Online citations, reference lists, and bibliographies.
Please confirm you are human
(Sign Up for free to never see this)
← Back to Search

Molecular Zinc Hydrides

Ann-Kristin Wiegand, Arnab Rit, J. Okuda
Published 2016 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Abstract An overview of structurally characterized molecular organozinc hydrides is given. The compounds are presented based on the type of supporting ligand. Their synthesis, structure, reactivity, and catalytic applications are summarized in this overview.
This paper references
10.1021/OM00001A041
Monomeric Alkyl and Hydride Derivatives of Zinc Supported by Poly(pyrazoly)hydroborato Ligation: Synthetic, Structural, and Reactivity Studies
Adrian Looney (1995)
10.1021/OM401000S
Reactions of CO2 with Heteroleptic Zinc and Zinc–NHC Complexes
Phillip Jochmann (2013)
10.1039/C39810000213
Hydrosilylation of carbon dioxide catalysed by ruthenium complexes
H. Koinuma (1981)
10.1039/J19680000823
Some amino- and oxy-beryllium hydrides: 2-dimethylaminoethyl(methyl)aminozinc hydride dimer
N. Bell (1968)
10.1002/anie.201404611
Accessing zinc monohydride cations through coordinative interactions.
P. Lummis (2014)
10.1002/chem.201402141
Comparison of hydrogen elimination from molecular zinc and magnesium hydride clusters.
Julia Intemann (2014)
10.1021/JA053860U
Hydrogen production from hydrolytic oxidation of organosilanes using a cationic oxorhenium catalyst.
E. A. Ison (2005)
10.1039/b922984a
Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry.
Hervé Clavier (2010)
10.1002/anie.201300749
Molecular zinc dihydride stabilized by N-heterocyclic carbenes.
Arnab Rit (2013)
10.1016/S0166-9834(00)84123-8
Mechanism of methanol synthesis from CO2/CO/H2 mixtures over copper/zinc oxide/alumina catalysts: use of14C-labelled reactants
G. Chinchen (1987)
10.1039/C3CY01065A
Reduction of bicarbonate and carbonate to formate in molecular zinc complexes
W. Sattler (2014)
10.1021/CS400581W
Unexpected Role of Zinc Hydride in Catalytic Hydrosilylation of Ketones and Nitriles
Courtney Boone (2013)
10.1002/anie.201303968
H2 cleavage, hydride formation, and catalytic hydrogenation of imines with zinc complexes of C5Me5 and N-heterocyclic carbenes.
Phillip Jochmann (2013)
10.1021/OM500190C
Mixed Alkyl Hydrido Complexes of Zinc: Synthesis, Structure, and Reactivity
Arnab Rit (2014)
10.1021/JA01197A061
Lithium Aluminum Hydride, Aluminum Hydride and Lithium Gallium Hydride, and Some of their Applications in Organic and Inorganic Chemistry1
A. E. Finholt (1947)
10.1134/S003602361414006X
Hydride compounds of zinc
K. Zhizhin (2014)
10.1021/ic50140a011
Reaction of alkali metal hydrides with zinc halides in tetrahydrofuran. Convenient and economical preparation of zinc hydride
J. Watkins (1974)
10.1023/A:1019181715731
The role of zinc oxide in Cu/ZnO catalysts for methanol synthesis and the water–gas shift reaction
M. S. Spencer (1999)
10.1039/c5dt00312a
Two alternative approaches to access mixed hydride-amido zinc complexes: synthetic, structural and solution implications.
A. J. Roberts (2015)
10.1021/ja2035706
Synthesis, structure, and reactivity of a mononuclear organozinc hydride complex: facile insertion of CO2 into a Zn-H Bond and CO2-promoted displacement of siloxide ligands.
W. Sattler (2011)
10.1021/OM900291X
Binuclear Zinc Complexes with Radical-Anionic Diimine Ligands
I. Fedushkin (2009)
10.1021/jp7103787
Homogeneous decomposition mechanisms of diethylzinc by Raman spectroscopy and quantum chemical calculations.
Y. Kim (2008)
10.1039/C39910000717
Tris(3-tert-butylpyrazolyl)hydroborato zinc hydride: synthesis, structure and reactivity of a monomeric zinc hydride derivative
R. Han (1991)
10.1021/IC961249D
Fluoro[eta(3)-hydrotris(3-R-5-methylpyrazol-1-yl)borato]zinc(II): The First TpZnF Complexes, Convenient Precursors to Zinc Hydride Complexes(,).
W. Klaeui (1997)
10.1021/OM060443X
Convenient access to homo- and heterobimetallic alkoxo hydridozinc clusters of formula [(HZnOtBu)4-n(LiOtBu)n] (n = 0, 1, 2, 3)
W. Marciniak (2006)
10.1039/c4cc03256j
The synthesis and structure of [Zn(TEMPO)2]2 and [Zn(μ-H)(μ(2)-η(1):η(1)-TEMPO)]6.
Phillip Jochmann (2014)
10.1002/(SICI)1521-3749(199810)624:10<1563::AID-ZAAC1563>3.0.CO;2-U
Kristallstruktur von [ZnH(NPMe3)]4, einem tetrameren Phosphaniminato‐Komplex des Zinks mit terminalen Hydrido‐Liganden
M. Krieger (1998)
10.1016/S0022-328X(00)91255-5
Preparation and characterization of the first stable organozinc hydride, PhZn2H3
E. C. Ashby (1977)
10.1002/ANIE.200462374
Active sites on oxide surfaces: ZnO-catalyzed synthesis of methanol from CO and H2.
M. Kurtz (2005)
10.1002/1099-0682(20021)2002:1<153::AID-EJIC153>3.0.CO;2-K
The Insertion of Heterocumulenes into Zn−H and Zn−OH Bonds of Pyrazolylborate−Zinc Complexes
M. Rombach (2002)
10.1002/EJIC.201200378
Reactivity of (β‐Diketiminato)zinc Hydride toward Lewis Bases, Heterocumulenes and Cyclohexene Oxide
G. Bendt (2012)
10.1021/JA072682X
Synthesis and characterization of the homologous M-M bonded series Ar'MMAr' (M = Zn, Cd, or Hg; Ar' = C6H3-2,6-(C6H3-2,6-Pr(i)2)2) and related arylmetal halides and hydride species.
Zhong-Liang Zhu (2007)
10.1039/c0cc01329c
Reactions of a β-diketiminate zinc hydride complex with heterocumulenes.
S. Schulz (2010)
10.1002/anie.200804224
An organozinc hydride cluster: an encapsulated tetrahydrozincate?
M. Coles (2008)
10.1021/JA9718477
Design, Reactivities, and Practical Application of Dialkylzinc Hydride Ate Complexes Generated in Situ from Dialkylzinc and Metal Hydride. A New Methodology for Activation of NaH and LiH under Mild Conditions
M. Uchiyama (1997)
10.1016/J.JORGANCHEM.2011.01.033
Synthesis and crystal structures of dinuclear zinc complexes with the 1,3-bis(2-pyridylmethyl)acetamidinato ligand
Marcel Kahnes (2011)
10.1021/om400679n
Mononuclear Phenolate Diamine Zinc Hydride Complexes and Their Reactions With CO2
N. Brown (2014)
10.1021/ja303440n
Remarkably robust monomeric alkylperoxyzinc compounds from tris(oxazolinyl)boratozinc alkyls and O2.
Debabrata Mukherjee (2012)
10.1016/S0022-328X(00)89864-2
Reactions of zinc hydride and magnesium hydride with pyridine; synthesis and characterization of 1,4-dihydro-1-pyridylzinc and -magnesium complexes
A. J. D. Koning (1980)
10.1002/(SICI)1521-3749(199809)624:9<1434::AID-ZAAC1434>3.0.CO;2-7
Phosphaniminato-Komplexe des Zinks mit Hydrido-, Alkinylo-, Alkenylo- und Amido-Liganden
M. Krieger (1998)
10.1021/OM900005T
Steric Enhancement of Group 12 Metal Hydride Stability and the Reaction of an Arylzinc Hydride with Tetramethylpiperidinyl Oxide (TEMPO)
Zhong-Liang Zhu (2009)
10.1021/OM100966D
Synthesis, Structure, and Reactivity of a Tetranuclear Amidinato Zinc Hydride Complex
Benjamin Gutschank (2010)
10.1021/ja308500s
Zinc catalysts for on-demand hydrogen generation and carbon dioxide functionalization.
W. Sattler (2012)
10.1107/S056774088001059X
Terminal zinc–hydrogen bonding. X-ray and neutron diffraction studies of the (2-dimethylamino-N-methylethylamido)hydridozinc dimer
N. Bell (1980)
10.1021/JA01154A025
The Preparation of the Hydrides of Zinc, Cadmium, Beryllium, Magnesium and Lithium by the Use of Lithium Aluminum Hydride1
G. D. Barbaras (1951)
10.1039/JM9930300587
Infrared laser pyrolysis of diethylzinc: first evidence for β-hydride elimination
Rachel E. Linney (1993)
10.1016/S0022-328X(00)90431-5
Preparation and characterization of the pyridine complexes of ethylzinc hydride and phenylzinc hydride
A. J. D. Koning (1978)
10.1039/B714806B
Lithium-promoted hydrogenation of carbon dioxide to formates by heterobimetallic hydridozinc alkoxide clusters.
K. Merz (2008)
10.1039/b822783g
Catalysis by cationic oxorhenium(v): hydrolysis and alcoholysis of organic silanes.
R. A. Corbin (2009)
10.1039/B102275J
Syntheses and structures of the first examples of zinc compounds with bridging fluorine and hydrogen atoms
Haijun Hao (2001)
10.1016/S0022-328X(00)93381-3
Synthesis, characterization and properties of some organozinc hydride complexes
A. J. D. Koning (1980)
10.1016/S0040-4039(01)83816-8
Reaction of zinc hydride with pyridine; Formation of a complex of 1,4-dihydro-1-pyridylzinc hydride, zinc hydride and pyridine
A. J. D. Koning (1977)
10.1039/b906319f
Convenient synthesis and crystal structure of a monomeric zinc hydride complex with a three-coordinate metal center.
Jan Spielmann (2009)
10.1515/znb-2009-11-1221
Solid-state and Solution Studies on a β-Diketiminate Zinc Hydride Complex
S. Schulz (2009)
10.1002/ASIA.201301268
Dinuclear zinc hydride supported by an anionic bis(N-heterocyclic carbene) ligand.
Arnab Rit (2014)
10.1021/CS2001016
Coordinatively Saturated Tris(oxazolinyl)borato Zinc Hydride-Catalyzed Cross Dehydrocoupling of Silanes and Alcohols
D. Mukherjee (2011)
10.1021/IC00307A038
A soluble alkoxyzinc hydride, [HZnOC(CH3)3]4. Synthesis and reactions with copper(I) alkoxides
Thomas L. Neils (1989)
10.1021/OM990654K
trans-[RuIICl(MeCN)5][RuIIICl4(MeCN)2]: A Reactive Intermediate in the Homogeneous Catalyzed Hydrosilylation of Carbon Dioxide†
A. Jansen (2000)
10.1002/ANIE.200701477
Facile synthesis of well-defined sodium hydridoalkylzincates(II).
A. Lennartson (2007)
10.1021/OM100153Z
Synthesis and Catalytic Reactivity of Bis(alkylzinc)-hydride-di(2-pyridylmethyl)amides
Marcel Kahnes (2010)
10.1021/ja102323g
Conversion of a zinc disilazide to a zinc hydride mediated by LiCl.
Debabrata Mukherjee (2010)
10.1002/ANIE.200601926
A zinc-zinc-bonded compound and its derivatives bridged by one or two hydrogen atoms: a new type of Zn-Zn bonding.
Zhong-Liang Zhu (2006)
10.1002/anie.201501539
An Air- and Water-Tolerant Zinc Hydride Cluster That Reacts Selectively With CO2.
David M. Ermert (2015)



This paper is referenced by
10.1002/anie.202011480
Molecular Zinc Hydride Cations [ZnH]+: Synthesis, Structure, and CO2 Hydrosilylation Catalysis
Florian Ritter (2020)
10.1039/c7dt01094j
Zinc hydridotriphenylborates supported by a neutral macrocyclic polyamine.
D. Mukherjee (2017)
10.1016/j.poly.2020.114542
Synthesis and structural characterization of bis(2-pyridylthio)(p-tolylthio)methyl zinc complexes and the catalytic hydrosilylation of CO2
W. Sattler (2020)
10.1055/S-0037-1610088
Recent Developments on N-Heterocyclic Carbene Supported Zinc Complexes: Synthesis and Use in Catalysis
S. Dagorne (2018)
10.1039/c8cc09839e
Terminal hydridozinc cation.
Raju Chambenahalli (2019)
10.1002/EJIC.201701425
Zinc Dihydride and Mixed Halo Hydrides Supported by an N‐Heterocyclic Carbene
Arnab Rit (2018)
10.1021/acs.chemrev.6b00259
Nickel Hydride Complexes.
Nathan A. Eberhardt (2016)
10.1002/ange.202011480
Molekulare Zinkhydridkationen [ZnH] + : Synthese, Struktur und CO 2 ‐Hydrosilylierungskatalyse
Florian Ritter (2020)
10.1002/CHIN.201623240
Molecular Zinc Hydrides
Ann-Kristin Wiegand (2016)
10.1039/c8dt04651d
Transition metal-induced dehydrogenative coupling of zinc hydrides.
Min Chen (2019)
10.1002/zaac.201900179
Low‐Coordinate Monomeric Zinc Hydride Complexes with Encapsulating Dipyrromethene Ligands and Reactivity with B(C6F5)3
G. Ballmann (2020)
10.1021/jacs.0c05500
Metal–Ligand Cooperation Facilitates Bond Activation and Catalytic Hydrogenation with Zinc Pincer Complexes
M. Rauch (2020)
10.1039/c6dt04595b
Azido- and amido-substituted gallium hydrides supported by N-heterocyclic carbenes.
Anindya K. Swarnakar (2017)
10.1002/chem.201603704
Investigation of N-Heterocyclic Carbene-Supported Group 12 Triflates as Pre-catalysts for Hydrosilylation/Borylation.
M. D. Roy (2016)
10.1002/ZAAC.201600280
Zinc Bis(triphenylsilyl) Stabilized by N‐Heterocyclic Carbene
L. E. Lemmerz (2016)
10.1039/c7dt00398f
Engaging dual donor sites within an N-heterocyclic olefin phosphine ligand.
M. Lui (2017)
10.1002/anie.201608599
Trajectory of Approach of a Zinc-Hydrogen Bond to Transition Metals.
Olga Ekkert (2016)
10.1002/chem.201804402
Zinc Oxide-Catalyzed Dehydrogenation of Primary Alcohols into Carboxylic Acids.
Fabrizio Monda (2018)
10.1002/chem.201601623
Ring-Shaped Phosphinoamido-Magnesium-Hydride Complexes: Syntheses, Structures, Reactivity, and Catalysis.
Lea Fohlmeister (2016)
10.1039/c7cc08393a
Carbodiimides as catalysts for the reduction of a cadmium hydride complex.
Dylan J Webb (2018)
10.1039/c7dt01303e
Organocatalytic hydroborylation promoted by N-heterocyclic olefins.
C. Hering-Junghans (2017)
10.1039/C7CY01850A
Effect of steam and CO2 on ethane activation over Zn-ZSM-5
A. Mehdad (2018)
10.1002/anie.201900233
Controlled Reduction of Carboxamides to Alcohols or Amines by Zinc Hydrides.
D. Ong (2019)
10.1021/jacs.6b05243
Activation of H2 over the Ru-Zn Bond in the Transition Metal-Lewis Acid Heterobimetallic Species [Ru(IPr)2(CO)ZnEt](.).
I. Riddlestone (2016)
Semantic Scholar Logo Some data provided by SemanticScholar