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Simultaneous Photocatalytic And Catalytic Activity Of P–n Junction NiO@anatase/rutile-TiO2 As A Noble-metal Free Reusable Nanoparticle For Synthesis Of Organic Compounds

A. Ziarati, Alireza Badiei, Ghodsi Mohammadi Ziarani, H. Eskandarloo
Published 2017 · Materials Science

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Abstract Photocatalytic and catalytic activity of NiO loaded on mixture of anatase/rutile phases of TiO 2 nanoparticles were investigated for some organic reactions including selective oxidation of alcohols, synthesis of benzimidazoles and preparation of imines at room temperature. The p–n junction formed between NiO and TiO 2 as well as difference between band gaps in anatase/rutile phases facilitated electron transfer to TiO 2 and successfully promoted synthesis of compounds. The use of a reusable photocatalyst without noble metal co-catalysts, along with the mild reaction conditions and use of light energy, make this method as an environmentally benign and energy saving chemical procedure.
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