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Chemical Modification Of Reduced Graphene Oxide With Sulfonic Acid Groups: Efficient Solid Acids For Acetalization And Esterification Reactions

M. Hosseini, Majid Masteri-Farahani, Samaneh Shahsavarifar
Published 2019 · Chemistry
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Abstract Surface chemical modification of reduced graphene oxide (rGO) with sulfonic acid groups produced two solid acids for acid-catalyzed reactions. One of the solid acids was prepared by covalent modification of rGO with oleum to achieve rGO-SO3H. The second solid acid obtained from the reaction of diazonium salt of para-amino benzene sulfonic acid with rGO. The prepared solid acids were characterized by various physicochemical methods which verified the successful modification of rGO with sulfonic acid groups. Catalytic activities of the obtained solid acids were evaluated and compared in the esterification of acetic acid with butanol and acetalization of benzaldehyde with ethylene glycol which indicated excellent catalytic efficiencies in both reactions. Both solid acids exhibited very high and almost identical conversion in esterification and acetalization reactions in short times, indicating the good catalytic efficiency of these solid acids for production of fine chemicals.
This paper references
10.1007/s00706-016-1762-2
Green and recyclable sulfonated graphene and graphene oxide nanosheet catalysts for the syntheses of 3,4-dihydropyrimidinones
Esmail Vessally (2016)
10.1016/J.CEJ.2017.07.020
Valorization of biomass to hydroxymethylfurfural, levulinic acid, and fatty acid methyl ester by heterogeneous catalysts
Season S. Chen (2017)
10.1016/J.CEJ.2014.09.025
Sulfonic acid-functionalized MIL-101(Cr): An efficient catalyst for esterification of oleic acid and vapor-phase dehydration of butanol
Z. Inamul Hasan (2015)
10.1002/cssc.201700950
Highly Efficient Sulfonic/Carboxylic Dual-Acid Synergistic Catalysis for Esterification Enabled by Sulfur-Rich Graphene Oxide.
Honglei Zhang (2017)
10.1007/s11164-016-2745-y
Eco-friendly highly efficient solvent free synthesis of benzimidazole derivatives over sulfonic acid functionalized graphene oxide in ambient condition
Mantosh B. Swami (2016)
10.1039/C4GC01470G
Syntheses of novel halogen-free Brønsted–Lewis acidic ionic liquid catalysts and their applications for synthesis of methyl caprylate
Xiaoxiang Han (2015)
10.1016/J.CATTOD.2014.04.010
Solid acids: Green alternatives for acid catalysis
P. Gupta (2014)
10.1002/cssc.201301149
Sulfonated graphene oxide as effective catalyst for conversion of 5-(hydroxymethyl)-2-furfural into biofuels.
Margarida M Antunes (2014)
10.1039/C5RA14813H
A novel poly(p-styrenesulfonic acid) grafted carbon nanotube/graphene oxide architecture with enhanced catalytic performance for the synthesis of benzoate esters and fatty acid alkyl esters
Gang Bian (2015)
10.1016/J.CATCOM.2016.02.019
Enhanced esterification of carboxylic acids with ethanol using propylsulfonic acid-functionalized natural rubber/hexagonal mesoporous silica nanocomposites
Sakdinun Nuntang (2016)
10.1039/c3dt52098f
Synthesis of sulfonic acid-functionalized Fe3O4@C nanoparticles as magnetically recyclable solid acid catalysts for acetalization reaction.
Fangcai Zheng (2014)
10.1016/J.CARBON.2011.10.007
Carbocatalytic dehydration of xylose to furfural in water
Edmond W.M. Lam (2012)
10.1021/EF500129X
Upgrading Bio-oil: Simultaneous Catalytic Esterification of Acetic Acid and Alkylation of Acetaldehyde
Jun Ye (2014)
10.1039/C3CY01081C
p-Sulfonic acid calix[n]arenes: the most active and water tolerant organocatalysts in esterification reactions
Ricardo Natalino (2014)
10.1039/C4GC01044B
Etherification of glycerol with isobutene on sulfonated graphene: reaction and separation
Jinxia Zhou (2014)
10.1016/J.RENENE.2017.01.024
Biodiesel production from palm oil using sulfonated graphene catalyst
Medy C. Nongbe (2017)
10.1016/J.COLSURFA.2017.11.025
Covalent functionalization of graphene oxide with molybdenum-carboxylate complexes: New reusable catalysts for the epoxidation of olefins
Majid Masteri-Farahani (2018)
10.1016/J.CATCOM.2017.06.026
Synthesis and sulfation of titanium based metal organic framework; MIL-125 and usage as catalyst in esterification reactions
Esra Yılmaz (2017)
10.1016/J.ELECTACTA.2018.10.068
One-step hydrothermal synthesis of three-dimensional nitrogen-doped reduced graphene oxide hydrogels anchored PtPd alloyed nanoparticles for ethylene glycol oxidation and hydrogen evolution reactions
Ya-Cheng Shi (2019)
10.1016/j.catcom.2006.05.050
Sulfonic acid functionalized mesoporous SBA-15 for selective synthesis of 4-phenyl-1,3-dioxane
S. S. Reddy (2007)
10.1039/C2JM15644J
Grafting of oxo-vanadium Schiff base on graphene nanosheets and its catalytic activity for the oxidation of alcohols
Harshal P. Mungse (2012)
10.1038/s41598-017-04143-4
Sulfonated reduced graphene oxide catalyzed cyclization of hydrazides and carbon dioxide to 1,3,4-oxadiazoles under sonication
Manuri Brahmayya (2017)
10.1039/C3GC40353J
Chemical conversion of biomass-derived hexose sugars to levulinic acid over sulfonic acid-functionalized graphene oxide catalysts
Pravin P. Upare (2013)
10.1021/nn1006368
Improved synthesis of graphene oxide.
D. Marcano (2010)
10.1039/C3GC40136G
Hydrolysis of cellulose to glucose by solid acid catalysts
Yao-Bing Huang (2013)
10.1039/C3GC40297E
Mesoporous poly-melamine-formaldehyde (mPMF) – a highly efficient catalyst for chemoselective acetalization of aldehydes
Mei Xuan Tan (2013)
10.1016/j.msec.2016.10.065
Synthesis and antioxidant activity of star-shape phenolic antioxidants catalyzed by acidic nanocatalyst based on reduced graphene oxide.
Mohsen Golestanzadeh (2017)
10.1007/s10563-017-9226-1
Sulfonic Acid-Functionalized Solid Acid Catalyst in Esterification and Transesterification Reactions
Shagufta (2017)
10.1016/j.jcis.2017.08.059
One-pot fabrication of reduced graphene oxide supported dendritic core-shell gold@gold-palladium nanoflowers for glycerol oxidation.
J. Feng (2018)
10.1039/C4NJ02340D
Microwave-assisted synthesis of 6,6′-(aryl(alkyl)methylene)bis(2,4-dialkylphenol) antioxidants catalyzed by multi-sulfonated reduced graphene oxide nanosheets in water
Hossein Naeimi (2015)
10.1016/J.MOLCATA.2013.12.005
Synthesis of sulfonic acid-functionalized MIL-101 for acetalization of aldehydes with diols
Yan Jin (2014)
10.1007/s00706-013-1022-7
Synthesis of a novel melamine-formaldehyde resin-supported ionic liquid with Brønsted acid sites and its catalytic activities
Guiying Xing (2013)
10.1039/C2JM16608A
Sulfated graphene as an efficient solid catalyst for acid-catalyzed liquid reactions
Fujian Liu (2012)
10.1002/CCTC.201402254
Graphene Oxide and Its Functionalized Derivatives as Carbocatalysts in the Multicomponent Strecker Reaction of Ketones
Ananya Sengupta (2014)
10.1007/S10563-008-9044-6
Functionalized SBA-15 and its Catalytic Applications in Selective Organic Transformations
Darbha Srinivas (2008)
10.1039/C5TA05605E
Al-coordination polymer-derived nanoporous nitrogen-doped carbon microfibers as metal-free catalysts for oxygen electroreduction and acetalization reactions
Zhen Han (2015)
10.1039/C3CY00044C
Sulfonic acid-functionalized MIL-101 as a highly recyclable catalyst for esterification
Yindi Zang (2013)
10.1016/J.CATCOM.2012.05.007
A comparative investigation of palmitic acid esterification over p-sulfonic acid calix[4]arene and sulfuric acid catalysts via 1H NMR spectroscopy
Sergio Antonio Fernandes (2012)
10.1016/J.JPOWSOUR.2015.05.091
Hydrogen generation from deliquescence of ammonia borane using Ni–Co/r-GO catalyst
Chang Chen Chou (2015)
10.1016/J.CARBON.2013.09.005
Simultaneous sulfonation and reduction of graphene oxide as highly efficient supports for metal nanocatalysts
Daping He (2014)
10.1039/c5cc08344c
Graphitic carbon nitride catalysed photoacetalization of aldehydes/ketones under ambient conditions.
M. Abdullah Khan (2016)
10.1021/SC5008412
Brønsted Acidic Polymer Nanotubes with Tunable Wettability toward Efficient Conversion of One-Pot Cellulose to 5-Hydroxymethylfurfural
Yunlei Zhang (2015)
10.1016/j.jcis.2018.01.047
Controlled fabrication of well-dispersed AgPd nanoclusters supported on reduced graphene oxide with highly enhanced catalytic properties towards 4-nitrophenol reduction.
Xiaoyan Zhu (2018)
10.1002/SLCT.201800302
Tunable Fabrication of NiAl‐LDHs Containing Acid Activity Sites as Green Catalyst for Acetalization of Furfural to Furfural Diethyl Acetal
Yali Du (2018)
10.1016/J.MATCHEMPHYS.2017.07.028
Clicked graphene oxide supported venturello catalyst: A new hybrid nanomaterial as catalyst for the selective epoxidation of olefins
Majid Masteri-Farahani (2017)
10.1039/C3CY00272A
Towards acid MOFs – catalytic performance of sulfonic acid functionalized architectures
Jana Juan-Alcañiz (2013)
10.1039/C4RA12695E
Catalytic acetoxylation of lactic acid to 2-acetoxypropionic acid, en route to acrylic acid
R. K. Beerthuis (2015)
10.1039/c5nr01770j
Supramolecular fabrication of multilevel graphene-based gas sensors with high NO2 sensibility.
Zhuo Chen (2015)
10.1016/J.MOLCATA.2011.08.005
Acetalization of carbonyl compounds catalyzed by acidic ionic liquid immobilized on silica gel
Jinmei Miao (2011)
10.1016/J.JTICE.2011.02.002
The synthesis of heterogeneous 7-amino-1-naphthalene sulfonic acid immobilized silica nano particles and its catalytic activity
Farook Adam (2011)
10.1016/J.COLSURFA.2017.06.073
Clicked graphene oxide as new support for the immobilization of peroxophosphotungstate: Efficient catalysts for the epoxidation of olefins
Majid Masteri-Farahani (2017)
10.1021/ja105089w
Structure-directing role of graphene in the synthesis of metal-organic framework nanowire.
Maryam Jahan (2010)
10.1016/j.jcat.2005.01.017
Acidic properties of sulfonic acid-functionalized FSM-16 mesoporous silica and its catalytic efficiency for acetalization of carbonyl compounds
Ken-ichi Shimizu (2005)
10.1039/C6RA23420H
One-pot synthesis of sulfonated graphene oxide for efficient conversion of fructose into HMF
Qidong Hou (2016)
10.1039/C0SC00484G
Sulfonated graphene as water-tolerant solid acid catalyst
Junyi Ji (2011)
10.1016/J.CEJ.2011.09.072
Synthesis of monoglyceride through glycerol esterification with lauric acid over propyl sulfonic acid post-synthesis functionalized SBA-15 mesoporous catalyst
L. Hermida (2011)



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