Online citations, reference lists, and bibliographies.
← Back to Search

Highly Selective Conversion Of Carbon Dioxide To Aromatics Over Tandem Catalysts

Zelong Li, Y. Qu, Y. Qu, Wang Ji-jie, H. Liu, M. Li, S. Miao, Can Li
Published 2019 · Chemistry

Cite This
Download PDF
Analyze on Scholarcy
Share
Summary Conversion of CO2 to aromatics is a promising route to realize the proposal on carbon capture and utilization based on strategic CO2 carbon resource. In this work, CO2 is converted to aromatics with aromatics selectivity up to 73% at CO2 conversion of 14%, and the selectivity of CO was suppressed down to 44% over a tandem catalyst ZnZrO/ZSM-5, which was constructed by using ZnZrO solid solution and H-ZSM-5 zeolite. The selectivity of aromatics can reach to 78% at the space velocity of 1,800 mL/gcat/h. Tandem catalysis enables the direct hydrogenation of CO2 to aromatics favorable in thermodynamics through the coupling of CO2 hydrogenation over ZnZrO and aromatics formation over H-ZSM-5. The H2O generated through CO2 hydrogenation over ZnZrO can obviously increase the selectivity of aromatics and the CO2 in the reaction system promotes the formation of aromatics. Interestingly, it is found that the presence of H2O and CO2 significantly suppresses the generation of polycyclic aromatics and consequently enhances the stability of the tandem catalyst; therefore, no obvious deactivation of tandem catalysts was observed for at least 100 hr in the reaction stream.
This paper references
10.1002/anie.201602512
Pt3 Co Octapods as Superior Catalysts of CO2 Hydrogenation.
M. U. Khan (2016)
10.1038/nchem.1873
Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol.
F. Studt (2014)
10.1039/C7CY01549F
Direct and selective hydrogenation of CO2 to ethylene and propene by bifunctional catalysts
J. Gao (2017)
10.1021/ACSCATAL.7B03457
Effect of n-butanol cofeeding on the methanol to aromatics conversion over Ga-modified nano H-ZSM-5 and its mechanistic interpretation
W. Dai (2018)
10.1002/anie.201103657
Conversion of methanol to hydrocarbons: how zeolite cavity and pore size controls product selectivity.
U. Olsbye (2012)
10.1021/CR068357U
Transformation of carbon dioxide.
T. Sakakura (2007)
10.1021/jacs.6b05791
Optimizing Binding Energies of Key Intermediates for CO2 Hydrogenation to Methanol over Oxide-Supported Copper.
Shyam Kattel (2016)
10.1002/anie.201600943
Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO2 Hydrogenation.
O. Martin (2016)
10.1126/science.aaf0718
Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis
Sebastian Kuld (2016)
10.1038/s41929-018-0078-5
Recent trends and fundamental insights in the methanol-to-hydrocarbons process
I. Yarulina (2018)
10.1039/c6cc01965j
Synthesis of isoalkanes over a core (Fe-Zn-Zr)-shell (zeolite) catalyst by CO2 hydrogenation.
Xiaoxing Wang (2016)
10.1126/sciadv.1701290
A highly selective and stable ZnO-ZrO2 solid solution catalyst for CO2 hydrogenation to methanol
Jijie Wang (2017)
10.1002/AIC.15144
Production of benzene, toluene, and xylenes from natural gas via methanol: Process synthesis and global optimization
Alexander M. Niziolek (2016)
10.1039/C7CY00024C
Comparative investigation of the deactivation behaviors over HZSM-5 and HSAPO-34 catalysts during low-temperature methanol conversion
L. Qi (2017)
10.1006/JCAT.1996.0148
Selectivity Enhancement in Methylamine Synthesis via Postsynthesis Modification of Brønsted Acidic Mordenite
Christian Gründling (1996)
10.1016/J.CHEMPR.2017.05.007
Bifunctional Catalysts for One-Step Conversion of Syngas into Aromatics with Excellent Selectivity and Stability
K. Cheng (2017)
10.1021/ACS.NANOLETT.6B03637
Copper Nanocrystals Encapsulated in Zr-based Metal-Organic Frameworks for Highly Selective CO2 Hydrogenation to Methanol.
Bunyarat Rungtaweevoranit (2016)
10.1021/ACSCATAL.7B02649
Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis
P. Gao (2018)
10.1038/s41467-018-05880-4
Selective conversion of CO2 and H2 into aromatics
Youming Ni (2018)
10.1021/JA065810A
Conversion of methanol into hydrocarbons over zeolite H-ZSM-5: ethene formation is mechanistically separated from the formation of higher alkenes.
S. Svelle (2006)
10.1002/anie.201606099
Coke Formation in a Zeolite Crystal During the Methanol‐to‐Hydrocarbons Reaction as Studied with Atom Probe Tomography
Joel E Schmidt (2016)
10.1126/science.1253057
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
J. Graciani (2014)
10.1016/S0167-2991(08)62017-0
UV-Visible Spectroscopic Investigations and Related Studies on Coke Formation Over Industrial H-ZSM-5-Based Catalysts
H. Karge (1989)
10.1016/S1002-0721(12)60305-6
Dimethyl ether synthesis from CO2 hydrogenation on La-modified CuO-ZnO-Al2O3/HZSM-5 bifunctional catalysts
Gao Wengui (2013)
10.1021/JA061018Y
On the reactivity of surface methoxy species in acidic zeolites.
Y. Jiang (2006)
10.3762/bjnano.5.88
Carbon dioxide hydrogenation to aromatic hydrocarbons by using an iron/iron oxide nanocatalyst
Hongwang Wang (2014)
10.1021/ACSCATAL.7B03251
Highly Selective Conversion of Carbon Dioxide to Lower Olefins
Zelong Li (2017)
10.1021/jacs.5b06150
Low Pressure CO2 Hydrogenation to Methanol over Gold Nanoparticles Activated on a CeO(x)/TiO2 Interface.
Xiaofang Yang (2015)
10.1002/anie.201610166
CO2 -to-Methanol Hydrogenation on Zirconia-Supported Copper Nanoparticles: Reaction Intermediates and the Role of the Metal-Support Interface.
Kim Larmier (2017)
10.1016/S0926-860X(98)00408-6
On the elementary steps of acid zeolite catalyzed amination of light alcohols
V. Veefkind (1999)
10.1039/C6CY02459A
Unusual deactivation of HZSM-5 zeolite in the methanol to hydrocarbon reaction
L. Qi (2017)
10.1021/ar700210f
Reactivity of surface alkoxy species on acidic zeolite catalysts.
W. Wang (2008)
10.1021/jacs.7b00058
Confinement of Ultrasmall Cu/ZnOx Nanoparticles in Metal-Organic Frameworks for Selective Methanol Synthesis from Catalytic Hydrogenation of CO2.
B. An (2017)
10.1016/J.CHEMPR.2017.06.017
Direct Transformation of Syngas to Aromatics over Na-Zn-Fe5C2 and Hierarchical HZSM-5 Tandem Catalysts
B. Zhao (2017)
10.1016/0021-9517(94)90029-9
Methylamine synthesis over solid acid catalysts: Microcalorimetric and infrared spectroscopic studies of adsorbed species
D. T. Chen (1994)
10.1039/c7cc04768a
Direct conversion of syngas to aromatics.
Junhao Yang (2017)
10.1039/c1cs15008a
Recent advances in catalytic hydrogenation of carbon dioxide.
W. Wang (2011)
10.1021/acs.nanolett.7b01139
Tandem Catalysis for CO2 Hydrogenation to C2-C4 Hydrocarbons.
Chenlu Xie (2017)
10.1016/J.JOULE.2017.09.003
What Should We Make with CO2 and How Can We Make It
Oleksandr S Bushuyev (2018)
10.1038/nchem.2794
Direct conversion of CO2 into liquid fuels with high selectivity over a bifunctional catalyst
P. Gao (2017)
10.1126/science.aal3573
Active sites for CO2 hydrogenation to methanol on Cu/ZnO catalysts
Shyam Kattel (2017)
10.1039/C4CY01010H
Atmospheric pressure synthesis of nanosized ZSM-5 with enhanced catalytic performance for methanol to aromatics reaction
K. Shen (2014)
10.1016/J.JCAT.2016.07.008
Direct and selective conversion of methanol to para-xylene over Zn ion doped ZSM-5/silicalite-1 core-shell zeolite catalyst
K. Miyake (2016)
10.1038/ncomms15174
Directly converting CO2 into a gasoline fuel
Jian Wei (2017)
10.1039/c5cc08471g
Bayberry-like ZnO/MFI zeolite as high performance methanol-to-aromatics catalyst.
Ning Wang (2016)
10.1006/JCAT.1998.2312
Reaction Pathways and Rate-Determining Steps in Reactions of Alkanes on H-ZSM5 and Zn/H-ZSM5 Catalysts☆
Joseph A. Biscardi (1999)
10.1016/S0920-5861(97)00003-5
Methylamines synthesis: A review
David R. Corbin (1997)
10.1016/J.JOULE.2017.12.004
Breaking Compromises in CO2 Reduction
B. Sutherland (2017)
10.1016/J.JOULE.2018.03.007
Photocatalytic Hydrogenation of Carbon Dioxide with High Selectivity to Methanol at Atmospheric Pressure
L. Wang (2018)
10.1021/ACSCATAL.5B00192
Increasing para-Xylene Selectivity in Making Aromatics from Methanol with a Surface-Modified Zn/P/ZSM-5 Catalyst
J. Zhang (2015)
10.1039/C4TA04444D
Centrifugation-free and high yield synthesis of nanosized H-ZSM-5 and its structure-guided aromatization of methanol to 1,2,4-trimethylbenzene
K. Shen (2014)
10.1021/ACSCATAL.6B02928
Pd2Ga-Based Colloids as Highly Active Catalysts for the Hydrogenation of CO2 to Methanol
Andrés García-Trenco (2017)
10.1016/0926-860X(93)80043-P
Hydrogenation of carbon dioxide to C1-C7 hydrocarbons via methanol on composite catalysts
T. Inui (1993)
10.1039/c7cc08642c
Selective transformation of carbon dioxide into lower olefins with a bifunctional catalyst composed of ZnGa2O4 and SAPO-34.
X. Liu (2018)
10.1039/C39920000767
Hydrocarbon synthesis from carbon dioxide and hydrogen over Cu–Zn–Cr oxide/zeolite hybrid catalysts
M. Fujiwara (1992)
10.1126/science.1219831
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts
M. Behrens (2012)



This paper is referenced by
10.1016/j.apcatb.2020.119648
Precisely Regulating Brønsted Acid Sites to Promote the Synthesis of Light Aromatics via CO2 Hydrogenation
Jian Wei (2021)
10.1016/j.cogsc.2020.100386
Hydrogenation of carbon dioxide: From waste to value
A. Braga (2020)
10.1016/j.apsusc.2020.146622
The evolutions of carbon and iron species modified by Na and their tuning effect on the hydrogenation of CO2 to olefins
Chongyang Wei (2020)
10.1016/j.joule.2020.07.009
Cu-Ag Tandem Catalysts for High-Rate CO2 Electrolysis toward Multicarbons
Chubai Chen (2020)
10.1039/c8cs00502h
New horizon in C1 chemistry: breaking the selectivity limitation in transformation of syngas and hydrogenation of CO2 into hydrocarbon chemicals and fuels.
W. Zhou (2019)
10.1016/j.apcatb.2020.118792
Direct conversion of CO2 to aromatics with high yield via a modified Fischer-Tropsch synthesis pathway
Yang Wang (2020)
10.1021/acscentsci.0c00976
Novel Heterogeneous Catalysts for CO2 Hydrogenation to Liquid Fuels
P. Gao (2020)
10.1016/j.jcat.2020.06.018
Atomically dispersed Ptn+ species as highly active sites in Pt/In2O3 catalysts for methanol synthesis from CO2 hydrogenation
Z. Han (2020)
10.1002/adma.202002927
Applications of Zeolites to C1 Chemistry: Recent Advances, Challenges, and Opportunities.
Qiang Zhang (2020)
10.1007/S11708-019-0628-9
Photocatalytic reduction of carbon dioxide by titanium oxide-based semiconductors to produce fuels
X. Chen (2019)
10.1016/J.FUEL.2020.119151
Engineering Ni/SiO2 catalysts for enhanced CO2 methanation
Run-ping Ye (2021)
10.1039/d0nr03115a
Surface-coordinated metal-organic framework thin films (SURMOFs) for electrocatalytic applications.
Y. Xiao (2020)
10.1038/s41467-019-13638-9
CO2 hydrogenation to high-value products via heterogeneous catalysis
Run-Ping Ye (2019)
10.1016/j.matt.2019.09.001
Highly Efficient AuPd Catalyst for Synthesizing Polybenzoxazole with Controlled Polymerization
C. Yu (2019)
10.1016/j.enchem.2020.100038
Realizing efficient carbon dioxide hydrogenation to liquid hydrocarbons by tandem catalysis design
Xinhua Gao (2020)
10.1016/J.CHEMPR.2020.08.026
Catalysis for Selected C1 Chemistry
Y. Liu (2020)
10.1002/cssc.201903576
Well-Defined Core-Shell-Structured Capsule Catalyst for Direct Conversion of CO2 into Liquefied Petroleum Gas.
Hangjie Li (2020)
10.1039/c9cp03541a
Understanding photoelectrochemical kinetics in a model CO2 fixation reaction.
B. Zhong (2019)
10.1016/j.chempr.2020.09.025
Selective Conversion of CO2 into Propene and Butene
Sen Wang (2020)
10.3390/CATAL9030275
Hydrogenation of Carbon Dioxide to Value-Added Chemicals by Heterogeneous Catalysis and Plasma Catalysis
M. Liu (2019)
10.1016/j.jclepro.2020.123999
A review on CO2 capture via nitrogen-doped porous polymers and catalytic conversion as a feedstock for fuels
A. Mukhtar (2020)
10.1016/J.CCR.2019.02.001
Metal-organic framework-based heterogeneous catalysts for the conversion of C1 chemistry: CO, CO2 and CH4
Wen-Gang Cui (2019)
10.1002/solr.201900456
A Novel Double Perovskite Oxide Semiconductor Sr 2 CoWO 6 as Bifunctional Photocatalyst for Photocatalytic Oxygen and Hydrogen Evolution Reactions from Water under Visible Light Irradiation
A. Idris (2020)
10.1126/sciadv.aba5433
Selective methylation of toluene using CO2 and H2 to para-xylene
Jiachang Zuo (2020)
10.1039/C9CY00750D
Direct production of aromatics from syngas over a hybrid FeMn Fischer–Tropsch catalyst and HZSM-5 zeolite: local environment effect and mechanism-directed tuning of the aromatic selectivity
T. Wang (2019)
10.1002/cctc.202000036
Catalytic Methylation of Aromatic Hydrocarbons using CO2/H2 over Re/TiO2 and H‐MOR Catalysts
Kah Wei Ting (2020)
10.1039/d0se01314e
Hydrogen-efficient non-oxidative transformation of methanol into dimethoxymethane over a tailored bifunctional Cu catalyst
Ruiyan Sun (2020)
Semantic Scholar Logo Some data provided by SemanticScholar