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Progress Towards Organic Single-monolayer Rectifiers

R. Metzger, C. A. Panetta, Y. Miura, E. Torres
Published 1987 · Chemistry

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Abstract We outline our progress towards Langmuir-Blodgett (LB) monolayers of organic molecules that rectify electrical current (first proposed in 1973 by Aviram). LB monolayers of pyrene-carbamate-bromohydroxyethoxyTCNQ and of dodecyloxyphenyl-carbamate-bromohydroxyethoxyTCNQ have been obtained, but a proper test of their rectification could not be made. Faster and more efficient routes to TCNQ-like monofunctionalized acceptors show considerable promise.
This paper references
10.1080/00268948408072077
TTF-NHCO2(Ce2)2 O-TCNQBr and TTF-Co2(Ch2)2 O-TCNQBR, Two Potential Molecular Rectifiers
C. A. Panetta (1984)
10.1051/JPHYSCOL/1983074
PROGRESS IN COHESIVE ENERGIES, AND IN BUILDING ORGANIC UN IMOLECULAR RECTIFIERS
R. Metzger (1983)
10.1021/JO00870A027
Charge-transfer polymers containing 7,7,8,8-tetracyanoquinodimethan and tetrathiafulvalene
W. Hertler (1976)
10.1246/CL.1985.689
PREPARATION OF 7,7,8,8-TETRACYANOQUINODIMETHANE AND ITS DERIVATIVES
S. Yamaguchi (1985)
10.1021/JA00351A054
Strategic design of organic conductors. Structure of a prototypical molecule
J. Becker (1983)
10.1039/DF9602900021
Exchange reactions and electron transfer reactions including isotopic exchange. Theory of oxidation-reduction reactions involving electron transfer. Part 4.—A statistical-mechanical basis for treating contributions from solvent, ligands, and inert salt
R. Marcus (1960)
10.1351/pac198855020323
Charge transfer transition for symmetry-forbidden charge transfer interaction. Theory and experimental verification
I. Murata (1983)
10.1109/T-ED.1983.21337
I-1 fine line MOS technology for high speed integrated circuits
G. Smith (1983)
10.1080/00268948508075810
Novel Conducting LB Films
A. Ruaudel-Teixier (1985)
10.1109/T-ED.1983.21347
IIA-7 ultra high speed integrated circuits using GaAs/GaAlAs high electron mobility transistors
C.P. Lee (1983)
10.1021/JA00289A006
New synthesis and properties of 11,11,12,12-tetracyano-9,10-anthraquinodimethane: an electron acceptor displaying a single-wave, two-electron reduction and a coproportionation pathway to the radical anion
A. Kini (1985)
10.1021/JA00322A058
Intramolecular long-distance electron transfer in radical anions. The effects of free energy and solvent on the reaction rates
J. Miller (1984)
10.1016/0040-6090(80)90144-3
Monolayer assemblies with functional units of sensitizing and conducting molecular components: Photovoltage, dark conduction and photoconduction in systems with aluminium and barium electrodes
E. E. Polymeropoulos (1980)
10.1021/ja00341a084
Fast intramolecular electron transfer in radical ions over long distances across rigid saturated hydrocarbon spacers
L. T. Calcaterra (1983)



This paper is referenced by
10.1016/0379-6779(91)91868-B
Langmur-Blodgett films of potential organic rectifiers: New scanning tunneling microscopy and non-linear optics results
R. Metzger (1991)
10.1063/1.351340
The electrical properties of metal‐sandwiched Langmuir–Blodgett multilayers and monolayers of a redox‐active organic molecular compound
N. Geddes (1992)
10.1016/S0040-4039(97)10395-1
Direct thiophene arylation catalysed by Palladium
C. Gozzi (1997)
10.1081/MA-100108401
THE QUEST FOR UNIMOLECULAR RECTIFICATION FROM OXFORD TO WALTHAM TO EXETER TO TUSCALOOSA
R. Metzger (2001)
10.1049/IP-CDS:20040990
Towards individual molecules as electronic components
I. Peterson (2004)
10.1007/978-1-4899-2091-1_18
Langmuir-Blodgett Films of Donor-Sigma-Acceptor Molecules and Prospects for Organic Rectifiers
R. Metzger (1988)
10.1007/BF01185384
Crystal structure of DMAP-C-HMTCAQ, C30H20N6O2, N,N-dimethylaminophenyl-carbamate-2′-hydroxymethyl-11,11,12,12-tetracyano-anthraquinodimethan
R. Metzger (1989)
10.1007/978-1-4684-1348-9_60
Langmuir-Blodgett Films of Potential Organic Rectifiers
R. Metzger (1991)
10.1039/C39900001374
Rectifying characteristics of Mg|(C16H33-Q3CNQ LB film)|Pt structures
G. J. Ashwell (1990)
10.1039/A902863C
The unimolecular rectifier: unimolecular electronic devices are coming …
R. Metzger (1999)
10.1016/0040-6090(88)90642-6
Surface structure investigation of Langmuir-Blodgett films
H. Braun (1988)
10.1016/0928-4931(95)00060-7
D-σ-A unimolecular rectifiers
R. Metzger (1995)
10.1007/978-3-642-78677-8_5
Some Special Topics Relevant to Electrosynthesis
D. Kyriacou (1994)
10.1016/J.MATCHEMPHYS.2009.07.020
Characterization of electrodeposited polymeric and composite modified electrodes on cobalt based alloy
V. Brânzoi (2009)
10.1007/3-540-57565-0_74
RADICAL IONS - WHERE ORGANIC-CHEMISTRY MEETS MATERIALS SCIENCES
M. Baumgarten (1994)
10.1557/PROC-173-531
Langmuir-Blodgett Films of Potential Unidimensional Organic Rectifiers
R. Metzger (1989)
10.1007/s41061-017-0170-3
Towards Rectifying Performance at the Molecular Scale
G. Zhang (2017)
10.1196/annals.1292.018
Unimolecular Rectifiers and Proposed Unimolecular Amplifier
R. Metzger (2003)
10.1016/0009-2614(88)87486-4
Evidence of switching and rectification by a single molecule effected with a scanning tunneling microscope
A. Aviram (1989)
10.1016/0379-6779(89)90608-5
Possible rectification in Langmuir-Blodgett monolayers of organic D-σ-A molecules
R. Metzger (1989)
10.1007/978-1-4899-2088-1_72
Review of the Organic Rectifier Project: Langmuir-Blodgett Films of Donor- Sigma-Acceptor Molecules
R. Metzger (1990)
10.1039/c0cp02693j
Can azulene-like molecules function as substitution-free molecular rectifiers?
Kai-ge Zhou (2011)
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