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Carboxylic Esters And Lactones
Published 2005 · Chemistry
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There are an extremely large number of procedures for the synthesis of carboxylic esters and lactones. This review attempts to summarize some of the more useful techniques. For example, esters can be prepared by direct esterification using a carboxylic acid and an alcohol. The synthesis of lactones can be achieved using many of the procedures used in the formation of carboxylic esters. One of the most useful techniques for lactone synthesis is macrolactonization, and a large number of natural products have been synthesized using this approach.
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Facile Synthesis of 1-Adamantyl Esters of L-α-Amino Acids, a New Class of Carboxy Protected Derivatives
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Application of the intramolecular vinylogous Morita-Baylis-Hillman reaction toward the synthesis of the spinosyn A tricyclic nucleus.
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Formal total synthesis of salicylihalamides A and B.
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A general and stereoselective approach to nonactate esters and isomers: A versatile synthesis of (+)-methyl nonactate
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Total Asymmetric Synthesis of Taxol by Dehydration Condensation between 7-TES Baccatin III and Protected N-Benzoylphenylisoserines Prepared by Enantioselective Aldol Reaction
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N-(.alpha.-Ethoxyallyl)benzotriazole: A Novel Propenoyl Anion Synthon Route to Vinyl Ketones
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Palladium-catalyzed carbonylation of aryl bromides and iodides with potassium phenoxides
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Direct Oxidation of Acetals and Aldehydes to Esters
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Extremely Efficient Chiral Induction in Conjugate Additions of p-Tolyl α-Lithio-β-(trimethylsilyl)ethyl Sulfoxide and Subsequent Electrophilic Trapping Reactions.
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Ruthenium- and enzyme-catalyzed dynamic kinetic resolution of secondary alcohols
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A new access to alkyl-α-ketoglutaric acids, precursors of glutamic acid analogues by enzymatic transamination. Application to the synthesis of (2S,4R)-4-propyl-glutamic acid
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Catalytic Asymmetric Propionate Aldol Reactions via Acyl Halide-Aldehyde Cyclocondensations.
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K. Nagahara (1997)
Chromium-mediated β-lactone synthesis using ultrasonication
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Amino Acid Side Chain Attachment Approach and Its Application to the Synthesis of Tyrosine-Containing Cyclic Peptides
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Mechanism of Amine-Catalyzed Ester Formation from an Acid Chloride and Alcohol.
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A NOVEL AND EFFICIENT STEREOSELECTIVE SYNTHESIS OF THE SOUTHERN PART OF PAMAMYCIN-607
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Synthesis and Ring-Opening Polymerization of Poly(alkylene 2,6-naphthalenedicarboxylate) Cyclic Oligomers
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Utilisation of homogeneous and supported chiral metal(salen) complexes in asymmetric catalysis
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Synthesis of trifluoromethylated γ- and β-lactones through the palladium-catalyzed cyclocarbonylation
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Total synthesis of ustiloxin D.
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Selective Esterification of Nonconjugated Carboxylic Acids in the Presence of Conjugated or Aromatic Carboxylic Acids Under Mild Conditions
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Butoxycarbonylation of aryl halides catalyzed by a silica-supportedpoly[3-(2-cyanoethylsulfanyl)propylsiloxane palladium] complex
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Synthesis of 3,6-dihydro-2H-pyran-2-ones via cationic palladium(II) complex-catalyzed tandem [2+2] cycloaddition-allylic rearrangement of ketene with α,β-unsaturated aldehydes and ketones
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Palladium-Mediated Ring Closure Reactions. Facile Syntheses of Enantiopure Bicyclic and Tricyclic Alkenones
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Formal synthesis of (+)-discodermolide.
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Indium-mediated consecutive 1,2-shift reaction and regioselective allylation of vinyl epoxides
Byung Kyu Oh (2003)
Macrolactonization of hydroxy acids using a polymer bound carbodiimide
G. E. Keck (2000)
Studies in Lipase Catalyzed Transesterifications: Synthesis of (+)-Albicanol, (+)-Albicanyl Acetate and Chiral Intermediates Useful in the Synthesis of Drimanes and Labdanes
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Butylstannonic acid catalyzed transesterification of carboxylic esters
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Synthesis of the macrolide core of migrastatin
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Chemo-enzymatic synthesis of (R)-(+)-aminoglutethimide by kinetic resolution of (±)-4-cyano-4-phenyl-1-hexanol
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Synthesis and application of α-trifluoromethylated aldehydes
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