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Liquid Phase Aerobic Oxidation Of Benzyl Alcohol By Using Manganese Ferrite Supported-manganese Oxide Nanocomposite Catalyst

Gökhan Elmacı, Demet Ozer, B. Zümreoğlu-Karan
Published 2017 · Chemistry

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Abstract This study illustrates for the first time the performance of nano-manganese ferrite supported-manganese oxide catalyst in benzyl alcohol (BzOH) oxidation without employing any oxidizing agent other than the air present in the reactor. The magnetic catalyst displayed moderate activity but 100% selectivity in conversion to benzaldehyde (BzH) under mild conditions. Compared to the other heterogeneous MnO x -based systems, the catalyst deserves attention in that an enhancement of the activity can be achieved by tuning the core-shell composition which plays a synergistic role in the catalytic reaction.
This paper references
The role of lattice oxygen in selective benzyl alcohol oxidation using OMS-2 catalyst: A kinetic and isotope-labeling study
V. D. Makwana (2002)
Nano-iron oxide-catalyzed selective oxidations of alcohols and olefins with hydrogen peroxide
F. Shi (2008)
Morphology-Controlled Synthesis and Characterization of Magnetic Iron Oxide Nanocrystals and Their Potential Applications in Selective Oxidation of Alcohols and Olefins
S. Banerjee (2013)
Oxidation of 1,2- and 1,4-Dihydroxybenzene by Birnessite in Acidic Aqueous Suspension
M. Mcbride (1989)
Solid Manganese Dioxide as an Oxidizing Agent
R. Highet (1955)
Water oxidation catalysis by birnessite@iron oxide core-shell nanocomposites.
Gökhan Elmacı (2015)
Nanostructured MnOx catalysts in the liquid phase selective oxidation of benzyl alcohol with oxygen: Part I. Effects of Ce and Fe addition on structure and reactivity
F. Arena (2015)
Octahedral molecular sieves of the type K-OMS-2 with different particle sizes and morphologies: Impact on the catalytic properties in the aerobic partial oxidation of benzyl alcohol
Fanny Schurz (2009)
Oxidation of benzyl alcohol and carbon monoxide using gold nanoparticles supported on MnO2 nanowire microspheres.
Mosaed S. Alhumaimess (2014)
Tuning catalytic activity between homogeneous and heterogeneous catalysis: improved activity and selectivity of free nano-Fe2O3 in selective oxidations.
Feng Shi (2007)
Nanolayered manganese-calcium oxide as an efficient and environmentally friendly catalyst for alcohol oxidation
M. Amini (2014)
Enhanced catalytic activity of K-birnessite MnO2 confined in carbon nanotubes for selective oxidation of benzyl alcohol
M. Yang (2014)
Promoting role of bismuth on carbon nanotube supported platinum catalysts in aqueous phase aerobic oxidation of benzyl alcohol
Chunmei Zhou (2016)
Au25(SPh-pNH2)17 nanoclusters deposited on SBA-15 as catalysts for aerobic benzyl alcohol oxidation
Christophe Lavenn (2015)
Introduction to Magnetism and Magnetic Materials
D. Jiles (2015)
Large-scale size-controlled synthesis of cryptomelane-type manganese oxide OMS-2 in lateral and longitudinal directions
Q. Zhang (2011)
Encyclopedia of chemical technology
R. Kirk (1998)
Magnetic iron oxide nanoparticles embedded in SBA-15 silica wall as a green and recoverable catalyst for the oxidation of alcohols and sulfides
Hassan Atashin (2017)
Water-oxidation catalysis by synthetic manganese oxides--systematic variations of the calcium birnessite theme.
C. Frey (2014)
Liquid-phase aerobic oxidation of benzyl alcohol catalyzed by mechanochemically synthesized manganese oxide
Mohammad Ilyas (2013)
Catalytic performances of Mn–Ni mixed hydroxide catalysts in liquid-phase benzyl alcohol oxidation using molecular oxygen
Qinghu Tang (2011)
K-birnessite MnO2: a new selective oxidant for benzylic and allylic alcohols
A. Kamimura (2011)
Iron catalysis : fundamentals and applications
B. Plietker (2011)
Facile synthesis of Fe3O4 nanoparticles on metal organic framework MIL-101(Cr): characterization and catalytic activity
M. Saikia (2015)

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R. Tomar (2018)
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Modification of Au nanoparticles electronic state by MOFs defect engineering to realize highly active photocatalytic oxidative esterification of benzyl alcohol with methanol
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Magnetic Hollow Biocomposites Prepared from Lycopodium clavatum Pollens as Efficient Recyclable Catalyst
Gökhan Elmacı (2020)
Green and time-saving synthesis of MIL-100(Cr) and its catalytic performance
Ying Mao (2019)
Degradation of inkjet ink by greensand and ultrasonic sonification
M. Rožić (2017)
C-dots/Mn3O4 nanocomposite as an oxidase nanozyme for colorimetric determination of ferrous ion
Fatemeh Honarasa (2019)
Liquid phase oxidation of benzyl alcohol to benzaldehyde over chromium borophosphate catalyst synthesized by solution combustion method using different types of fuel
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