Online citations, reference lists, and bibliographies.

Racemic Estrone Methyl Ether Is The Lamellar Conglomerate

V. P. Kislyi, Yan V Zubavichus, Kirill K. Babievsky, Viktor N Khrustalev, Kasimir K. Pivnitsky
Published 2019 · Chemistry
Cite This
Download PDF
Analyze on Scholarcy
Share
Methyl ether of racemic estrone, the long-known steroid, crystallizes in the form of a lamellar conglomerate. This form exhibits many properties of the ordinary conglomerates, however it requires special methods for the enantiomer separation due to pseudoracemic composition of the crystals.
This paper references
10.1016/j.tetlet.2004.03.166
A new total synthesis of (±)-oestrone
Gerald Pattenden (2004)
10.1016/S0009-2509(00)00442-5
Preferential crystallisation and comparative crystal growth study between pure enantiomer and racemic mixture of a chiral molecule: 5-ethyl-5-methylhydantoin
Stéphane Beilles (2001)
10.1002/chir.10237
Preparation of enantiomeric gossypol by crystallization.
Michael K. Dowd (2003)
Enantiomers, Racemates, and Resolutions
Jean Jacques (1981)
10.1016/S0039-128X(02)00181-2
Synthesis and receptor-binding examinations of the normal and 13-epi-D-homoestrones and their 3-methyl ethers
János Wölfling (2003)
10.1021/ja01131a037
The Total Synthesis of Estrone and Three Stereoisomers Including Lumiestrone
William S. Johnson (1952)
10.1016/S0040-4020(01)91468-1
Resolution and optical properties ([α]max, ord and cd) of hepta-, octa- and nonahelicene
Ricardo Martin (1974)
10.1021/cr020071b
Enantiomeric steroids: synthesis, physical, and biological properties.
J. F. Biellmann (2003)
10.1021/jp035588l
Lamellar Racemic Twinning as an Obstacle for the Resolution of Enantiomers by Crystallization: The Case of Me(All)N+(CH2Ph)Ph X-(X = Br, I) Salts
Vladimir Torbeev (2003)
10.1002/hlca.19480310739
Über Steroide. 83. Mitteilung. Die Synthese des natürlichen Oestrons. Totalsynthesen in der Oestronreihe III
Georg Anner (1948)
10.1021/ja01536a040
Configuration of the Estrones. Total Synthesis of the Remaining Stereoisomers
William S. Johnson (1958)
10.1016/j.steroids.2006.12.007
A facile total synthesis of ent-17β-estradiol and structurally related analogues
Zu Yun Cai (2007)
10.1021/ja01159a529
THE TOTAL SYNTHESIS OF ESTRONE AND THE REMAINING STEREOISOMERS
William S. Johnson (1950)
10.1002/ange.200802468
Attrition‐Enhanced Deracemization of an Amino Acid Derivative That Forms an Epitaxial Racemic Conglomerate
Bernard Kaptein (2008)
10.1016/S0040-4020(01)98930-6
Synthesis and circular dichroism studies of steroidal schiff bases of biogenic amines
Howard C. Price (1981)
10.1016/S0040-4020(00)00465-8
A Cyclic Continuous Process for Converting Conglomerates into Optically Pure Enantiomers by Crystallization and Dissolution with the Assistance of ‘Tailor-made’ Polymers
David Zbaida (2000)
10.1002/hlca.19490320623
Über Steroide. 93. Mitteilung. Die Synthese von weiteren Oestron‐Racematen. Totalsynthesen in der Oestronreihe IV
Georg Anner (1949)
10.1107/S0108767383001762
On enantiomorph‐polarity estimation
Howard D. Flack (1983)
10.1016/S0040-4020(01)99290-7
Syntheses of derivatives of oestrane and 19-norsteroids from 6-methoxytetralone and 6-hydroxytetralone
S. N. Ananchenko (1962)
10.1002/9783906390819
Classical Methods in Structure Elucidation of Natural Products
R. W. Hoffmann (2018)
10.1107/S0108767385001064
Least‐squares absolute‐structure refinement. Practical experience and ancillary calculations
Gérald Bernardinelli (1985)
10.1021/cr60325a001
Optical resolution by direct crystallization of enantiomer mixtures
André Collet (1980)
10.1002/hlca.19770600717
Totalsynthese von (+)‐D‐Homoöstron‐3‐methyläther
Juerg Albert Walter Gutzwiller (1977)
10.1021/jacs.5b05938
Are the Crystal Structures of Enantiopure and Racemic Mandelic Acids Determined by Kinetics or Thermodynamics?
Rebecca K. Hylton (2015)
10.1021/ja00381a018
RESOLUTION OF CONGLOMERATES WITH THE ASSISTANCE OF TAILOR-MADE IMPURITIES. GENERALITY AND MECHANISTIC ASPECTS OF THE “RULE OF REVERSAL”. A NEW METHOD FOR ASSIGNMENT OF ABSOLUTE CONFIGURATION
Lia Addadi (1982)
10.1002/anie.199616661
Oscillating Crystallization of (+) and (–) Enantiomers during Resolution by Entrainment of 2-Azabicyclo[2.2.1]hept-5-en-3-one†
Gerard Andrew Potter (1996)
10.1016/j.steroids.2008.11.019
ent-Steroids: Novel tools for studies of signaling pathways
Douglas F. Covey (2009)
10.1107/S0108767399004262
Absolute structure and absolute configuration.
Flack (1999)
10.1002/hlca.19500330538
Über Steroide. 98. Mitteilung. Zur Konstitution der synthetischen Oestronracemate. Totalsynthesen in der Oestronreihe V
Georg Anner (1950)
10.1524/zkri.1915.55.1.123
VII. Über die Krystallform der Phenylglyzerinsäure C6H5 C(OH)H C(OH)H COOH (Smp. 141° C.) und ihrer aktiven Komponenten
Victor Moritz Goldschmidt
10.1107/S0567740879010086
Steroid structure and function. III. Conformational transmission in 1,3,5(10)‐estratrienes
William L. Duax (1979)
10.1016/j.tetlet.2006.02.038
Short and simple synthesis of chelating bis-ethers and bis-amines in the bicyclo[3.3.1]nonane series
Felix H.V. Chau (2006)
10.1021/ja00452a045
A stereoselective total synthesis of estrone by an intramolecular cycloaddition reaction of olefinic o-quinodimethane.
Tomio Kametani (1977)
10.1126/science.214.4522.795
Lamellar Twinning Explains the Nearly Racemic Composition of Chiral, Single Crystals of Hexahelicene
Bernard S. Green (1981)
10.1002/(SICI)1521-4095(199903)11:4<328::AID-ADMA328>3.0.CO;2-V
‘Tailor‐made’ Polymers for the Removal of Lamellar Twinning: Resolution of α‐Amino Acids by Entrainment
Maria Berfeld (1999)
10.1016/S0040-4039(01)80565-7
Efficient approach to the oppolzer-kametani intermediate for estrone methyl ether using the conjugate addition-enolate methylation of the cyclopentenone containing an α-appended benzocyclobutane moiety
Takashi Takahashi (1989)
10.1007/978-1-4757-0587-4
Total steroid synthesis
A. A. Akhrem (1970)
10.1070/MC2001v011n04ABEH001469
Crystal properties of N-alkyl-substituted glycolurils as the precursors of chiral drugs
Remir G. Kostyanovsky (2001)
10.1039/C4CE00615A
Racemic compound versus conglomerate: concerning the crystal chemistry of the triazoylketone, 1-(4-chlorophenyl)-4,4-dimethyl-2-(1H-1,2,4-triazol-1-yl)pentan-3-one
Roger J Davey (2014)
10.1016/S0040-4039(00)93155-1
Boron annulation: total synthesis of (±)-estrone methyl ether
Thomas A. Bryson (1980)
10.1021/jp012622s
Oscillating crystallization in solution between (+)- and (-)-5-ethyl-5-methylhydantoin under the influence of stirring
Claire Gervais (2002)
10.1021/JP108527H
On the Crystallization of Epitaxial Racemic Conglomerates
W.J.P. van Enckevort (2010)



This paper is referenced by
Semantic Scholar Logo Some data provided by SemanticScholar