Heteroleptic Diimine–diphosphine Cu(I) Complexes As An Alternative Towards Noble-metal Based Photosensitizers: Design Strategies, Photophysical Properties And Perspective Applications
Y. Zhang, M. Schulz, Maria Wächtler, M. Karnahl, B. Dietzek
Published 2018 · Chemistry
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Abstract Photoactive Cu(I) complexes are considered as a promising alternative to traditional noble-metal complexes that are mainly based on Ru(II) and Ir(III). Therefore, in recent years heteroleptic Cu(I) complexes of the type [Cu(N^N)(P^P)]+ have been developed exhibiting impressive performance, e.g., long-lived excited-states, high emission quantum yields with tunable emission spectra as well as largely adjustable redox properties. These favorable features render heteroleptic Cu(I) complexes as suitable non-noble metal photosensitizers. Due to the exploding number of examples reported in literature, this review aims at systematically comparing the fundamental features of various cationic and neutral diimine–diphosphine Cu(I) complexes regarding to their geometrical, optical as well as electrochemical properties. In particular, this review focuses on the ability to tune the optoelectronic properties and excited-state dynamics by the design and the choice of the underlying N^N and P^P chelate ligands. Finally, this review briefly indicates some application scenarios of these novel class of complexes, e.g., in the fields of photocatalytic hydrogen evolution and light-emitting devices. As a result this review likes to contribute to a detailed understanding of structure–function relationships and to the rational design of heteroleptic diimine–diphosphine Cu(I) complexes for specific photophysical applications in the future.
This paper references
Shining Light on Copper: Unique Opportunities for Visible-Light-Catalyzed Atom Transfer Radical Addition Reactions and Related Processes.
Oliver Reiser (2016)
Synthesis and structural characterization of Cu(I) and Ni(II) complexes that contain the bis[2-(diphenylphosphino)phenyl]ether ligand. Novel emission properties for the Cu(I) species.
Shan-Ming Kuang (2002)
New phosphorescent polynuclear Cu(I) compounds based on linear and star-shaped 2-(2'-pyridyl)benzimidazolyl derivatives: syntheses, structures, luminescence, and electroluminescence.
Wen Li Jia (2005)
Luminescent ionic transition-metal complexes for light-emitting electrochemical cells.
Ruben Monteiro da Costa (2012)
Exciplex quenching of photo-excitd copper complexes
D. McMillin (1985)
Crowded Cu(I) complexes involving benzo[h]quinoline: pi-stacking effects and long-lives excited states.
E. Riesgo (2001)
New tetrazole-based Cu(I) homo- and heteroleptic complexes with various P^P ligands: synthesis, characterization, redox and photophysical properties.
Cristina Femoni (2013)
Phosphorus(III) ligands in homogeneous catalysis : design and synthesis
Paul C J Kamer (2012)
The emergence of copper(I)-based dye sensitized solar cells.
Catherine E Housecroft (2015)
Effects of Intraligand Electron Delocalization, Steric Tuning, and Excited-State Vibronic Coupling on the Photophysics of Aryl-Substituted Bipyridyl Complexes of Ru(II)
Niels H Damrauer (1997)
Photophysical characteristics and reactivity of bis(2,9-di-tert-butyl-1,10-phenanthroline)copper(I).
Omar Green (2009)
Structures, Electronic States and Electroluminescent Properties of a Series of CuI Complexes
Li Chih Yang (2005)
Highly efficient luminescence of Cu(I) compounds: thermally activated delayed fluorescence combined with short-lived phosphorescence.
Thomas Hofbeck (2015)
Highly Efficient Green Phosphorescent Organic Light-Emitting Diodes Based on CuI Complexes†
Qisheng Zhang (2004)
Copper(I) complexes with bipyridyl and phosphine ligands: a systematic study.
Inmaculada Andrés‐Tomé (2012)
The role of transition metal complexes in dye sensitized solar devices
Carlo A. Bignozzi (2013)
Temperature-dependent Emission of Copper(I) Phenanthroline Complexes with Bulky Substituents: Estimation of an Energy Gap between the Singlet and Triplet MLCT States
Motoko S Asano (2010)
Electrophosphorescent homo- and heteroleptic copper(I) complexes prepared from various bis-phosphine ligands.
Omar Moudam (2007)
Assignment of the Charge-Transfer Excited States of Bis(N-Heterocyclic) Complexes of Copper(I)
W. L. Parker (1989)
Highly efficient green organic light-emitting diodes containing luminescent tetrahedral copper(I) complexes
Satoshi Igawa (2013)
Neutral copper(I) phosphorescent complexes from their ionic counterparts with 2-(2'-quinolyl)benzimidazole and phosphine mixed ligands.
Junhui Min (2011)
A series of luminescent Cu(I) mixed-ligand complexes containing 2,9-dimethyl-1,10-phenanthroline and simple diphosphine ligands.
K. Saito (2006)
MLCT state structure and dynamics of a copper(I) diimine complex characterized by pump-probe X-ray and laser spectroscopies and DFT calculations.
L. Chen (2003)
In-situ oxidation, addition and cyclization reaction of 5,6-diamino-1,10-phenanthroline to construct copper(I)-diimine–diphosphine complexes
Xi-Xi Yao (2015)
Rational Design of Strongly Blue-Emitting Cuprous Complexes with Thermally Activated Delayed Fluorescence and Application in Solution-Processed OLEDs
Xu-Lin Chen (2013)
First application of the HETPHEN concept to new heteroleptic bis(diimine) copper(I) complexes as sensitizers in dye sensitized solar cells.
Martina Sandroni (2013)
Heteroleptic bis-diimine copper(I) complexes for applications in solar energy conversion
M. Sandroni (2016)
Simple Cu(I) complexes with unprecedented excited-state lifetimes.
D. G. Cuttell (2002)
Phosphorescence enhancement triggered by pi stacking in solid-state [Cu(N-N)(P-P)]BF4 complexes.
Liming Zhang (2009)
A noble-metal-free system for photocatalytic hydrogen production from water.
Esteban Mejía (2013)
Temperature dependence of luminescence from Cu(NN)2+ systems in fluid solution. Evidence for the participation of two excited states
J. R. Kirchhoff (1983)
Photostudies of copper(I) systems. 6. Room-temperature emission and quenching studies of bis(2,9-dimethyl-1,10-phenanthroline)copper(I)
M. W. Blaskie (1980)
Understanding the Control of Singlet-Triplet Splitting for Organic Exciton Manipulating: A Combined Theoretical and Experimental Approach
Ting Chen (2015)
Neutral, heteroleptic copper(i)-4H-imidazolate complexes: synthesis and characterization of their structural, spectral and redox properties.
M. Schulz (2016)
Advances in the light conversion properties of Cu(I)-based photosensitizers
Megan S. Lazorski (2014)
Highly luminescent Cu(I)-phenanthroline complexes in rigid matrix and temperature dependence of the photophysical properties.
D. Felder (2001)
Highly emissive copper(I) complexes bearing diimine and bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane.
Michihiro Nishikawa (2015)
Direct Observation of Temperature-Dependent Excited-State Equilibrium in Dinuclear Ruthenium Terpyridine Complexes Bearing Electron-Poor Bridging Ligands
R. Siebert (2011)
A noble-metal-free system for photodriven catalytic proton reduction.
Bart van den Bosch (2013)
Long-lived excited states of zwitterionic copper(I) complexes for photoinduced cross-dehydrogenative coupling reactions.
Bin Wang (2015)
Light-emitting electrochemical cells: recent progress and future prospects
Sebastian Meier (2014)
Artificial photosynthesis: molecular systems for catalytic water oxidation.
Markus D Kärkäs (2014)
Copper(I) Complexes for Thermally Activated Delayed Fluorescence: From Photophysical to Device Properties
Markus J. Leitl (2016)
Substitution-controlled excited state processes in heteroleptic copper(I) photosensitizers used in hydrogen evolving systems.
Stefanie Tschierlei (2014)
Luminescence of some CuI complexes
Paul A. Breddels (1982)
Design of a long-lifetime, earth-abundant, aqueous compatible Cu(I) photosensitizer using cooperative steric effects.
Catherine E McCusker (2013)
Theoretical Rationalization of the Emission Properties of Prototypical Cu(I)-Phenanthroline Complexes.
G. Capano (2015)
Systematic investigation of the metal-structure-photophysics relationship of emissive d10-complexes of group 11 elements: the prospect of application in organic light emitting devices.
Chien-Wei Hsu (2011)
Theoretical study on photoexcitation dynamics of a bis-diimine Cu(I) complex in solutions
Asaka Agena (2017)
Heteroleptic diimine copper(I) complexes with large extinction coefficients: synthesis, quantum chemistry calculations and physico-chemical properties.
Martina Sandroni (2013)
Geometry, electronic structure, and coordination ability of (diiminoethane)bis(phosphine)copper(1+) at the lowest energy triplet metal-to-ligand charge-transfer excited state. A theoretical study
Shigeyoshi Sakaki (1992)
Thermally activated delayed fluorescence (TADF) and enhancing photoluminescence quantum yields of [Cu(I)(diimine)(diphosphine)](+) complexes-photophysical, structural, and computational studies.
Charlotte L Linfoot (2014)
Ultrafast excited-state dynamics of copper(I) complexes.
Munetaka Iwamura (2015)
Equilibration between three different excited states in a bichromophoric copper(I) polypyridine complex.
Yoann Leydet (2007)
The triplet state of organo-transition metal compounds. Triplet harvesting and singlet harvesting for efficient OLEDs
H. Yersin (2011)
Structures and photophysical properties of copper(I) complexes bearing diphenylphenanthroline and bis(diphenylphosphino)alkane: the effect of phenyl groups on the phenanthroline ligand.
Taro Tsubomura (2015)
Synthesis and characterization of heteroleptic copper(I) complexes for solar energy conversion
Martina Sandroni (2012)
The bite angle makes the difference: a practical ligand parameter for diphosphine ligands
P. Dierkes (1999)
Singlets, triplets, and exciplexes: complex, temperature-dependent emissions from (2,9-dimethyl-1,10-phenanthroline)bis(triphenylphosphine)copper(1+) and (1,10-phenanthroline)(triphenylphosphine)copper(1+)
C. A. Palmer (1987)
Heteroleptic copper(I) photosensitizers of dibenzo[b,j]-1,10-phenanthroline derivatives driven hydrogen generation from water reduction
Shuping Luo (2016)
Artificial photosynthesis for solar fuels.
Stenbjörn Styring (2012)
Wide bite angle diphosphines: xantphos ligands in transition metal complexes and catalysis.
Paulus Clemens Jozef Kamer (2001)
A series of copper(I) complexes with electron donor/acceptor embedded ligands: Synthesis, photophysical and electroluminescent properties
Hu Rong Ge (2011)
Shine bright or live long: substituent effects in [Cu(N^N)(P^P)]+-based light-emitting electrochemical cells where N^N is a 6-substituted 2,2′-bipyridine
S. Keller (2016)
Cu(I)-2,9-dimethyl-1,10-phenanthroline: Density functional study of the structure, vibrational force-field, and excited electronic states
M. Zgierski (2003)
Copper-Based Photosensitisers in Water Reduction: A More Efficient In Situ Formed System and Improved Mechanistic Understanding.
A. Lennox (2016)
Blue and orange oxygen responsive emissions in the solid state based on copper(I) complexes bearing dodecafluorinated diphosphine and 1,10-phenanthroline derivative ligands
Masaya Washimi (2017)
Successful photocatalytic reduction of methylviologen (MV2+) with [Cu(NN)(PPh3)2]+ (NN = 2,9-dimethyl-1,10-phenanthroline or 4,4',6,6'-tetramethyl-2,2'-bipyridine) upon near-UV-light irradiation and a novel solvent effect on its catalytic activity
Shigeyoshi Sakaki (1986)
σ-Hammett parameter: a strategy to enhance both photo- and electro-luminescence features of heteroleptic copper(i) complexes.
Michael Dr. Weber (2017)
Copper(I) complexes for sustainable light-emitting electrochemical cells
Ruben Monteiro da Costa (2011)
Transient absorption dynamics of sterically congested Cu(I) MLCT excited states.
Sofia Garakyaraghi (2015)
Heteroleptic Cu-Based Sensitizers in Photoredox Catalysis.
Augusto C. Hernandez-Perez (2016)
Ru(II) dyads derived from 2-(1-pyrenyl)-1H-imidazo[4,5-f][1,10]phenanthroline: versatile photosensitizers for photodynamic applications.
Mat Stephenson (2014)
Diversity of copper(I) complexes showing thermally activated delayed fluorescence: basic photophysical analysis.
Rafał Czerwieniec (2015)
Outstanding luminescence from neutral copper(I) complexes with pyridyl-tetrazolate and phosphine ligands.
Larissa Bergmann (2013)
Powering the future of molecular artificial photosynthesis with light-harvesting metallosupramolecular dye assemblies.
Peter D. Frischmann (2013)
Strong steric hindrance effect on excited state structural dynamics of Cu(I) diimine complexes.
Nosheen A. Gothard (2012)
Substituted [Cu(I)(POP)(bipyridyl)] and related complexes: synthesis, structure, properties and applications to dye-sensitised solar cells.
Charlotte L Linfoot (2010)
The Organometallic Chemistry of the Transition Metals
R. Crabtree (1988)
Photostudies of 2,2'-bipyridine bis(triphenylphosphine)copper(1+), 1,10-phenanthroline bis(triphenylphosphine)copper(1+), and 2,9-dimethyl-1,10-phenanthroline bis(triphenylphosphine)copper(1+) in solution and in rigid, low-temperature glasses. Simultaneous multiple emissions from intraligand and cha
Rosemary A. Rader (1981)
Highly Luminescent CuI Complexes for Light-Emitting Electrochemical Cells†
N. Armaroli (2006)
Ultrafast structural rearrangements in the MLCT excited state for copper(I) bis-phenanthrolines in solution.
G. Shaw (2006)
Luminescent complexes beyond the platinum group: the d10 avenue.
Andrea Barbieri (2008)
Peripheral halo-functionalization in [Cu(N^N)(P^P)]+ emitters: influence on the performances of light-emitting electrochemical cells.
Fabian Brunner (2016)
Photocatalytic Hydrogen Production with Copper Photosensitizer–Titanium Dioxide Composites
Michael Karnahl (2014)
Death and Rebirth: Photocatalytic Hydrogen Production by a Self-Organizing Copper–Iron System
Steffen Fischer (2014)
Determination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistry
Y. Zhang (2016)
Luminescent and Redox-Active Polynuclear Transition Metal Complexes.
V. Balzani (1996)
Steric Effects in the Ground and Excited States of Cu(NN)2+ Systems
M. Eggleston (1997)
Cu(I) complexes – Thermally activated delayed fluorescence. Photophysical approach and material design
Rafał Czerwieniec (2016)
Steric effects and the behavior of Cu(NN)(PPh3)2+ systems in fluid solution. Crystal and molecular structures of [Cu(dmp)(PPh3)2]NO3 and [Cu(phen)(PPh3)2]NO3.1.5EtOH
J. R. Kirchhoff (1985)
Artificial photosynthesis: from molecular catalysts for light-driven water splitting to photoelectrochemical cells.
E. Andreiadis (2011)
Copper(I) Diphosphine Catalysts for C−N Bond Formation: Synthesis, Structure, and Ligand Effects
S. Daly (2008)
The beneficial effects of trifluoromethyl-substituents on the photoconversion efficiency of copper(i) dyes in dye-sensitized solar cells
Fabian Brunner (2015)
Influence of ligand substitution on excited state structural dynamics in Cu(I) bisphenanthroline complexes.
Jenny V Lockard (2010)
Synthesis and study on a series of phosphorescent Cu(I) complexes having sterically blocking ligands.
K. Zhang (2014)
Long-lived and oxygen-responsive photoluminescence in the solid state of copper(I) complexes bearing fluorinated diphosphine and bipyridine ligands.
Michihiro Nishikawa (2015)
Anion-induced quenching of excited bis(2,9-dimethyl-1,10-phenanthroline)copper(1+)
Kevin V. Goodwin (1987)
Bite angle effects in diphosphine metal catalysts: steric or electronic?Based on the presentation given at Dalton Discussion No. 5, 10?12th April 2003, Noordwijkerhout, The Netherlands.
Z. Freixa (2003)
Structure-dependent photophysical properties of singlet and triplet metal-to-ligand charge transfer states in copper(I) bis(diimine) compounds.
Z. A. Siddique (2003)
Capturing and analyzing the excited-state structure of a Cu(I) phenanthroline complex by time-resolved diffraction and theoretical calculations.
Ivan I. Vorontsov (2009)
Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges
Pingwu Du (2012)
A theoretical analysis of the phosphorescence efficiencies of Cu(i) complexes.
Luyi Zou (2014)
Photocatalytic water reduction with copper-based photosensitizers: a noble-metal-free system.
Shu-Ping Luo (2013)
Copper in Photocatalysis
Suva Paria (2014)
CONCENTRATION-DEPENDENT LIFETIMES OF Cu(NN)+2 SYSTEMS: EXCIPLEX QUENCHING FROM THE ION PAIR STATE
R. Michael Everly (1989)
Oxidative damage by ruthenium complexes containing the dipyridophenazine ligand or its derivatives: a focus on intercalation.
Sarah Delaney (2002)
Highly Efficient Electroluminescence from Green‐Light‐Emitting Electrochemical Cells Based on CuI Complexes
Qisheng Zhang (2006)
Time-resolved resonance Raman spectroscopy of bis(2,9-dimethyl-1,10-phenanthroline)copper(1+) in solution
K. Gordon (1991)
A Highly Emissive Heteroleptic Copper(I) Bis(phenanthroline) Complex: [Cu(dbp)(dmp)]+ (dbp = 2,9-Di-tert-butyl-1,10-phenanthroline; dmp = 2,9-Dimethyl-1,10-phenanthroline)
Mark T. Miller (1999)
Designing Highly Efficient CuI Photosensitizers for Photocatalytic H2 Evolution from Water.
Jae‐kwan Kim (2017)
Understanding excited-state structure in metal polypyridyl complexes using resonance Raman excitation profiles, time-resolved resonance Raman spectroscopy and density functional theory
Raphael Horvath (2010)
The Natural Bite Angle of Chelating Diphosphines
Charles P. Casey (1990)
Photoluminescence from copper(I) complexes with low-lying metal-to-ligand charge transfer excited states
Michael T. Buckner (1978)
Substituent effects and the photoluminescence of Cu(PPh3)2(NN)+ systems
Alan A. Del Paggio (1983)
Singlet harvesting with brightly emitting Cu(I) and metal-free organic compounds
H. Yersin (2012)
Charge-transfer absorption and emission of Cu(NN)2+ systems
A. K. Ichinaga (1987)
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
C. A. Tolman (1977)
Oxygen gas sensing by luminescence quenching in crystals of Cu(xantphos)(phen)+ complexes.
Conor S. Smith (2010)
Earth-abundant photocatalytic systems for the visible-light-driven reduction of CO2 to CO
Alonso Rosas-Hernández (2017)
[Cu(bpy)(P^P)]⁺ containing light-emitting electrochemical cells: improving performance through simple substitution.
Sarah Keller (2014)
Interplays of excited state structures and dynamics in copper(I) diimine complexes: Implications and perspectives
Michael W Mara (2015)
The stereochemistry of Bis(α,α'-diimine)copper(I) complexes: the crystal and molecular structures of Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) bromide hydrate, Bis(4,4',6,6'-tetramethyl-2,2'-bipyridine)copper(I) chloride dihydrate, and Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) nitrate dihy
John F. Dobson (1984)
On the luminescence of bis (triphenylphosphine) phenanthroline copper (I)
George Blasse (1980)
Effects of electronic and nuclear interactions on the excited-state properties and structural dynamics of copper(I) diimine complexes.
Michael W Mara (2013)
Synthesis and characterization of neutral luminescent diphosphine pyrrole- and indole-aldimine copper(I) complexes.
M. Crestani (2011)
Novel Heteroleptic CuI Complexes with Tunable Emission Color for Efficient Phosphorescent Light-Emitting Diodes†
Qisheng Zhang (2007)
Photoactive mono- and polynuclear Cu(I)–phenanthrolines. A viable alternative to Ru(II)–polypyridines?
N. Armaroli (2001)
Highly efficient thermally activated fluorescence of a new rigid Cu(I) complex [Cu(dmp)(phanephos)]+.
Rafał Czerwieniec (2013)
Realization of High-Energy Emission from [Cu(N−N)(P−P)]+ Complexes for Organic Light-Emitting Diode Applications
Liming Zhang (2009)
Strongly absorbing pi-pi* states in heteroleptic dipyrrin/2,2'-bipyridine ruthenium complexes: excited-state dynamics from resonance raman spectroscopy.
Tracey M. McLean (2010)
Catalyst: Chemistry’s Role in Providing Clean and Affordable Energy for All
Leif Hammarström (2016)
Solvent-induced luminescence quenching: static and time-resolved X-ray absorption spectroscopy of a copper(I) phenanthroline complex.
T. Penfold (2013)
Direct observation of intersystem crossing in a thermally activated delayed fluorescence copper complex in the solid state
Larissa Bergmann (2016)
Blue-light emission of Cu(I) complexes and singlet harvesting.
Rafał Czerwieniec (2011)
The basis of aryl substituent effects on charge-transfer absorption intensities
C. C. Phifer (1986)
Photoinduced electron transfer between [Cu(dmphen)L2]+[dmphen = 2,9-dimethyl-1,10-phenanthroline, L = PPhn(C6H4OMe-p)3 –n(n= 0–3)] and methyl viologen
S. Sakaki (1996)
Phosphorescent Cu(I) complexes of 2-(2'-pyridylbenzimidazolyl)benzene: impact of phosphine ancillary ligands on electronic and photophysical properties of the Cu(I) complexes.
T. McCormick (2006)
Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry, and chemiluminescence
A. Juris (1988)
Photoelectrochemical cells : Materials for clean energy
M. Grätzel (2001)
Bis(2,9-diphenyl-1,10-phenanthroline)copper(I): a copper complex with a long-lived charge-transfer excited state
C. Dietrich-Buchecker (1983)
Reinvestigation of the absorbing and emitting charge-transfer excited states of [Cu(NN)2]+ systems
R. Michael Everly (1991)
Effect of the bite angle of diphosphine ligands on activity and selectivity in the nickel-catalysed hydrocyanation of styrene
Mirko Kranenburg (1995)
Cooperative Substituent Effects on the Excited States of Copper Phenanthrolines.
Corey Cunningham (1999)
Geometric and electronic properties in a series of phosphorescent heteroleptic Cu(I) complexes: Crystallographic and computational studies
Katharina Kubiček (2017)
Exploring copper(I)-based dye-sensitized solar cells: a complementary experimental and TD-DFT investigation.
Biljana Bozic-Weber (2012)
Heteroleptic Copper Photosensitizers: Why an Extended π-System Does Not Automatically Lead to Enhanced Hydrogen Production.
Martin Heberle (2017)
Phosphorescence versus thermally activated delayed fluorescence. Controlling singlet-triplet splitting in brightly emitting and sublimable Cu(I) compounds.
Markus J. Leitl (2014)
Bright coppertunities: multinuclear Cu(I) complexes with N-P ligands and their applications.
Manuela Wallesch (2014)
Hindered internal conversion in rigid media. Thermally nonequilibrated 3IL and 3CT emissions from [Cu(5-X-phen)(PPh3)2]+ and [Cu(4,7-X2-phen)(PPh3)2]+ systems in a glass at 77 K
D. Casadonte (1987)
This paper is referenced by
Impact of the Type of Reactor and the Catalytic Conditions on the Photocatalytic Production of Hydrogen Using a Fully Noble‐Metal‐Free System
Immanuel Reim (2018)
Imidazo-Phenanthroline Ligands as a Convenient Modular Platform for the Preparation of Heteroleptic Cu(I) Photosensitizers
M. Schmid (2018)
Mechanistic Pathways Toward the Synthesis of Heterocycles Under Cross-Dehydrogenative Conditions
Ahmad A Almasalma (2019)
Electrochemical Synthesis, Properties, and Structure of 1,10-Phenanthroline Adducts of Mononuclear Copper, Cobalt, and Nickel Chelates in the N,N,O-Ligand Environment
Dmitrii A. Garnovskii (2018)
Heterocycles via Cross Dehydrogenative Coupling: Synthesis and Functionalization
Jairton Dupont (2019)
Licht und Leuchten bei 3d‐Metallen
Katja Heinze (2019)
Photophysics and photochemistry with Earth-abundant metals - fundamentals and concepts.
Christoph Förster (2020)
Efficiently luminescent cuprous iodide complexes supported by novel N^P-chelating ligands: Synthesis, structure and optoelectronic performances
W. Yang (2020)
Quantum dots based “On-Off” fluorescence probe for the selective detection of Cu2+ ion: Application to real sample analysis
Samadhan P. Pawar (2019)
Mononuclear and dinuclear heteroleptic Cu(I) complexes based on pyridyl-triazole and DPEPhos with long-lived excited-state lifetimes
Claudia Bizzarri (2018)
Photocatalytic CO2 Reduction Using Various Heteroleptic Diimine-Diphosphine Cu(I) Complexes as Photosensitizers
Yasuomi Yamazaki (2019)
Developments in Visible-Light-Mediated Copper Photocatalysis
Thomas P. Nicholls (2019)
Phosphines in artificial photosynthesis: considering different aspects such as chromophores, water reduction catalysts (WRCs), water oxidation catalysts (WOCs), and dyads
Johann M Pann (2019)
Copper(I) ionic complexes based on imidazo[4,5-f][1,10]phenanthrolin diimine chelating ligands: crystal structures, and photo- and electroluminescence properties
Anton V Rozhkov (2020)
Rationalizing Fabrication and Design Toward Highly Efficient and Stable Blue Light‐Emitting Electrochemical Cells Based on NHC Copper(I) Complexes
Michael Dr. Weber (2018)
Remarkably long-lived excited states of copper photosensitizers containing an extended π-system based on an anthracene moiety
Robin Giereth (2019)
Dinuclear Copper Complexes Triply Bridged by a Tetraphosphane, rac-Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2: Dinuclear Copper Complexes Triply Bridged by a Tetraphosphane, rac-Ph2PCH2P(Ph)CH2P(Ph)CH2PPh2
Tomoaki Tanase (2019)
Structural characterization, DFT studied, luminescent properties of cationic/neutral three‐coordinated copper (I) complexes and application in warm‐white light‐emitting diode
Tiancheng Wu (2020)
An earth-abundant system for light-driven CO2 reduction to CO using a pyridinophane iron catalyst.
Y. Sakaguchi (2019)
Synthesis, structures, luminescence and terahertz time-domain spectroscopy of nine Cu(I) complexes with P^P ligands and 1,10-phenanthroline derivatives
Xiao Yu (2019)
Progress on Light‐Emitting Electrochemical Cells toward Blue Emission, High Efficiency, and Long Lifetime
Chen Zhang (2020)
Synthesis, structures and luminescent properties of red emissive neutral copper(I) complexes with bisphosphino-substituted benzimidazole
Yile Song (2020)
Triphenylamine-substituted 2-pyridyl-1,2,3-triazole copper(I) complexes: an experimental and computational investigation
Joseph I. Mapley (2019)
Weak Intramolecular Interactions to Stabilize Supramolecular Fullerene-Porphyrin Conjugates and to Control the Conformation of Multiporphyrinic Arrays: Weak Intramolecular Interactions to Stabilize Supramolecular Fullerene-Porphyrin Conjugates and to Control the Conformation of Multiporphyrinic Arra
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Electrochemical synthesis, structural, spectral studies and DFT calculations of heteroleptic metal-chelates bearing N, N, S tridentate tosylamino functionalized pyrazole containing Schiff base and 1,10-phenathroline
Valery G. Vlasenko (2019)
Topological and Steric Constraints to Stabilize Heteroleptic Copper(I) Complexes Combining Phenanthroline Ligands and Phosphines.
Michel Holler (2019)
Heteroleptic iron(ii) complexes with naphthoquinone-type ligands.
T. Shiga (2020)
Life Cycle Assessment for the Organocatalytic Synthesis of Glycerol Carbonate Methacrylate.
Hendrik Buettner (2019)
Phenanthroline‐Fused Pyrazinacenes: One‐Pot Synthesis, Tautomerization and a RuII(2,2′‐bpy)2 Derivative
Pavel Švec (2018)
Revealing the initial steps in homogeneous photocatalysis by time-resolved spectroscopy.
Ayla Päpcke (2019)
Dinuclear Copper(I) Complexes Combining Bis(diphenylphosphanyl)acetylene with 1,10-Phenanthroline Ligands: Dinuclear Copper(I) Complexes Combining Bis(diphenylphosphanyl)acetylene with 1,10-Phenanthroline Ligands
Jean-François Nierengarten (2019)
On the interplay of solvent and conformational effects in simulated excited-state dynamics of a copper phenanthroline photosensitizer.
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