Online citations, reference lists, and bibliographies.
← Back to Search

An Electrically-conductive Composite Prepared By Electrochemical Polymerization Of Pyrrole Into Polyurethane

Xiantong Bi, Q. Pei
Published 1987 · Materials Science

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Abstract A study of the electrochemical preparation of conductive composite films from polypyrrole and non-conducting polyurethane resin is presented. Pyrrole and dopants can penetrate through a polyurethane substrate (precoated on a Pt electrode by casting) and electropolymerize on the Pt surface due to the swelling of the coating by the electrolyte solution (dry acetonitrile mixed with ethylene glycol). Cyclic voltammograms show that the diffusion process in polyurethane is inhibited for larger anions. The electrical conductivity of the composites falls in the range 1–35 S/cm and is influenced by the electropolymerization conditions (electrode potential, reaction time, type of supporting electrolyte, etc.). The mechanical properties of the composites resemble those of pure polyurethane. Scanning electron micrographs, FT infrared spectra and other experiments indicate that polypyrrole is dispersed in the polyurethane matrix like a net with unusually thickset ‘knots’.
This paper references
10.1021/MA00154A005
Poly(pyrrol-2-ylium tosylate), electrochemical synthesis and physical and mechanical properties
K. Wynne (1985)
10.1016/0379-6779(87)90846-0
Conducting polypyrrole electrochemically prepared from aqueous solutions
R. Qian (1987)
10.1016/0379-6779(84)90080-8
Conductive composites from polyvinyl alcohol and polypyrrole
S. Lindsey (1984)
10.1149/1.2108568
Electronically Conductive Composite Polymer Membranes.
R. Penner (1986)
10.1016/0379-6779(86)90042-1
Dependences of electrical and mechanical properties of conducting polypyrrole films on conditions of electrochemical polymerization in an aqueous medium
M. Satoh (1986)
10.1039/C39840000946
Composites of conducting polymers: polyacetylene–polypyrrole
G. Ahlgren (1984)
10.1016/S0022-0728(81)80008-3
Electrochemistry of conducting polypyrrole films
A. F. Diaz (1981)
10.1039/C39850000871
Flexible and heat-processable conductive films of polypyrrole
N. Bates (1985)
10.1002/JBM.820200403
Ex vivo interactions and surface property relationships of polyetherurethanes.
M. Lelah (1986)
10.1016/0379-6779(81)90027-8
Electrical properties of pyrrole and its copolymers
K. Kanazawa (1981)
10.1149/1.2108566
Polymer Films on Electrodes XIX . Electrochemical Behavior at Polypyrrole‐Nafion and Polypyrrole‐Clay Thin Films on Glassy Carbon Electrodes
F. R. Fan (1986)
The development and use of polyurethane products
E. N. Doyle (1971)
10.1143/JJAP.24.L423
Highly Conducting Polypyrrole Prepared by Electrochemical Oxidation Method in Aqueous Solution
M. Satoh (1985)
10.1016/0379-6779(86)90021-4
Electrochemical polymerization of pyrrole in the presence of latexes
S. Jasne (1986)
10.1039/C39850000375
Pyrrole–styrene graft copolymers
A. Nazzal (1985)
10.1147/RD.274.0342
Mechanical properties of electrochemically prepared polypyrrole films
A. F. Diaz (1983)
10.1139/V86-015
Electrically conducting polymers: a review of the electropolymerization reaction, of the effects of chemical structure on polymer film properties, and of applications towards technology
R. Waltman (1986)
10.1039/C39790000635
Electrochemical polymerization of pyrrole
A. F. Diaz (1979)
10.1039/C39840000817
Electrochemical polymerization of pyrrole on polymer-coated electrodes
O. Niwa (1984)
10.1002/MACP.1985.021860520
Studies on electrochemically prepared oxidized polypyrrole salt films
Xiangtong Bi (1985)
10.1002/POL.1985.170230610
An electrically conductive plastic composite derived from polypyrrole and poly(vinyl chloride)
M. D. Paoli (1985)
10.1149/1.2124000
Polymer Films on Electrodes VII . Electrochemical Behavior at Polypyrrole‐Coated Platinum and Tantalum Electrodes
R. A. Bull (1982)



This paper is referenced by
10.1007/978-3-319-69378-1_27
Introducing Conducting Polymers (CPs)
P. Chandrasekhar (2018)
10.1016/J.COMPOSITESA.2006.02.008
The conductive polyaniline/poly(ethylene terephthalate) composite fabrics
S. Kutanis (2007)
10.1002/APP.23326
Preparation and characterization of conducting poly(diphenylamine) entrapped polyurethane network electrolyte
P. Santhosh (2006)
10.1007/978-3-319-69378-1_39
Displays, Including Light-Emitting Diodes (LEDs) and Conductive Films
P. Chandrasekhar (2018)
10.1016/0022-0728(89)87132-3
Electrochemically controlled binding and release of protonated dimethyldopamine and other cations from poly( N-methyl-pyrrole)/polyanion composite redox polymers
Qin-Xin Zhou (1989)
10.1007/978-3-319-69378-1_11
CNT Applications in Microelectronics, “Nanoelectronics,” and “Nanobioelectronics”
P. Chandrasekhar (2018)
10.1016/0379-6779(89)90616-4
Polyheterocyclic conducting polymers and composites derivates
J. Dubois (1989)
Modeling, Design and Fabrication of Biocompatible Silk-Based Electronics and Actuators
Nicholas A Ostrovsky-Snider (2017)
10.1002/PEN.11844
Conductive polymer blends prepared by in situ polymerization of pyrrole: A review
M. Jesus (1997)
10.1002/(SICI)1097-4628(20000314)75:11<1385::AID-APP10>3.0.CO;2-Q
Carboxylated polyurethane anionomers and their composites with polypyrrole
Gabriela Robil (2000)
10.1007/978-3-319-69378-1_37
Batteries and Energy Devices
P. Chandrasekhar (2018)
10.1557/PROC-247-699
Electrically Conductive Composite of Polypyrrole and Liquid Crystalline Aromatic Copolyamide
Jing-Sheng Bao (1992)
10.1007/978-3-319-69378-1_14
CNT Applications in the Environment and in Materials Used in Separation Science
P. Chandrasekhar (2018)
10.1016/S0014-3057(97)00181-X
Conducting composite films based on polypyrrole and crosslinked poly(methyl acrylate-co-hydroxyethyl acrylate)
Wusheng Yin (1998)
10.1007/978-3-319-69378-1_4
Physical, Mechanical, and Thermal Properties of CNTs
P. Chandrasekhar (2018)
10.1109/57.285420
Update on electrically conductive polymers and their applications
K. F. Schoch (1994)
10.1007/978-3-319-69378-1_10
CNT Applications in Drug and Biomolecule Delivery
P. Chandrasekhar (2018)
10.1007/978-3-319-69378-1_32
Structural Aspects and Morphology of CPs
P. Chandrasekhar (2018)
10.1016/0168-583X(95)00556-0
Polymerization of pyrrole into track membranes
N. I. Zhitariuk (1995)
10.1007/978-3-319-69378-1_3
Synthesis, Purification, and Chemical Modification of CNTs
P. Chandrasekhar (2018)
10.1007/978-3-319-69378-1_30
Basic Electrochemistry of CPs
P. Chandrasekhar (2018)
10.1002/APP.20536
Flexible and conducting composites of polypyrrole and polydimethylsiloxane
Gueliz Cakmak (2004)
10.1016/0379-6779(94)90225-9
Electrodeposition of pyrrole into a porous film prepared by microemulsion polymerization
David A. Kaplin (1994)
10.1007/978-3-319-69378-1_15
Miscellaneous CNT Applications
P. Chandrasekhar (2018)
10.1007/978-3-319-69378-1_41
Electro-Optic and Optical Devices
P. Chandrasekhar (1999)
10.1002/PC.750120410
The electromagnetic interference shielding of polypyrrole impregnated conducting polymer composites
E. Ruckenstein (1991)
10.1002/APP.1225
Conducting composite film based on polypyrrole and crosslinked cellulose
Wusheng Yin (2001)
10.1007/978-3-319-69378-1_31
Syntheses and Processing of CPs
P. Chandrasekhar (2018)
10.1007/978-3-319-69378-1_34
Classes of CPs: Part 1
P. Chandrasekhar (1999)
10.1007/BF02655838
Conducting polyheterocycle composites based on porous hosts
J. Park (1992)
10.1016/0379-6779(93)90211-E
Electrochemical polymerization of pyrrole in polyesteramide matrix
G. P. Zhang (1993)
10.1007/978-3-319-69378-1_21
Graphene Applications in Batteries and Energy Devices
P. Chandrasekhar (2018)
See more
Semantic Scholar Logo Some data provided by SemanticScholar