Online citations, reference lists, and bibliographies.

Cross-linked Mixed Matrix Membranes (MMMs) Consisting Of Amine-functionalized Multi-walled Carbon Nanotubes And P84 Polyimide For Organic Solvent Nanofiltration (OSN) With Enhanced Flux

Mohammad Hossein Farahani, Dan Hua, T. F. Chung
Published 2018 · Chemistry
Cite This
Download PDF
Analyze on Scholarcy
Share
Abstract High-flux mixed matrix membranes (MMMs) for organic solvent nanofiltration (OSN) were designed using amine-functionalized multi-walled carbon nanotubes (NH2-MWCNTs) and P84 polyimide with the aid of 1,6-hexanediamine (HDA) as a cross-linker and thermal annealing to tighten the pore size. The embedding of hydrophilic NH2-MWCNTs into the P84 matrix not only enhanced membrane's porosity, sorption capacity, and liquid transport but also resulted in an amidation reaction between them. The resultant MMMs had higher water, ethanol, and isopropanol permeances than the pristine P84 one. However, a higher loading of NH2-MWCNTs diminished the rejection due to visible agglomeration among them. The cross-linked MMMs consisting of 2 mg/g of NH2-MWCNTs/P84 showed a rejection of > 98% to eosin Y (MW of 648 g/mol) while pure water, ethanol, and IPA permeances were 16.4, 3.3, and 1.4 LMH/bar at 20 bar, respectively. Moreover, they showed a superlative rejection of 92.1% to tetracycline, a smaller drug solute with a MW of 444 g/mol, in IPA solutions after thermal annealing at 120 °C for 40 min. Interestingly, the annealed MMMs still possessed a higher ethanol flux and solute rejections than the pristine P84 membrane. Besides, they also showed promising OSN performance in 72-h continuous tests.
This paper references
10.1016/J.MEMSCI.2017.01.038
Thermally treated ammonia functionalized graphene oxide/polyimide membranes for pervaporation dehydration of isopropanol
Peyman Salehian (2017)
10.1002/AIC.14558
Enhancement of flux and solvent stability of Matrimid® thin‐film composite membranes for organic solvent nanofiltration
Shipeng Sun (2014)
10.1039/C5RA09546H
UV irradiation-induced cross-linked bicarbonate anion exchange membranes based on vinylimidazolium-functionalized poly(arylene ether ketone)
Fanzhe Bu (2015)
10.1021/cr050569o
Chemistry of carbon nanotubes.
Dimitrios Tasis (2006)
10.1021/ie990799r
Factors controlling successful formation of mixed-matrix gas separation materials
Rajiv Mahajan (2000)
10.3390/nano7050099
Carbon Nanotube Membranes: Synthesis, Properties, and Future Filtration Applications
Md. Harun-or Rashid (2017)
10.1016/J.MEMSCI.2007.12.060
Comparison of diamino cross-linking in different polyimide solutions and membranes by precipitation observation and gas transport
Lu Shao (2008)
10.1016/J.MEMSCI.2008.04.026
Cross-linked polyimide membranes for solvent resistant nanofiltration in aprotic solvents
Katrien Vanherck (2008)
10.1016/J.CARBON.2017.07.011
Polyelectrolyte functionalized lamellar graphene oxide membranes on polypropylene support for organic solvent nanofiltration
Dan Hua (2017)
10.1016/j.memsci.2005.01.039
Polymeric nanofiltration of binary water–alcohol mixtures: Influence of feed composition and membrane properties on permeability and rejection
Jeroen Geens (2005)
10.1016/J.MEMSCI.2016.01.024
Hybrid Polymer/MOF membranes for Organic Solvent Nanofiltration (OSN): Chemical Modification and the Quest for Perfection
John Robert Campbell (2016)
10.1016/J.MEMSCI.2016.09.027
Crosslinked poly(ether block amide) composite membranes for organic solvent nanofiltration applications
Jamaliah Aburabie (2017)
10.1016/J.MEMSCI.2016.04.011
Mixed matrix membranes containing functionalized multiwalled carbon nanotubes: Mesoscale simulation and experimental approach for optimizing dispersion
Chi Hoon Park (2016)
10.1016/J.PROGPOLYMSCI.2012.11.001
Crosslinking polyimides for membrane applications: A review
Katrien Vanherck (2013)
10.1016/J.MEMSCI.2013.07.009
Influence of the blend composition on the properties and separation performance of novel solvent resistant polyphenylsulfone/polyimide nanofiltration membranes
Johannes Carolus Jansen (2013)
10.1002/aic.10029
Hybrid membrane materials comprising organic polymers with rigid dispersed phases
Theodore T. Moore (2004)
10.1016/j.memsci.2006.08.013
Fabrication and characterization of multi-walled carbon nanotubes/polymer blend membranes
Jae Hyun Choi (2006)
10.1039/c0cp00230e
Mechanisms of solute rejection in solvent resistant nanofiltration: the effect of solvent on solute rejection.
Siavash Darvishmanesh (2010)
10.1002/ADV.21455
Recent Advances in Polymeric Solvent-Resistant Nanofiltration Membranes
Xi Cheng (2014)
10.1016/J.MEMSCI.2009.09.059
Solvent flux behavior and rejection characteristics of hydrophilic and hydrophobic mesoporous and microporous TiO2 and ZrO2 membranes
Agnieszka Dobrak (2010)
10.1016/J.MEMSCI.2014.07.019
Mineralization-inspired preparation of composite membranes with polyethyleneimine–nanoparticle hybrid active layer for solvent resistant nanofiltration
Haoqing Zhang (2014)
10.1021/cr500006j
Molecular separation with organic solvent nanofiltration: a critical review.
Patrizia Marchetti (2014)
10.1016/J.CES.2013.11.043
Cross-linked polyacrylonitrile/polyethyleneimine–polydimethylsiloxane composite membrane for solvent resistant nanofiltration
Haoqin Zhang (2014)
10.1002/aic.10964
Diamine modification of P84 polyimide membranes for pervaporation dehydration of isopropanol
Xiangyi Qiao (2006)
10.1039/C5TA01715G
Simultaneously covalent and ionic bridging towards antifouling of GO-imbedded nanocomposite hollow fiber membranes
Yu Pan Tang (2015)
10.1016/J.MEMSCI.2016.07.034
Novel thin film composite forward osmosis membrane of enhanced water flux and anti-fouling property with N-[3-(trimethoxysilyl) propyl] ethylenediamine incorporated
Shu Xiong (2016)
10.1039/B500401B
Zeolite filled polydimethylsiloxane (PDMS) as an improved membrane for solvent-resistant nanofiltration (SRNF).
Lieven E. M. Gevers (2005)
10.1016/j.carbon.2006.06.032
Functionalization of carbon nanotubes using a silane coupling agent
Peng-cheng Ma (2006)
10.1016/J.MEMSCI.2013.05.016
Natural gas purification and olefin/paraffin separation using thermal cross-linkable co-polyimide/ZIF-8 mixed matrix membranes
Mohammad Askari (2013)
10.1016/J.COMPOSITESA.2010.07.003
DISPERSION AND FUNCTIONALIZATION OF CARBON NANOTUBES FOR POLYMER-BASED NANOCOMPOSITES: A REVIEW
Peng-cheng Ma (2010)
10.1016/J.PROGPOLYMSCI.2009.06.001
Polyimides membranes for pervaporation and biofuels separation
Lan Ying Jiang (2009)
10.1016/S0376-7388(02)00423-4
Nanofiltration-based diafiltration process for solvent exchange in pharmaceutical manufacturing
Jignesh P. Sheth (2003)
10.1021/ie050836g
Fundamental Characteristics of Sorption, Swelling, and Permeation of P84 Co-polyimide Membranes for Pervaporation Dehydration of Alcohols
Xiangyi Qiao (2005)
10.1016/J.MEMSCI.2008.07.023
Controlling molecular weight cut-off curves for highly solvent stable organic solvent nanofiltration (OSN) membranes
Yoong Hsiang See-Toh (2008)
10.1016/j.envpol.2010.03.024
The use of nanoparticles in polymeric and ceramic membrane structures: review of manufacturing procedures and performance improvement for water treatment.
Jeonghwan Kim (2010)
10.1039/C6TA05175H
Controlled positioning of MOFs in interfacially polymerized thin-film nanocomposites
Charles Van Goethem (2016)
10.1016/J.MEMSCI.2012.07.026
Solvent nanofiltration through high permeability glassy polymers: Effect of polymer and solute nature
Sergey Tsarkov (2012)
10.1021/jp709845u
Designing carbon nanotube membranes for efficient water desalination.
Ben Corry (2008)
10.1016/J.MEMSCI.2016.12.026
Nanocomposite organic solvent nanofiltration membranes by a highly-efficient mussel-inspired co-deposition strategy
Yanchao Xu (2017)
10.1016/j.memsci.2005.03.019
The effects of polymer chain rigidification, zeolite pore size and pore blockage on polyethersulfone (PES)-zeolite A mixed matrix membranes
Yi Li (2005)
10.1039/C4TA00316K
ZIF-71 as a potential filler to prepare pervaporation membranes for bio-alcohol recovery
Yingtao Li (2014)
10.1039/b610848m
Solvent resistant nanofiltration: separating on a molecular level.
Pieter Vandezande (2008)
10.1016/J.MEMSCI.2012.02.008
High performance organic solvent nanofiltration membranes: Development and thorough testing of thin film composite membranes made of polymers of intrinsic microporosity (PIMs)
Detlev Fritsch (2012)
10.1039/C5RA10259F
Mixed matrix membranes containing MIL-53(Al) for potential application in organic solvent nanofiltration
Lifang Zhu (2015)
10.1016/0376-7388(93)85032-R
Aqueous quenched asymmetric polysulfone membranes prepared by dry/wet phase separation
S. C. Pesek (1993)
10.1016/J.MEMSCI.2009.07.026
Impact of TiO2 nanoparticles on morphology and performance of crosslinked polyimide organic solvent nanofiltration (OSN) membranes
Iwona Soroko (2009)
10.1080/00268970500108403
Comparisons of diffusive and viscous contributions to transport coefficients of light gases in single-walled carbon nanotubes
Suresh K. Bhatia (2005)
10.1016/J.MEMSCI.2014.04.031
Fouling reduction and retention increment of polyethersulfone nanofiltration membranes embedded by amine-functionalized multi-walled carbon nanotubes
Vahid Vatanpour (2014)
10.1016/J.MEMSCI.2013.10.036
Polyethyleneimine (PEI) cross-linked P84 nanofiltration (NF) hollow fiber membranes for Pb2+ removal
Jie Gao (2014)
10.1016/J.MEMSCI.2011.07.007
Organic solvent nanofiltration: A platform for removal of genotoxins from active pharmaceutical ingr
Gyorgy Szekely (2011)
10.1016/J.MEMSCI.2014.08.051
Preparation and characterization of emulsion poly(vinyl chloride) (EPVC)/TiO2 nanocomposite ultrafiltration membrane
Hesamoddin Rabiee (2014)
10.1016/J.MEMSCI.2014.01.030
Pervaporation dehydration of acetone using P84 co-polyimide flat sheet membranes modified by vapor phase crosslinking
Dave Mangindaan (2014)
10.1016/S0032-3861(01)00358-5
States of water in different hydrophilic polymers — DSC and FTIR studies
Zhenghua Ping (2001)
10.1016/J.MEMSCI.2017.04.038
Improved performance of thin-film composite membrane with PVDF/PFSA substrate for forward osmosis process
Xuan Zhang (2017)
10.1016/J.PROGPOLYMSCI.2009.09.003
Carbon nanotube–polymer composites: Chemistry, processing, mechanical and electrical properties
Zdenko Špitalský (2010)
10.1016/J.MEMSCI.2008.04.057
Interfacially polymerized thin film composite membranes on microporous polypropylene supports for solvent-resistant nanofiltration
P. Kosaraju (2008)
10.1021/jp9944280
A Computational Study of Molecular Diffusion and Dynamic Flow through Carbon Nanotubes
Zugang Mao (2000)
10.1016/J.SEPPUR.2017.06.021
Cross-linked mixed matrix membranes consisting of carboxyl-functionalized multi-walled carbon nanotubes and P84 polyimide for organic solvent nanofiltration (OSN)
Mohammad Hossein Farahani (2017)
10.1016/J.CARBON.2011.03.051
One-step synthesis of NH2-graphene from in situ graphene-oxide reduction and its improved electrochemical properties
Linfei Lai (2011)
10.1016/J.MEMSCI.2012.02.029
Multi-walled carbon nanotubes (MWCNTs) mixed polyacrylonitrile (PAN) ultrafiltration membranes
Shahid Majeed (2012)
10.1039/C3GC41634H
The ionic liquid [EMIM]OAc as a solvent to fabricate stable polybenzimidazole membranes for organic solvent nanofiltration
Ding Yu Xing (2014)
10.1016/J.MEMSCI.2010.02.046
A simplified diamine crosslinking method for PI nanofiltration membranes
Katrien Vanherck (2010)



This paper is referenced by
10.1039/d0ta02150d
Accurately controlling the hierarchical nanostructure of polyamide membranes via electrostatic atomization-assisted interfacial polymerization
Jingjing Chen (2020)
10.1016/j.cis.2020.102126
Functionalization of carbon nanotubes by combination of controlled radical polymerization and "grafting to" method.
Zahra Abousalman-Rezvani (2020)
10.1016/j.jenvman.2019.109358
Antifouling and antibacterial evaluation of ZnO/MWCNT dual nanofiller polyethersulfone mixed matrix membrane.
Wen Yu Pang (2019)
10.1016/J.MEMSCI.2018.12.047
Facile synthesis of Kevlar nanofibrous membranes via regeneration of hydrogen bonds for organic solvent nanofiltration
Shushan Yuan (2019)
10.1016/J.CEJ.2018.03.153
Solvent resistant hollow fiber membranes comprising P84 polyimide and amine-functionalized carbon nanotubes with potential applications in pharmaceutical, food, and petrochemical industries
Mohammad Hossein Farahani (2018)
10.1016/j.envres.2020.109278
A high-flux P84 polyimide mixed matrix membranes incorporated with cadmium-based metal organic frameworks for enhanced simultaneous dyes removal: Response surface methodology.
Mohammad Mehdi Baneshi (2020)
10.1016/j.memsci.2020.118049
A thin and high loading two-dimensional MOF nanosheet based mixed-matrix membrane for high permeance nanofiltration
Lun Shu (2020)
10.1016/j.seppur.2019.116033
Polyetheramide organic solvent nanofiltration membrane prepared via an interfacial assembly and polymerization procedure
Muntadher M. Alwan Almijbilee (2020)
10.1021/acsami.9b12445
Ultrathin membranes with polymer/nanofiber inter-penetrated structure for high-efficiency liquid separations.
Yufan Ji (2019)
10.1002/ADMI.201800823
Thin‐Film Composite Polyionic Liquid Gel Membranes and Their Potential for Nanofiltration in Organic Solvents
S. Al-Kharabsheh (2018)
10.1016/j.seppur.2020.116545
A high-permeance organic solvent nanofiltration membrane via covalently bonding mesoporous MCM-41 with polyimide
Zhihao Si (2020)
10.1016/J.SEPPUR.2018.01.031
A comprehensive study on the performance and antifouling enhancement of the PVDF mixed matrix membranes by embedding different nanoparticulates: Clay, functionalized carbon nanotube, SiO2 and TiO2
Mohammad Hossein Farahani (2018)
10.1016/J.MEMSCI.2019.117261
Fabrication and characterization of a defect-free mixed matrix membrane by facile mixing PPSU with ZIF-8 core–shell microspheres for solvent-resistant nanofiltration
Juan Dai (2019)
10.1016/J.MEMSCI.2018.12.027
High nanoparticles loadings mixed matrix membranes via chemical bridging-crosslinking for CO2 separation
Rui Xu (2019)
10.1016/J.SEPPUR.2018.10.041
Fabrication of high-performance antibiofouling ultrafiltration membranes with potential application in membrane bioreactors (MBRs) comprising polyethersulfone (PES) and polycitrate-Alumoxane (PC-A)
Meghdad Pirsaheb (2019)
2D materials for improved membrane technology
Monica Raquel Pedrosa Alberto (2018)
10.2174/1389200220666181127104812
Removal of Pharmaceutical Contaminants in Wastewater using Nanomaterials: A Comprehensive Review.
Anjali Chauhan (2018)
10.1016/J.SEPPUR.2019.115687
Improving ZIF-8 stability in the preparation process of polyimide-based organic solvent nanofiltration membrane
Ze Wang (2019)
10.1039/C8RA05507F
Three-channel capillary NF membrane with PAMAM-MWCNT-embedded inner polyamide skin layer for heavy metals removal
Hai-zhen Zhang (2018)
10.1039/C8TA08518H
A high flux organic solvent nanofiltration membrane from Kevlar aramid nanofibers with in situ incorporation of microspheres
Yi Li (2018)
10.1016/J.CES.2019.01.008
Fabrication of organic solvent nanofiltration membranes via facile bioinspired one-step modification
Yingnan Feng (2019)
10.1016/J.MEMSCI.2018.12.064
Vapor-phase crosslinked mixed matrix membranes with UiO-66-NH2 for organic solvent nanofiltration
Zhuo Fan Gao (2019)
10.1002/adfm.201906797
Ultrathin 2D-Layered Cyclodextrin Membranes for High- Performance Organic Solvent Nanofiltration
Tiefan Huang (2020)
10.1080/15422119.2018.1526805
Nanocomposite membranes for organic solvent nanofiltration
Mohammad Hossein Farahani (2020)
10.1016/J.CEJ.2019.03.044
Fluorine incorporation for enhancing solvent resistance of organic solvent nanofiltration membrane
Yi Guo (2019)
Contrôle de l'interaction polymère/particules dans les membranes à matrice mixte
Tien Binh Nguyen (2018)
10.1016/j.diamond.2020.107767
Direct observation of graphene during Raman analysis and the effect of precursor solution parameter on the graphene structures
Mohd Asyadi Azam (2020)
10.1016/J.CES.2019.04.022
High flux thin film nanocomposite membrane incorporated with functionalized TiO2@reduced graphene oxide nanohybrids for organic solvent nanofiltration
Hamidreza Abadikhah (2019)
10.3390/membranes9100128
Progress and Perspectives on Ceramic Membranes for Solvent Recovery
Senthilnathan Ruthusree (2019)
10.1039/C9TA01915D
Graphene oxide (GO)-interlayered thin-film nanocomposite (TFN) membranes with high solvent resistance for organic solvent nanofiltration (OSN)
Yanyang Li (2019)
10.1016/j.isci.2020.101065
Green Treatment of Phosphate from Wastewater Using a Porous Bio-Templated Graphene Oxide/MgMn-Layered Double Hydroxide Composite
Yi-Ting Lai (2020)
10.5004/dwt.2019.24614
Preparation and application of P84 copolyimide/GO mixed matrix membrane with improved permselectivity and solvent resistance
Runlin Han (2019)
See more
Semantic Scholar Logo Some data provided by SemanticScholar