Online citations, reference lists, and bibliographies.
← Back to Search

Large Reversible Capacity Of High Quality Graphene Sheets As An Anode Material For Lithium-ion Batteries

P. Lian, Xuefeng Zhu, S. Liang, Z. Li, Weishen Yang, Haihui Wang
Published 2010 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy Visualize in Litmaps
Share
Reduce the time it takes to create your bibliography by a factor of 10 by using the world’s favourite reference manager
Time to take this seriously.
Get Citationsy
Abstract High quality graphene sheets were prepared from graphite powder through oxidation followed by rapid thermal expansion in nitrogen atmosphere. The preparation process was systematically investigated by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and Brunauer–Emmett–Teller (BET) measurements. The morphology and structure of graphene sheets were characterized by scanning electron microscope (SEM) and high-resolution transmission electron microscopy (HRTEM). The electrochemical performances were evaluated in coin-type cells versus metallic lithium. It is found that the graphene sheets possess a curled morphology consisting of a thin wrinkled paper-like structure, fewer layers (∼4 layers) and large specific surface area (492.5 m 2  g −1 ). The first reversible specific capacity of the prepared graphene sheets was as high as 1264 mA h g −1 at a current density of 100 mA g −1 . Even at a high current density of 500 mA g −1 , the reversible specific capacity remained at 718 mA h g −1 . After 40 cycles, the reversible capacity was still kept at 848 mA h g −1 at the current density of 100 mA g −1 . These results indicate that the prepared high quality graphene sheets possess excellent electrochemical performances for lithium storage.
This paper references
10.1126/science.270.5236.590
Mechanisms for Lithium Insertion in Carbonaceous Materials
Jeff Dahn (1995)
10.1016/0008-6223(95)00120-3
Study of oxygen-containing groups in a series of graphite oxides: Physical and chemical characterization
C. Hontoria-Lucas (1995)
10.1149/1.1837227
Density of States Calculations of Small Diameter Single Graphene Sheets
A. Gerouki (1996)
10.1149/1.1837572
Study of Irreversible Capacities for Li Insertion in Hard and Graphitic Carbons
W. Xing (1997)
10.1126/SCIENCE.276.5317.1395
Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material
Yoshio Idota (1997)
10.1016/S0008-6223(98)00160-2
Anodic performances of coke from coals
Y. Chang (1998)
10.1016/S0378-7753(99)00130-5
Electrochemical insertion of lithium in catalytic multi-walled carbon nanotubes
F. Leroux (1999)
10.1016/S1388-2481(00)00022-9
Effects of catalytic oxidation on the electrochemical performance of common natural graphite as an anode material for lithium ion batteries
Y. Wu (2000)
10.1103/PHYSREVB.61.14095
Interpretation of Raman spectra of disordered and amorphous carbon
A. Ferrari (2000)
10.1038/35035045
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
P. Poizot (2000)
10.1016/S0378-7753(00)00431-6
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries
D. Aurbach (2000)
10.1038/35104644
Issues and challenges facing rechargeable lithium batteries
J.-M. Tarascon (2001)
10.1002/ADMA.200306125
Lithium Storage in Ordered Mesoporous Carbon (CMK‐3) with High Reversible Specific Energy Capacity and Good Cycling Performance
H. Zhou (2003)
10.1126/SCIENCE.1102896
Electric Field Effect in Atomically Thin Carbon Films
K. Novoselov (2004)
10.1016/J.CARBON.2005.07.013
DRIFT study of deuterium-exchanged graphite oxide
T. Szab'o (2005)
10.1016/J.JPOWSOUR.2006.04.148
Influence of the oxidative stabilisation treatment time on the electrochemical performance of anthracene oils cokes as electrode materials for lithium batteries
A. Concheso (2006)
10.1021/JP060936F
Functionalized single graphene sheets derived from splitting graphite oxide.
H. Schniepp (2006)
10.1038/NMAT1672
High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications
P. L. Taberna (2006)
10.1016/J.ELECTACTA.2006.01.043
Composite anode material of silicon/graphite/carbon nanotubes for Li-ion batteries
Yingwei Zhang (2006)
10.1016/J.ELECTACTA.2006.07.029
Electrochemical improvement of low-temperature petroleum cokes by chemical oxidation with H2O2 for their use as anodes in lithium ion batteries
A. Concheso (2006)
10.1038/nature05545
The structure of suspended graphene sheets
J. Meyer (2007)
10.1021/CM070991G
Flexible, aligned carbon nanotube/conducting polymer electrodes for a lithium-ion battery
J. Chen (2007)
10.1039/B613962K
Studying disorder in graphite-based systems by Raman spectroscopy.
M. A. Pimenta (2007)
10.1016/J.CARBON.2007.02.034
Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
S. Stankovich (2007)
10.1016/J.ELECTACTA.2007.09.040
A comparative study of electrochemical properties of two kinds of carbon nanotubes as anode materials for lithium ion batteries
Shubin Yang (2008)
10.1021/JP710931H
FACILE SYNTHESIS AND CHARACTERIZATION OF GRAPHENE NANOSHEETS
G. Wang (2008)
10.1038/nnano.2007.411
High-performance lithium battery anodes using silicon nanowires.
C. Chan (2008)
10.1002/ADMA.200701685
CNFs@CNTs: Superior Carbon for Electrochemical Energy Storage
J. Zhang (2008)
10.1021/NL071822Y
Raman spectra of graphite oxide and functionalized graphene sheets.
K. Kudin (2008)
10.1021/nl800957b
Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries.
E. Yoo (2008)
10.1021/nl802484w
Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure.
Seung-Min Paek (2009)
10.1007/S11581-009-0389-2
Synthesis of LiFePO4-C cathode materials using a green and low-cost method
Linghui Yu (2009)
10.1039/B901551E
Graphene-based electrode materials for rechargeable lithium batteries
Minghui Liang (2009)
10.1039/b907723e
Stable dispersions of graphene and highly conducting graphene films: a new approach to creating colloids of graphene monolayers.
Y. Chen (2009)
10.1016/J.JALLCOM.2009.07.087
Preparation of LiMn2O4 with an enhanced performance by mixed liquid and mechanical activations
Q. Liu (2009)
10.1016/J.JPOWSOUR.2008.09.074
Preparation and electrochemical performance of ultra-short carbon nanotubes
X. Wang (2009)
10.1021/nn900020u
Synthesis of graphene sheets with high electrical conductivity and good thermal stability by hydrogen arc discharge exfoliation.
Zhong-Shuai Wu (2009)
10.1016/J.CARBON.2009.03.053
Graphene nanosheets for enhanced lithium storage in lithium ion batteries
G. Wang (2009)
10.1016/J.CARBON.2008.10.031
Synthesis of high-quality graphene with a pre-determined number of layers
Zhong-Shuai Wu (2009)
10.1016/J.ELECOM.2009.04.036
Electrochemical performance of graphene nanosheets as anode material for lithium-ion batteries
Peng Guo (2009)
10.1021/CM900395K
Li Storage Properties of Disordered Graphene Nanosheets
Dengyu Pan (2009)
10.1016/J.MATLET.2009.10.011
Effect of vacuum carbonization treatment on the irreversible capacity of hard carbon prepared from biomass material
T. Liu (2010)
10.1021/cr900070d
Honeycomb carbon: a review of graphene.
M. Allen (2010)



This paper is referenced by
10.1007/S12649-021-01465-3
Application of Carbonized Starches as Carbon Electrode Active Material Compared to Graphene Nanoplatelets-Based Anode in a Lithium-Ion Cell
Marita Piglowska (2021)
10.1016/j.jpowsour.2020.229159
Mechanistic insights into the lattice reconfiguration of the anode graphite recycled from spent high-power lithium-ion batteries
Haijun Yu (2021)
10.1021/ACS.JPCC.0C10369
Defective BC2N as an Anode Material with Improved Performance for Lithium-Ion Batteries
Jing Zhang (2021)
10.1021/ACS.JPCC.1C02373
Mechanisms and Properties of Bismuthene and Graphene/Bismuthene Heterostructures as Anodes of Lithium-/Sodium-Ion Batteries by First-Principles Study
Mei Ai (2021)
10.1016/J.CARTRE.2021.100045
Li intercalation into multilayer graphene with controlled defect densities
M. Ochapski (2021)
10.1016/J.JPOWSOUR.2021.229709
Recent trends in silicon/graphene nanocomposite anodes for lithium-ion batteries
Poonam Sehrawat (2021)
10.1039/d0cp05879c
Blue-AsP monolayer as a promising anode material for lithium- and sodium-ion batteries: a DFT study.
J. Zhang (2021)
10.1007/s11581-021-04257-w
Synthesis and electrochemical performances of MoSx/ZnS/C composites for lithium ion battery application
Guihua Zeng (2021)
10.1016/J.CARTRE.2021.100035
Pure carbon-based electrodes for metal-ion batteries
J. J. H. Togonon (2021)
10.1016/j.jechem.2020.08.056
Recent progress of advanced anode materials of lithium-ion batteries
Hui Cheng (2021)
10.1016/J.SURFCOAT.2021.127262
Carbon coated Si nanoparticles anchored to graphene sheets with excellent cycle performance and rate capability for Lithium-ion battery anodes
Junke Ou (2021)
10.1016/J.JALLCOM.2021.160135
In situ implanting fine ZnSe nanoparticles into N-doped porous carbon nanosheets as an exposed highly active and long-life anode for lithium-ion batteries
Yue Yang (2021)
10.1007/s10853-021-05899-x
Structural and functional applications of 3D-printed graphene-based architectures
X. You (2021)
10.3390/CATAL11020208
Atomistic-Scale Simulations on Graphene Bending Near a Copper Surface
M. Kowalik (2021)
10.1016/J.APSUSC.2021.149588
Preparation and characterization of basic graphene-based catalysts and their application in biodiesel synthesis
Justina Gaidukevič (2021)
10.1016/j.cej.2020.128349
In-situ construction of g-C3N4/Mo2CTx hybrid for superior lithium storage with significantly improved Coulombic efficiency and cycling stability
Lijia Wan (2021)
10.3390/molecules26133903
Surface Properties of Graphene Functionalized TiO2/nHA Hybrid Coatings Made on Ti6Al7Nb Alloys via Plasma Electrolytic Oxidation (PEO)
Oktay Yigit (2021)
10.1016/J.JHAZMAT.2021.126098
Selective and fast removal and determination of β-lactam antibiotics in aqueous solution using multiple templates imprinted polymers based on magnetic hybrid carbon material.
Ying Wang (2021)
10.1021/acsomega.0c06048
Significant Capacitance Enhancement via In Situ Exfoliation of Quasi-One-Dimensional Graphene Nanostripes in Supercapacitor Electrodes
Jacob D. Bagley (2021)
10.1016/j.corsci.2020.109143
Anticorrosion performance of electro-deposited epoxy/ amine functionalized graphene oxide nanocomposite coatings
M. Aghili (2021)
10.1002/ER.6852
Controlled nanostructure of a graphene nanosheet‐TiO 2 composite fabricated via mediation of organic ligands for high‐performance Li storage applications
Keebum Hwang (2021)
10.1007/978-981-15-8844-0_10
Electrospun Nanostructured Iron Oxides for High-Performance Lithium Ion Batteries
Neethu T. M. Balakrishnan (2021)
10.1016/J.NANOEN.2021.105816
Novel binder-free carbon anode for high capacity Li-ion batteries
D. Yarmolich (2021)
10.3390/EN14092649
Applications of Carbon in Rechargeable Electrochemical Power Sources: A Review
J. Lach (2021)
10.1016/j.carbon.2020.08.064
Boosting lithium storage by facile functionalization of graphene oxide nanosheets via 2-aminoanthraquinone
P. Chen (2021)
10.1007/978-981-16-1052-3_5
Carbon-Based Nanocomposites: Processing, Electronic Properties and Applications
M. Mallik (2021)
10.1149/1945-7111/aba1a7
Graphene-Like Graphite Negative Electrode Rapidly Chargeable at Constant Voltage
S. Uchida (2020)
10.1002/celc.201901898
Maximized Energy Density of RuO 2 //RuO 2 Supercapacitors through Potential Dependence of Specific Capacitance
Yi-Ling Wang (2020)
10.1021/acsomega.9b03858
Graphene/ZnO Nanowire/p-GaN Vertical Junction for a High-Performance Nanoscale Light Source
Fang Lin (2020)
10.1016/j.egyr.2019.10.019
Improvement of Li-ion batteries energy storage by graphene additive
Safaa I. Al-Saedi (2020)
10.1007/978-3-319-18875-1_2
Carbon Nanoadsorbents
Fernando Machado Machado (2020)
10.1016/J.MATCHEMPHYS.2019.121987
Fabrication of graphene/MoS2 alternately stacked structure for enhanced lithium storage
X. Yu (2020)
See more
Semantic Scholar Logo Some data provided by SemanticScholar