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Ce And La Modification Of Mesoporous Cu–Ni/SBA-15 Catalysts For Hydrogen Production Through Ethanol Steam Reforming

J. A. Calles, A. Carrero, A. J. Vizcaíno
Published 2009 · Chemistry

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Abstract A series of Cu–Ni catalysts supported on Ce- or La-modified SBA-15 was prepared and tested on ethanol steam reforming for hydrogen production. Samples were characterized by TGA, XRD, ICP-AES, N 2 -physisorption, TPR and TEM. XRD analyses revealed different tendencies in the dispersion of Ce and La on the SBA-15 mesoporous support. Bulk CeO 2 particles together with large NiO crystallites found on CuNi/CeO 2 /SBA-15 catalysts were responsible for their lower metallic dispersion and hydrogen production in comparison to CuNi/SBA-15 sample. At high La loadings (10–20%), the development of a La 2 O 3 layer over the SBA-15 support strengthened metal-support interaction and enhanced metallic dispersion, achieving an improvement in the CuNi/La 2 O 3 /SBA-15 catalytic performance. Particularly, the incorporation of 20 wt% of La led to a significant enhancement of hydrogen selectivity (from 77.2 to 85.4 mol%) and, mainly, an important reduction in coke deposition (from 42.3 to 26.3 w/w% after 3 h of time on stream).
This paper references
10.1016/S0920-5861(97)00014-X
Coke formation and minimisation during steam reforming reactions
D. Trimm (1997)
10.1126/SCIENCE.279.5350.548
Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores
Y Zhao (1998)
10.1016/S0927-7757(00)00731-7
Thermal genesis course and characterization of lanthanum oxide
G. A. Mekhemer (2001)
10.1016/J.CATTOD.2007.12.045
Preparation and characterization of nickel-based mixed-oxides and their performance for catalytic methane decomposition
M. E. Rivas (2008)
10.1016/0021-9517(89)90354-0
Dispersion studies on the system La2O3γ-Al2O3
Max Bettman (1989)
10.1016/J.IJHYDENE.2005.04.004
Thermodynamic analysis of ethanol/water system with the stoichiometric method
V. Mas (2006)
10.1016/J.APCATA.2005.05.002
Partial oxidation of methane to syngas over Ni/MgO and Ni/La2O3 catalysts
J. Requies (2005)
10.1016/J.JPOWSOUR.2008.06.002
H2 production from CH4 decomposition: Regeneration capability and performance of nickel and rhodium oxide catalysts
M. E. Rivas (2008)
10.1016/J.CATCOM.2004.07.015
H2 production for MC fuel cell by steam reforming of ethanol over MgO supported Pd, Rh, Ni and Co catalysts
F. Frusteri (2004)
10.1016/J.JPOWSOUR.2005.02.041
Ethanol oxidative steam reforming over Ni-based catalysts
V. Fierro (2005)
10.1016/0920-5861(95)00005-4
Effects of promoters and preparation procedures on reforming of methane with carbon dioxide over Ni/Al2O3 catalyst
Zhenxing Cheng (1996)
10.1016/S0926-3373(98)00081-2
Role of CeO2 in Ni/CeO2–Al2O3 catalysts for carbon dioxide reforming of methane
S. Wang (1998)
10.1016/S0360-3199(97)00173-0
Hydrogen from steam reforming of ethanol. characterization and performance of copper-nickel supported catalysts
F. Mariño (1998)
10.1016/S0926-860X(01)00842-0
Perspectives in catalytic applications of mesostructured materials
D. T. On (2001)
10.1016/S0926-860X(03)00543-X
Characterization of Ca-promoted Ni/α-Al2O3 catalyst for CH4 reforming with CO2
Zhaoyin Hou (2003)
10.1016/J.JPOWSOUR.2005.02.046
Bio-ethanol steam reforming: Insights on the mechanism for hydrogen production
M. Benito (2005)
10.1016/S0926-860X(98)00244-0
The multiple roles for catalysis in the production of H2
J. Armor (1999)
10.1002/(SICI)1521-4176(199805)49:5<367::AID-MACO367>3.0.CO;2-M
Carbon formation on nickel and nickel-copper alloy catalysts
I. Alstrup (1998)
10.1016/J.CATTOD.2004.03.067
Carbon dioxide reforming of methane reaction catalyzed by stable nickel copper catalysts
Hsiu-Wei Chen (2004)
10.1039/B208201M
On-board hydrogen production in a hybrid electric vehicle by bio-ethanol oxidative steam reforming over Ni and noble metal based catalysts
V. Fierro (2003)
10.1016/J.JCAT.2004.04.034
Reaction network of steam reforming of ethanol over Ni-based catalysts
A. Fatsikostas (2004)
10.1016/S0378-7753(01)00800-X
Hydrogen produced from ethanol for internal reforming molten carbonate fuel cell
S. Cavallaro (2001)
10.1016/J.APCATA.2007.04.030
Hydrogen production by ethanol steam reforming over Cu-Ni/SBA-15 supported catalysts prepared by direct synthesis and impregnation
A. Carrero (2007)
10.1021/EF0500538
Current status of hydrogen production techniques by steam reforming of ethanol : A review
A. Haryanto (2005)
10.1021/EF0000779
Ethanol steam reforming on Rh/Al2O3 catalysts
S. Cavallaro (2000)
10.1016/S0926-860X(02)00233-8
Characterization of ceria-coated alumina carrier
S. Damyanova (2002)
10.1016/J.CATTOD.2006.10.013
Ethanol steam reforming over Ni/La–Al2O3 catalysts: Influence of lanthanum loading
M. Sanchez-Sanchez (2007)
10.1016/J.JCAT.2005.07.014
Deactivation characteristics of lanthanide-promoted sol–gel Ni/Al2O3 catalysts in propane steam reforming
S. Natesakhawat (2005)
10.1016/J.COLSURFA.2003.12.009
Dispersion of ceria and lanthana on silica and alumina supports—X-ray diffractometry and nitrogen sorptometry studies
G. A. Mekhemer (2004)
10.1021/J100328A029
Surface characterization of alumina-supported ceria
J. Z. Shyu (1988)
10.1016/S1566-7367(02)00118-8
Bio-ethanol catalytic steam reforming over supported metal catalysts
F. Auprêtre (2002)
10.1016/S0926-3373(02)00075-9
Metal-catalysed steam reforming of ethanol in the production of hydrogen for fuel cell applications
J. P. Breen (2002)
10.1016/J.IJHYDENE.2006.01.015
The era of energy vectors
F. Orecchini (2006)
10.1016/J.IJHYDENE.2004.10.004
Study of Ni catalysts on different supports to obtain synthesis gas
F. Pompeo (2005)
10.1021/EF0498521
Combined Carbon Dioxide Reforming and Partial Oxidation of Methane to Syngas over Ni−La2O3/SiO2 Catalysts in a Fluidized-Bed Reactor
L. Mo (2005)
10.1016/J.IJHYDENE.2006.10.024
Hydrogen production by ethanol steam reforming over Cu–Ni supported catalysts
A. J. Vizcaíno (2007)
10.1016/J.CATTOD.2007.10.048
Promotion effect of cerium and lanthanum oxides on Ni/SBA-15 catalyst for ammonia decomposition
Hong-chao Liu (2008)
10.1016/J.IJHYDENE.2007.10.023
Performance of La,Ce-modified alumina-supported Pt and Ni catalysts for the oxidative reforming of diesel hydrocarbons
M. C. Álvarez-Galván (2008)
10.1016/J.MOLCATA.2005.07.017
Effect of lanthanide promotion on catalytic performance of sol–gel Ni/Al2O3 catalysts in steam reforming of propane
S. Natesakhawat (2005)
10.1016/J.CATTOD.2004.12.005
Influence of the addition of promoters to steam reforming catalysts
Juliana S. Lisboa (2005)
10.1016/J.IJHYDENE.2006.10.025
Ethanol steam reforming over Ni/MxOy–Al2O3 (M=Ce, La, Zr and Mg) catalysts: Influence of support on the hydrogen production
M. Sanchez-Sanchez (2007)



This paper is referenced by
10.1039/C5CY00410A
Rational design of ethanol steam reforming catalyst based on analysis of Ni/La2O3 metal–support interactions
Jyong-Yue Liu (2016)
10.1016/j.cattod.2020.04.069
Coke evolution in simulated bio-oil aqueous fraction steam reforming using Co/SBA-15
P. J. Megía (2020)
10.1016/J.APCATB.2015.04.020
Ceria-promoted Ni/SBA-15 catalysts for ethanol steam reforming with enhanced activity and resistance to deactivation
D. Li (2015)
10.1016/J.APCATA.2017.08.030
Hydrogen from pyroligneous acid via modified bimetal Al-SBA-15 catalysts
Xiwei Xu (2017)
10.1016/J.IJHYDENE.2011.07.144
Hydrogen production by biomass gasification in supercritical water with bimetallic Ni–M/γAl2O3 catalysts (M = Cu, Co and Sn)
Sha Li (2011)
10.4236/MRC.2013.22A003
Steam Reforming of Ethanol over CoMg/SBA-15 Catalysts
J. Y. Chiou (2013)
10.1016/J.IJHYDENE.2018.02.139
Synthesis and characterization of Zr-promoted Ni-Co bimetallic catalyst supported OMC and investigation of its catalytic performance in steam reforming of ethanol
Vahid Shahed Gharahshiran (2018)
10.1002/cctc.201800421
Modification of Cu/SiO2 Catalysts by La2O3 to Quantitatively Tune Cu+‐Cu0 Dual Sites with Improved Catalytic Activities and Stabilities for Dimethyl Ether Steam Reforming
Jingjing Huang (2018)
10.3390/catal9121013
Hydrogen Production from Steam Reforming of Acetic Acid as a Model Compound of the Aqueous Fraction of Microalgae HTL Using Co-M/SBA-15 (M: Cu, Ag, Ce, Cr) Catalysts
P. J. Megía (2019)
Hydrodeoxygenation of Anisole in a Novel Externally Agitated Reactor
Brett Pomeroy (2017)
10.1039/C6CY02334G
A novel strategy for constructing mesoporous solid superbase catalysts: bimetallic Al–La oxides supported on SBA-15 modified with KF
Liu Ning (2017)
10.1016/J.IJHYDENE.2017.01.034
Pursuing complete and stable steam reforming of n-dodecane over nickel catalysts at low temperature and high LHSV
Z. Xiao (2017)
10.1002/cctc.201300720
One‐pot Synthesis of Ordered Mesoporous NiCeAl Oxide Catalysts and a Study of Their Performance in Methane Dry Reforming
Ning Wang (2014)
10.1016/j.ces.2020.115863
An overview on the role of lanthanide series (rare earth metals) in H2 and syngas production from CH4 reforming processes
O. Osazuwa (2020)
10.1016/J.IJHYDENE.2011.01.009
Steam reforming of ethanol over Ni/ZrO2 catalysts: Effect of support on product distribution
Shuirong Li (2012)
Hydrogen Production by Steam Reforming of Bioethanol over Pt Based Catalysts
D. Ghita (2016)
10.3844/AJASSP.2010.1579.1586
A review: Mesoporous Santa Barbara amorphous-15, types, synthesis and its applications towards biorefinery production
N. Rahmat (2010)
10.1016/j.apcata.2020.117487
Mesoporous copper-ceria-titania ternary oxides as catalysts for environmental protection: Impact of Ce/Ti ratio and preparation procedure
T. Tsoncheva (2020)
10.1016/J.APCATA.2018.04.015
Advanced synthesis strategies of mesoporous SBA-15 supported catalysts for catalytic reforming applications: a state-of-the-art review
S. Singh (2018)
10.1016/J.IJHYDENE.2017.05.022
Achievement of hydrogen production from autothermal steam reforming of methanol over Cu-loaded mesoporous CeO2 and Cu-loaded mesoporous CeO2–ZrO2 catalysts
S. Jampa (2017)
10.1016/J.IJHYDENE.2016.04.110
Anti-coking of Yb-promoted Ni/Al2O3 catalyst in partial oxidation of methane
Chuanmin Ding (2016)
10.1016/B978-0-444-56352-1.00007-6
Hydrogen from Bioethanol
J. Llorca (2013)
10.1016/J.IJHYDENE.2011.04.179
Hydrogen production by steam reforming of ethanol using Ni catalysts based on ternary mixed oxides prepared by coprecipitation
A. J. Vizcaíno (2012)
10.1177/1468678319891842
A highly efficient and stable Ni/SBA-15 catalyst for hydrogen production by ethanol steam reforming
Xia An (2020)
10.1039/C8CY02093K
Probing the promotional roles of cerium in the structure and performance of Cu/SiO2 catalysts for ethanol production
Peipei Ai (2018)
10.1016/J.APCATB.2011.06.028
The ethanol steam reforming over Cu-Ni/SiO2 catalysts: Effect of Cu/Ni ratio
Li-Chung Chen (2011)
10.1088/1757-899x/736/4/042021
Syngas Production via CO2 Reforming of CH4 over Zr-Ni/SBA-15
N. Abdullah (2020)
10.1021/SC300081Q
Hydrogen Production via Steam Reforming of Ethanol on Phyllosilicate-Derived Ni/SiO2: Enhanced Metal–Support Interaction and Catalytic Stability
Chengxi Zhang (2013)
10.1016/J.IJHYDENE.2019.03.053
Effect of La2O3 and CeO2 loadings on formation of nickel-phyllosilicate precursor during preparation of Ni/SBA-15 for hydrogen-rich gas production from ethanol steam reforming
Surendar Moogi (2019)
10.1016/J.ENCONMAN.2019.01.066
Hydrogen generation by steam reforming of tar model compounds using lanthanum modified Ni/sepiolite catalysts
Mingqiang Chen (2019)
10.32014/2020.2518-1491.34
SYNTHESIS AND STUDY OF STRUCTURAL PROPERTIES OF COMPOSITES BASED ON NI-RU FOR STEAM CONVERSION OF ETHANOL
Symbat Naurzkulova (2020)
10.1016/J.APCATB.2013.11.037
Ni/ZrO2 catalysts in ethanol steam reforming: Inhibition of coke formation by CaO-doping
Valentina Nichele (2014)
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