1016/J.IJHYDENE.2018.02.139
Synthesis and characterization of Zr-promoted Ni-Co bimetallic catalyst supported OMC and investigation of its catalytic performance in steam reforming of ethanol
Vahid Shahed Gharahshiran (2018)
10.1016/J.APSUSC.2016.12.073
Effect of transition metal-doped Ni(211) for CO dissociation: Insights from DFT calculations
Kuiwei Yang (2017)
10.5772/65407
Recent Advances in Heterogeneous Catalytic Hydrogenation of CO2 to Methane
Zuzeng Qin (2017)
10.1039/C4RA16114A
Recent advances in methanation catalysts for the production of synthetic natural gas
J. Gao (2015)
10.1007/s11144-017-1213-z
Catalytic methanation in a slurry-bed reactor over Ni/SiO2 catalysts: improvement by ZrO2 and β-cyclodextrin addition
X. Li (2017)
10.1016/J.JECHEM.2016.03.009
Catalytic carbon dioxide hydrogenation to methane: A review of recent studies
Xiong Su (2016)
10.1039/C7RA01673E
Alkaline-promoted Ni based ordered mesoporous catalysts with enhanced low-temperature catalytic activity toward CO2 methanation
Leilei Xu (2017)
10.5772/63314
Metal Nanoparticles as Emerging Green Catalysts
A. Alshammari (2016)
10.1016/J.JCAT.2016.09.027
Selective hydrogenation of biomass-derived 2(5H)-furanone over Pt-Ni and Pt-Co bimetallic catalysts: From model surfaces to supported catalysts
X. Li (2016)
10.1016/J.IJHYDENE.2019.04.119
Elucidation of cobalt disturbance on Ni/Al2O3 in dissociating hydrogen towards improved CO2 methanation and optimization by response surface methodology (RSM)
N.A.A. Fatah (2020)
10.1016/J.IJHYDENE.2018.01.132
Cobalt doped Ni based ordered mesoporous catalysts for CO2 methanation with enhanced catalytic performance
Q. Liu (2018)
10.1016/j.jenvman.2018.04.034
New Ni-based quaternary disk-shaped catalysts for low-temperature CO2 methanation: Fabrication, characterization, and performance.
Dea Hyun Moon (2018)
10.1016/J.IJHYDENE.2018.07.106
CO2 methanation over CoNi bimetal-doped ordered mesoporous Al2O3 catalysts with enhanced low-temperature activities
Leilei Xu (2018)
10.1016/J.CATTOD.2016.12.001
Methanation of CO2 on Ni/γ-Al2O3: Influence of Pt, Pd or Rh promotion
M. Mihet (2016)
10.1016/J.IJHYDENE.2019.03.276
Bimetallic NiPd/SBA-15 alloy as an effective catalyst for selective hydrogenation of CO2 to methane
Y. Li (2019)
10.3390/nano11010028
Bimetallic Ni-Based Catalysts for CO2 Methanation: A Review
Anastasios I Tsiotsias (2020)
10.1016/J.IJHYDENE.2015.09.063
Modulating and controlling active species dispersion over Ni–Co bimetallic catalysts for enhancement of hydrogen production of ethanol steam reforming
X. Zhao (2016)
10.1039/C7NJ01598D
Co-P/graphene alloy catalysts doped with Cu and Ni for efficient photocatalytic hydrogen generation
Wenlong Zhen (2017)
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