Online citations, reference lists, and bibliographies.
← Back to Search

Effect Of The Support On The High Activity Of The (Ni)Mo/ZrO2–SBA-15 Catalyst In The Simultaneous Hydrodesulfurization Of DBT And 4,6-DMDBT

O. Gutiérrez, T. Klimova
Published 2011 · Chemistry

Cite This
Download PDF
Analyze on Scholarcy
Share
Series of Mo- and NiMo-catalysts were supported on ZrO2, Al2O3, SBA-15, and ZrO2-modified SBA-15 and tested in the simultaneous hydrodesulfurization (HDS) of dibenzothiophene (DBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT). The rate constants of the main steps in the HDS reaction network of both molecules were calculated, and the materials were characterized by N2 physisorption, X-ray diffraction, UV–vis diffuse reflectance spectroscopy, temperature-programmed reduction and sulfidation, NO adsorption and high-resolution transmission electron microscopy. Tetrahedral and octahedral Mo species in the oxide precursors were related to the monolayers and multilayered MoS2 structures, respectively, in the sulfide catalysts. The morphology of the active phase and the formation of the NiMoS phase were the most important factors during the HDS process of DBT-type compounds given that the turnover frequency values did not depend on the support composition or the morphology of the active phase. The monolayers of MoS2 had low activity for the HDS of both molecules on the unpromoted catalysts, whereas on the NiMo catalysts, DBT reacted on monolayers and stacked NiMoS clusters but 4,6-DMDBT was converted only on the later structures. The optimum active phase–support interaction strength on ZrO2–SBA-15 materials led to the characteristics of the active phase that maximized the total active surface and the active surface not sterically hindered by the support, i.e., stacked MoS2-like clusters with short lengths. Thus, the NiMo/ZrO2–SBA-15 catalyst was able to convert DBT-type compounds with typical and low reactivity on the NiMo/Al2O3 catalyst.
This paper references
10.1016/J.MICROMESO.2004.06.030
Ordered mesoporous materials in catalysis
A. Taguchi (2005)
10.1016/S0926-860X(02)00385-X
XPS characterization of zirconium-promoted CoMo hydrodesulfurization catalysts
S. Damyanova (2003)
10.1016/S0920-5861(97)00085-0
Hydrodesulfurization of dibenzothiophene derivatives over TiO2Al2O3 supported sulfided molybdenum catalyst
C. Pophal (1997)
10.1007/S10562-010-0317-0
Influence of Frame Connectivity of SBA-15 and KIT-6 Supported NiMo Catalysts for Hydrotreating of Gas Oil
K. Soni (2010)
10.1016/J.CATTOD.2005.07.130
Hydrodesulfurization of dibenzothiophene over alumina-supported nickel molybdenum phosphide catalysts
M. Nagai (2005)
10.1016/J.APCATA.2005.05.042
Reaction pathways on NiMo/Al2O3 catalysts for hydrodesulfurization of diesel fuel
N. Kagami (2005)
10.1006/JCAT.2000.3158
The Relation between Morphology and Hydrotreating Activity for Supported MoS2 Particles
Ejm Emiel Hensen (2001)
10.1007/978-0-387-25789-1
Practical Advances in Petroleum Processing
C. Hsu (2006)
10.1007/S10562-006-0204-X
Support effect on the properties of iron–molybdenum hydrodesulfurization catalysts
E. Kraleva (2006)
10.1016/J.JCAT.2004.02.008
DBT derivatives adsorption over molybdenum sulfide catalysts: a theoretical study
S. Cristol (2004)
10.1016/S0926-3373(02)00212-6
New design approaches to ultra-clean diesel fuels by deep desulfurization and deep dearomatization
C. Song (2003)
10.1016/S0167-2991(06)80927-4
New NiMo catalysts supported on ZrO2-modified SBA-15 materials for 4,6-dimethyldibenzothiophene hydrodesulfurization
O. Gutiérrez (2006)
10.1006/JCAT.2000.3148
Hydrodesulfurization of Dibenzothiophene over Siliceous MCM-41-Supported Catalysts
Anjie Wang (2001)
10.1016/J.CATTOD.2007.10.110
Deep HDS over NiMo/Zr-SBA-15 catalysts with varying MoO3 loading
O. Gutiérrez (2008)
10.1016/0021-9517(83)90010-6
Characterization of the structures and active sites in sulfided CoMoAl2O3 and NiMoAl2O3 catalysts by NO chemisorption
Nan-Yu Topsøe (1983)
10.1016/J.APCATA.2005.04.056
Hydrodesulfurization of sulfur-containing polyaromatic compounds in light gas oil using noble metal catalysts
A. Ishihara (2005)
10.1021/EF049804G
Kinetics of Two Pathways for 4,6-Dimethyldibenzothiophene Hydrodesulfurization over NiMo, CoMo Sulfide, and Nickel Phosphide Catalysts
J. H. Kim (2005)
10.1016/J.CATTOD.2004.10.005
Physico-chemical characterization and catalysis on SBA-15 supported molybdenum hydrotreating catalysts
G. Dhar (2005)
High-Pressure Sulfidation of Hydrotreating Catalysts:Genesis and Properties of the Active Phase
A. Dugulan (2008)
10.1016/S0166-9834(00)83333-3
A geometrical model of the active phase of hydrotreating catalysts
S. Kasztelan (1984)
10.1016/J.CATTOD.2004.07.036
HDS kinetics study of dibenzothiophenic compounds in LCO
Jinwen Chen (2004)
10.1016/J.JCAT.2007.04.014
Mo and NiMo catalysts supported on SBA-15 modified by grafted ZrO2 species: Synthesis, characterization and evaluation in 4,6-dimethyldibenzothiophene hydrodesulfurization
O. Gutiérrez (2007)
10.1016/J.APCATA.2008.04.034
The single-layered morphology of supported MoS2-based catalysts—The role of the cobalt promoter and its effects in the hydrodesulfurization of dibenzothiophene
G. Berhault (2008)
10.1016/S0920-5861(03)00401-2
Morphology and orientation of MoS2 clusters on Al2O3 and TiO2 supports and their effect on catalytic performance
H. Shimada (2003)
10.1016/J.JCAT.2004.02.009
Hydrodesulfurization reaction pathways on MoS2 nanoclusters revealed by scanning tunneling microscopy
J. V. Lauritsen (2004)
10.1021/IE8005808
Kinetic Study of the HDS of 4,6-DMDBT over NiMo/Al2O3−SiO2(x) Catalysts
F. Sánchez-Minero (2009)
10.1016/J.JCAT.2007.04.013
Location and coordination of promoter atoms in Co- and Ni-promoted MoS2-based hydrotreating catalysts
J. V. Lauritsen (2007)
10.1021/J100175A068
A Raman and ultraviolet diffuse reflectance spectroscopic investigation of alumina-supported molybdenum oxide
C. C. Williams (1991)
10.1021/IE970895X
Kinetic Modeling of Hydrodesulfurization of Oil Fractions: Light Cycle Oil
Valérie Vanrysselberghe (1998)
10.1016/J.APCATA.2006.02.057
Effect of Al-SBA-15 support on catalytic functionalities of hydrotreating catalysts: I. Effect of variation of Si/Al ratio on catalytic functionalities
G. M. Kumaran (2006)
10.1016/S0167-2991(07)80441-1
SBA-15 mesoporous molecular sieves doped with ZrO2 or TiO2 as supports for Mo HDS catalysts
O. Gutiérrez (2007)
10.1016/J.MICROMESO.2007.08.037
Hydrotreating of gas oil on SBA-15 supported NiMo catalysts
V. Sundaramurthy (2008)
10.1016/J.CATTOD.2004.07.027
Highly active MoS2 on wide-pore ZrO2–TiO2 mixed oxides
M. C. Barrera (2004)
10.1016/J.APCATA.2006.08.034
Characterization and hydrodesulfurization activity of CoMo catalysts supported on boron-doped sol–gel alumina
F. Dumeignil (2006)
10.1016/J.JCAT.2009.09.016
The effect of Co-promotion on MoS2 catalysts for hydrodesulfurization of thiophene: A density functional study
P. G. Moses (2009)
10.1006/JCAT.1993.1154
Characterization and Modeling of the Mo Species in Grafted Mo/SiO2 Catalysts After Redox Thermal Treatments
C. Louis (1993)
10.1016/S0166-9834(00)81246-4
Active sites and support effects in hydrodesulfurization catalysts
H. Topsøe (1986)
10.1016/S0021-9517(02)00012-X
High loading of short WS2 slabs inside SBA-15: promotion with nickel and performance in hydrodesulfurization and hydrogenation
L. Vradman (2003)
10.1016/S0920-5861(03)00463-2
MCM-41-supported Co-Mo catalysts for deep hydrodesulfurization of light cycle oil
U. Turaga (2002)
10.1016/S1381-1169(02)00021-3
New catalysts for deep hydrotreatment of diesel fuel: Kinetics of 4,6-dimethyldibenzothiophene hydrodesulfurization over alumina-supported molybdenum carbide
P. Costa (2002)
10.1080/00986440902831789
APPLICATION OF NEW ZRO2-SBA-15 MATERIALS AS CATALYTIC SUPPORTS: STUDY OF INTRINSIC ACTIVITY OF MO CATALYSTS IN DEEP HDS
O. Gutiérrez (2009)
10.1016/J.CATTOD.2006.06.035
SBA-15 supports modified by Ti and Zr grafting for NiMo hydrodesulfurization catalysts
O. Gutiérrez (2006)
10.1006/JCAT.1998.2123
Spectroscopic studies on tetragonal ZrO2-supported MoO3 and NiO−MoO3 systems
Z. Liu (1998)
10.1006/JCAT.1994.1076
On the structural differences between alumina-supported CoMoS type I and alumina-, silica-, and carbon-supported CoMoS type II phases studied by XAFS, MES, and XPS
Smam Stephan Bouwens (1994)
10.1006/JCAT.1999.2790
Alkyldibenzothiophenes Hydrodesulfurization-Promoter Effect, Reactivity, and Reaction Mechanism
F. Bataille (2000)
10.1016/J.JCAT.2004.11.011
MoS2 morphology and promoter segregation in commercial Type 2 Ni–Mo/Al2O3 and Co–Mo/Al2O3 hydroprocessing catalysts
S. Eijsbouts (2005)
10.1016/0166-9834(91)90013-X
Temperature-programmed reduction and zeta potential studies of the structure ofMo/O3Al2O3 andMo/O3SiO2 catalysts effect of the impregnation pH and molybdenum loading
R. L. Cordero (1991)
10.1021/IE030856N
Kinetics of hydrodesulfurization of dibenzothiophene catalyzed by sulfided Co-Mo/MCM-41
Y. Wang (2004)
10.1016/J.APCATA.2004.03.023
MoCo(Ni)/ZrO2–SiO2 hydrotreating catalysts: physico-chemical characterization and activities studies
M. Rana (2004)
10.1016/0021-9517(88)90319-3
Support effect on the catalytic activity and properties of sulfided molybdenum catalysts
H. Shimada (1988)
10.1021/IE800626K
Modification of Activity and Selectivity of NiMo/SBA-15 HDS Catalysts by Grafting of Different Metal Oxides on the Support Surface
T. Klimova (2009)
10.1016/J.APCATA.2004.09.037
The influence of preparation method on the properties of NiMo sulfide catalysts supported on ZrO2
Meiling Jia (2005)
10.1006/JCAT.2002.3674
Hydrodesulfurization of Dibenzothiophene over Siliceous MCM-41-Supported Catalysts: II. Sulfided Ni–Mo Catalysts
Anjie Wang (2002)
10.1016/J.APCATA.2007.11.008
Novel bifunctional NiMo/Al-SBA-15 catalysts for deep hydrodesulfurization: Effect of support Si/Al ratio
T. Klimova (2008)
10.1016/J.CATTOD.2005.07.069
Hydrodesulfurization of dibenzothiophene on MoS2/MCM-41 and MoS2/SBA-15 catalysts prepared by thermal spreading of MoO3
A. Sampieri (2005)
10.1002/AIC.690240611
Hydrodesulfurization of dibenzothiophene catalyzed by sulfided CoO-MoO3γ-Al2O3: The reaction network
M. Houalla (1978)
10.1021/JA974025I
Nonionic Triblock and Star Diblock Copolymer and Oligomeric Surfactant Syntheses of Highly Ordered, Hydrothermally Stable, Mesoporous Silica Structures
D. Zhao (1998)
10.1016/S0920-5861(03)00408-5
Performance of CoMoS catalysts supported on nanoporous carbon in the hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene
J. Lee (2003)
10.1016/S0167-2991(97)80033-X
Influence of high Mo loading on the HYD/HDS selectivity of alumina supported MoS2 catalysts
P. Silva (1997)
10.1016/S0926-860X(02)00417-9
Ni and Mo interaction with Al-containing MCM-41 support and its effect on the catalytic behavior in DBT hydrodesulfurization
T. Klimova (2003)
10.1007/BF00807381
Performance, characterization, and surface acidity of zirconium modified hydroprocessing catalysts
J. Weissman (1994)



This paper is referenced by
10.1016/B978-0-08-097774-4.00723-3
Hydrotreating: Removal of Sulfur from Crude Oil Fractions with Sulfide Catalysts
W. Bensch (2013)
10.1016/J.APCATA.2016.11.015
Use of kinetic modeling for investigating support acidity effects of NiMo sulfide catalysts on quinoline hydrodenitrogenation
M. Nguyen (2017)
10.1016/J.CES.2014.03.006
Effect of pore diameter and structure of mesoporous sieve supported catalysts on hydrodesulfurization performance
P. Yuan (2014)
10.1016/J.CATTOD.2015.07.028
HDS performance of NiMo catalysts supported on nanostructured materials containing titania
J. C. Morales-Ortuño (2016)
10.1007/s10562-018-2365-9
Reactivation of CoMo/Al2O3 Hydrotreating Catalysts by Citric Acid
S. V. Budukva (2018)
10.1016/j.jcat.2020.03.017
Facile synthesis of few-layer and ordered K-promoted MoS2 nanosheets supported on SBA-15 and their potential application for heterogeneous catalysis
Jichang Lu (2020)
10.1016/J.JCAT.2015.05.005
Influence of Na content on behavior of NiMo catalysts supported on titania nanotubes in hydrodesulfurization
Rodrigo Arturo Ortega-Domínguez (2015)
10.1016/J.JCAT.2011.10.023
Synthesis and hydrodesulfurization properties of NiW catalyst supported on high-aluminum-content, highly ordered, and hydrothermally stable Al-SBA-15
Y. Li (2012)
10.1016/j.jcat.2020.04.008
Effects of Ni–Al2O3 interaction on NiMo/Al2O3 hydrodesulfurization catalysts
Z. Liu (2020)
10.1246/CL.2013.272
Selective Desorption by 4,6-Dimethyldibenzothiophene Addition during Carbazole Hydrodenitrogenation on Sulfided Phosphorus-doped NiMo/Al2O3 Catalyst
Masatoshi Nagai (2013)
10.1007/s11705-015-1535-1
HDS of dibenzothiophenes and hydrogenation of tetralin over a SiO2 supported Ni-Mo-S catalyst
Qiang Wei (2015)
10.1016/J.FUEL.2014.07.034
Deposition of WO3 on Al2O3 via a microwave hydrothermal method to prepare highly dispersed W/Al2O3 hydrodesulfurization catalyst
H. Wang (2014)
10.1016/J.FUEL.2018.10.114
A quantitative XPS examination of UV induced surface modification of TiO2 sorbents for the increased saturation capacity of sulfur heterocycles
Mingyang Chi (2019)
10.1016/J.APCATB.2014.10.034
Synthesis of NiMo catalysts supported on mesoporous Al-SBA-15 with different morphologies and their catalytic performance of DBT HDS
D. Gao (2015)
10.1016/J.CEJ.2015.02.015
Synthesis of CoMo catalysts supported on EMT/FAU intergrowth zeolites with different morphologies and their hydro-upgrading performances for FCC gasoline
D. Gao (2015)
10.1016/J.JCAT.2016.10.016
Synthesis of NiMo catalysts supported on mesoporous Al2O3 with different crystal forms and superior catalytic performance for the hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene
Xuesong Wang (2016)
10.1002/SLCT.201700055
Efficient CoMoS Catalysts Supported on Bio‐Inspired Polymer Coated Alumina for Hydrotreating Reactions
R. Baby Munirathinam (2017)
10.1007/978-3-319-60630-9_7
Hydrodesulfurization (HDS) Process Based on Nano-catalysts: The Role of Supports
Alimorad Rashidi (2018)
10.1016/J.JCAT.2013.03.001
The effect of starch addition on combustion synthesis of NiMo–Al2O3 catalysts for hydrodesulfurization
Weikun Lai (2013)
10.1016/J.APCATA.2016.04.008
NiMo catalysts supported on the Nb modified mesoporous SBA-15 and HMS: Effect of thioglycolic acid addition on HDS
R. Palcheva (2016)
10.1007/s11144-015-0859-7
Modeling the kinetics of sulfidation over NiMo/Al2O3 catalyst for thiophene hydrodesulfurization
Weikun Lai (2015)
10.1016/J.APCATB.2018.07.042
Hydrodesulfurization of 4,6-dimethyldibenzothiophene over NiMo sulfide catalysts supported on meso-microporous Y zeolite with different mesopore sizes
W. Zhou (2018)
10.1002/cctc.201300210
Synthesis of Methanethiol from CS2 on Ni‐, Co‐, and K‐Doped MoS2/SiO2 Catalysts
O. Gutiérrez (2013)
10.1155/2016/5208027
The Pore Confinement Effect of FDU-12 Mesochannels on MoS2 Active Phases and Their Hydrodesulfurization Performance
Cong Liu (2016)
10.1016/j.fuel.2020.118550
On the role of niobium in nanostructured Mo/Nb-MCM-41 and NiMo/Nb-MCM-41 catalysts for hydrodesulfurization of dibenzothiophene
Franklin J. Méndez (2020)
10.1016/S1872-5813(18)30038-0
Effect of preparation method of nanosized zeolite HY-Al2O3 composite as NiMo catalyst support on diesel HDS
Hai-liang Yin (2018)
10.1016/J.JCAT.2014.01.014
Effects of composition and morphology of active phase of CoMo/Al2O3 catalysts prepared using Co2Mo10–heteropolyacid and chelating agents on their catalytic properties in HDS and HYD reactions
P. Nikulshin (2014)
10.1016/j.jcat.2020.04.012
Tailoring NiMoS active phases with high hydrodesulfurization activity through facilely synthesized supports with tunable mesostructure and morphology
C. Liu (2020)
10.1016/J.FUEL.2014.03.055
Synthesis, characterization and hydrodesulfurization properties of nickel–copper–molybdenum catalysts for the production of ultra-low sulfur diesel
H. Liu (2014)
10.1002/cctc.201300856
γ‐Al2O3‐Supported and Unsupported (Ni)MoS2 for the Hydrodenitrogenation of Quinoline in the Presence of Dibenzothiophene
J. Hein (2014)
10.1016/J.CATTOD.2014.05.002
Support effect on the catalytic performance of trimetallic NiMoW catalysts prepared with citric acid in HDS of dibenzothiophenes
J. A. Mendoza-Nieto (2015)
10.1002/cctc.201500517
Development of a Magnetically Recyclable Molybdenum Disulfide Catalyst for Direct Hydrodesulfurization
Seyyedmajid Sharifvaghefi (2015)
See more
Semantic Scholar Logo Some data provided by SemanticScholar