Online citations, reference lists, and bibliographies.
← Back to Search

Spectroscopic Characterization Of Surface Species Derived From HCOOH, CH3COOH, CH3OH, C2H5OH, HCOOCH3, And C2H2 On MgO Thin Film Surfaces

X. Peng, M. Barteau
Published 1989 · Chemistry

Cite This
Download PDF
Analyze on Scholarcy
Share
Abstract Neutralization of surface charge and determination of an appropriate binding energy reference are among the difficulties in characterizing adsorbates on insulator surfaces with electron spectroscopies. In the present study, the surface charging problem associated with insulating MgO was circumvented by using MgO thin films formed on the Mg(0001) surface by O 2 adsorption. XPS and UPS spectra were obtained from HCOOH, CH 3 COOH, CH 3 OH, C 2 H 5 OH, HCOOCH 3 , and C 2 H 2 adsorbed on the MgO thin film at temperatures ranging from 170 to 550 K. The adsorption states of these molecules at different temperatures were essentially consistent with those reported on MgO powders and characterized by other techniques, indicating that MgO thin films provide good models of bulk MgO, with distinct advantages for electron spectroscopic studies.
This paper references
10.1016/0022-2860(82)85346-5
The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis
D. King (1981)
10.1016/b978-0-12-683250-1.x5001-9
Solid acids and bases
K. Tanabe (1970)
10.1016/0039-6028(75)90328-3
X-ray photoelectron studies of the reaction of clean metals (Mg, Al, Cr, Mn) with oxygen and water vapour
J. Fuggle (1975)
ESCA applied to free molecules
K. Siegbahn (1969)
10.1016/0039-6028(81)90045-5
XPS, UPS and thermal desorption studies of the reactions of formaldehyde and formic acid with the Cu(110) surface
M. Bowker (1981)
10.1016/0039-6028(85)90368-1
Methoxylation of magnesium studied by direct recoil spectroscopy, SIMS and XPS: Calibration of relative surface hydrogen concentration
J. Schultz (1985)
10.1016/0378-5963(80)90113-0
X-ray photoelectron spectroscopic study for the adsorption of acetic acid and ethylenediamine on iron and nickel
K. Kishi (1980)
10.1016/0378-5963(78)90023-5
The decomposition of ethanol, propanol and acetic acid chemisorbed on magnesium oxide
S. Parrott (1978)
10.1016/S0039-6028(87)81161-5
Adsorption of HCOOH on Rh(111) and its reaction with preadsorbed oxygen
F. Solymosi (1987)
10.1016/0039-6028(85)90797-6
UPS spectra of H2O, CH3OH and C5H9OH adsorbed onto Cu(111)/Na and Na(cp)
Jan Paul (1985)
10.1016/S0039-6028(87)80624-6
Formation of magnesium nitride layers on the Mg(0001) surface by ion implantation
X. Peng (1987)
10.1016/0378-5963(80)90100-2
A study of the interaction of formic acid and propionic acid with oxidised lead and copper surfaces by photoelectron spectroscopy and LEED
S. A. Isa (1980)
10.1021/LA00088A031
Adsorption of formaldehyde on model magnesia surfaces: evidence for the Cannizzaro reaction
X. Peng (1989)
10.1039/TF9716700854
Adsorption and desorption of methyl alcohol on magnesium oxide
A. J. Tench (1971)
10.1016/0039-6028(82)90415-0
Acetylenic complex formation and displacement via acid-base reactions on Ag(110)
M. Barteau (1982)
10.1039/F19787402092
Correlation between results of X-ray photoelectron spectroscopic studies and catalytic behaviour of MgO
H. Vinek (1978)
10.1016/0039-6028(84)90448-5
The catalytic decomposition of methanol on iron foil: I. Steady state flux experiments with photoelectron spectroscopy
F. Steinbach (1984)
10.1021/J100302A025
Structure sensitivity and selectivity of proton abstraction from alkynes on the polar faces of zinc oxide
J. Vohs (1987)
10.1016/S0039-6028(87)81192-5
Adsorption of Na atoms and oxygen-containing molecules on MgO(100) and (111) surfaces
H. Onishi (1987)
10.1016/0039-6028(77)90348-X
Chemisorption and decomposition reactions of oxygen-containing organic molecules on clean Pd surfaces studied by UV photoemission
H. Lüth (1977)
10.1016/0039-6028(80)90135-1
XPS, UPS and thermal desorption studies of alcohol adsorption on Cu(110): I. Methanol
M. Bowker (1980)
10.1021/LA00065A014
Adsorption and thermal decomposition of methanol on magnesium oxide. Carbon-13 NMR studies
S. H. Liang (1985)
10.1016/0378-5963(81)90125-2
The adsorption and oxidation of acetic acid and acetaldehyde on Cu(110)
M. Bowker (1981)
10.1016/0021-9517(77)90173-7
Thermal decomposition of methanol adsorbed on magnesia
D. Foyt (1977)
10.1016/0039-6028(85)90082-2
The adsorption and reactions of methanol on clean and oxidised aluminium surfaces
Ian F. Tindall (1985)
10.1021/LA00066A009
Synthesis and Reactivity of Thin Oxide Films on the Mg(001) Surface
R. Martínez (1985)
10.1021/IC00146A022
Formation of paramagnetic adsorbed molecules on thermally activated magnesium and calcium oxides. Characteristics of the active surface sites
R. M. Morris (1983)
10.1016/0378-5963(81)90094-5
Adsorption of oxygen on the magnesium (0001) surface studied by XPS
J. Ghijsen (1981)
10.1016/0039-6028(89)90723-1
Reactions of methanol on TiO2(001) single crystal surfaces
K. S. Kim (1989)
10.1016/0039-6028(82)90150-9
A study of the relative brönsted acidities of surface complexes on Ag(110)
M. Barteau (1982)
10.1088/0031-8949/2/1-2/014
Molecular Spectroscopy by Means of ESCA III. Carbon compounds
U. Gelius (1970)
10.1016/0254-0584(88)90015-6
Formation of well-defined MgO layers
M. Barteau (1988)
10.1016/0039-6028(88)90576-6
Spectroscopic characterization of surface formates produced via reaction of HCOOH and HCOOCH3 on the (0001) surface of zinc oxide
J. Vohs (1988)
10.1016/0169-4332(87)90143-7
Infrared studies of methanol adsorbed on magnesium oxide
J. Kondo (1987)
10.1016/0167-5729(87)90007-0
Core-level binding-energy shifts at surfaces and in solids
W. F. Egelhoff (1987)
10.1016/0039-6028(88)90499-2
Reaction pathways and intermediates in the decomposition of acetic and propionic acids on the polar surfaces of zinc oxide
J. Vohs (1988)
10.1016/0039-6028(85)90324-3
AES and UPS studies of CO and CO2 adsorption on Mg and MgO
Y. Fukuda (1985)



This paper is referenced by
10.1016/S0039-6028(99)01030-4
Ethanol reactions over the UO2(111) single crystal: effect of the Madelung potential on the reaction selectivity
S. V. Chong (2000)
10.1063/1.467404
An ab initio molecular orbital study on adsorption at the MgO surface. II. Site dependence of hydrogen chemisorption on the (MgO)4,6,8 clusters
K. Sawabe (1994)
10.1016/S1571-0785(97)80013-2
Chapter 10 Chemical and spectroscopic studies of ultrathin oxide films
S. Street (1997)
10.1016/S0920-5861(00)00470-3
The influence of surface defects on ethanol dehydrogenation versus dehydration on the UO2(1 1 1) surface
S. V. Chong (2000)
10.1021/cr300228z
Theoretical approaches to excited-state-related phenomena in oxide surfaces.
C. Sousa (2013)
10.1021/JP500605T
Etch-Resistant Zn1–xMgxO Alloys: An Alternative to ZnO for Carboxylic Acid Surface Modification
Thomas M Brenner (2014)
10.1007/BF00770896
Carboxylic acid adsorption on NiO(100) characterized by X-ray photoelectron and high resolution electron energy loss spectroscopies
K. Wulser (1992)
10.1016/S0039-6028(01)01600-4
Partial oxidation of methanol to formaldehyde on a model supported monolayer vanadia catalyst: vanadia on TiO2(110)
Qinggen Wang (2002)
10.1016/0039-6028(92)90226-V
Kinetics of desorption, adsorption, and surface diffusion of CO2 on MgO(100)
D. Meixner (1992)
10.1063/1.469227
Adsorption and reaction of CH3COOH and CD3COOD on the MgO(100) surface: A Fourier transform infrared and temperature programmed desorption study
C. Xu (1995)
10.1021/acsami.5b04107
Tuning Acid-Base Properties Using Mg-Al Oxide Atomic Layer Deposition.
David H. K. Jackson (2015)
10.1016/0021-9517(91)90082-F
The active phase in sodium-doped calcium oxide catalysts for oxidative coupling of methane
X. Peng (1991)
10.1063/1.4892591
Effects of rapid thermal annealing on properties of Ga-doped MgxZn1−xO films and Ga-doped MgxZn1−xO/AlGaN heterojunction diodes
Kuang-Po Hsueh (2014)
10.1016/0039-6028(90)90641-K
Characterization of oxide layers on Mg(0001) and comparison of H2O adsorption on surface and bulk oxides
X. Peng (1990)
10.1016/0039-6028(92)90847-Y
SIMS study of Cs/MoS2(0001). III: Chemisorption of acetone, propanal, 2-propanol and pyridine
M. Karolewski (1989)
10.1117/12.842643
Physical properties of MgZnO film grown by RF magnetron sputtering using ZnO/MgO (80/20 wt%) target
Kuang-Po Hsueh (2010)
10.1007/BF00770893
Acid/base properties of MgO studied by high resolution electron energy loss spectroscopy
Ming-Cheng Wu (1992)
10.1117/12.891269
Physical properties of Al-doped MgZnO film grown by RF magnetron sputtering using ZnO/MgO/Al2O3 target
Kuang-Po Hsueh (2011)
10.1116/1.3442476
Effect of rapid thermal annealing on MgxZn1−xO films prepared by radio-frequency magnetron sputtering
Kuang-Po Hsueh (2010)
10.1007/BF00764930
Dehydration of carboxylic acids on the MgO(100) surface
X. Peng (1990)
10.1016/0009-2614(91)87194-G
CO2 activation and reaction with hydrogen on Ni(110): formate formation
J. Wambach (1991)
10.1016/0039-6028(93)90590-G
Characterization by SIMS of Brønsted acid chemisorption on MgO(100) and Cs/MgO(100)
M. Karolewski (1993)
10.1049/IET-GTD.2016.1995
Transformer oil reclamation by combining several strategies enhanced by the use of four adsorbents
L. Safiddine (2017)
10.1186/s40563-016-0063-7
Implementation of diverse non-centrosymmetric layer concepts for tuning the interface activity of a magnesium alloy
Stephani Stamboroski (2016)
10.1016/0039-6028(94)00491-9
Adsorption of acetic acid on hydroxylated NiO(111) thin films
M. Langell (1994)
10.1016/S0039-6028(97)00192-1
The kinetics and mechanism of methanol synthesis by hydrogenation of CO2 over a Zn-deposited Cu(111) surface
T. Fujitani (1997)
10.1007/S00339-012-6815-8
Unipolar resistive switching in Au/Cr/Mg0.84Zn0.16O2−δ/p+-Si
Jing Qi (2012)
10.1016/J.MATCHEMPHYS.2018.08.052
Facile synthesis of rod-shaped bismuth sulfide@graphene oxide (Bi2S3@GO) composite
N.-G. García-Peña (2018)
10.1002/JEMT.1070200412
Preparation and characterization of MgO surfaces by reflection electron microscopy
P. Crozier (1992)
10.1016/0039-6028(94)90807-9
Formic acid decomposition on SnO2(110)
Victoria A. Gercher (1994)
10.1016/S1381-1169(99)00297-6
Reactions of ethanol over metal oxides
H. Idriss (2000)
10.1016/S0584-8547(00)00222-6
Stability of hydroxy-formate species at a Pb(110) surface
B. Afşin (2000)
See more
Semantic Scholar Logo Some data provided by SemanticScholar