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Oxidative Polymerization Of Poly(2-(N-pyrrolyl)ethyl Methacrylate) With Iron Chloride

Dietmar Stanke, M. L. Hallensleben, L. Toppare
Published 1995 · Chemistry

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Abstract Polymers 2 containing pyrrole in the side group were synthesized by radical polymerization of 2-( N -pyrrolyl)ethyl methacrylate 1 (PEMA). The PEMA units were coupled by oxidation with iron chloride in nitromethane. The polymers reached conductivities about 5 × 10 −5 S/cm upon doping with iodine. The polymers were further characterized using 1 H NMR, IR, gel permeation chromatography and thermogravimetric analysis.



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