Online citations, reference lists, and bibliographies.
Please confirm you are human
(Sign Up for free to never see this)
← Back to Search

Synthesis, Characterization, And Spectroscopic Studies Of Tetradentate Schiff Base Chromium(III) Complexes

P. Aranha, M. P. D. Santos, Sandra Romera, E. Dockal
Published 2007 · Chemistry

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Eight chromium(III) complexes of tetradentate Schiff bases have been prepared in situ by condensing of a substituted salicylaldehyde compound with ethylenediamine. These were characterized by elemental analysis, m.p., IR, molar conductivity, magnetic moment measurements, and electronic spectra. The free ligands were also characterized by 1 H and 13 C NMR spectra. The 13 C NMR spectra are discussed in terms of possible substituent effects. The IR and electronic spectra of the free ligand and the complexes are compared and discussed. The electrospray ionization (ESI) mass spectra of four free ligands and their complexes were measured. The deconvolution of the visible spectra of the complexes, C2v symmetry, in DMSO yields three peaks at ca. 15 600–17 600, 18 400–20 400 and 20 000– 23 100, and are assigned to the three d–d transitions, 4 B1g ! 4 Eg( 4 T2g); 4 B1g ! 4 B2g( 4 T2g); 4 B1g ! 4 Eg( 4 T1g), respectively. The complexes
This paper references
10.1016/0277-5387(95)00243-L
Synthesis and characterization of aquo[N,N′-ethylenebis(3-ethoxysalicylideneaminato)]dioxouranium(VI)
O. Signorini (1996)
10.1007/BF00139036
Tetradentate Schiff base oxovanadium(IV) complexes
J. R. Zamian (1996)
10.1016/S0277-5387(97)00399-9
Synthesis and characterization of nickel(II), copper(II), manganese(III) and iron(III) complexes with new chiral salen-type ligand |N,N′-bis(3,5-di-tert-butylsalicylidene)-(1R,3S)-1,3-diamine-1,2,2-trimethylcyclopentane|
A. Vogt (1998)
10.1016/S0968-0896(99)00260-6
Synthesis, spectroscopic characterization and biological properties of new natural aldehydes thiosemicarbazones.
P. Tarasconi (2000)
Cancer Res
K. A. Biedermann (1990)
10.1021/JA00311A064
Mechanism of the chromium-catalyzed epoxidation of olefins. Role of oxochromium(V) cations
E. G. Samsel (1985)
10.1016/J.JCAT.2005.12.023
Enantioselective epoxidation of unfunctionalized olefins catalyzed by the Mn(salen) catalysts immobilized in the nanopores of mesoporous materials
Huidong Zhang (2006)
10.1016/0022-1902(81)80367-3
Studies on some antifungal transition metal chelates of N-(5-phenyl-1, 3, 4-thiadiazol-2-yl) dithiocarbamic acid
H. Singh (1981)
10.1016/S0040-4020(00)01047-4
Enantioselective catalytic addition of allyl organometallic reagents to aldehydes promoted by [Cr(Salen)]: the hidden role played by weak Lewis acids in metallo-Salen promoted reactions
M. Bandini (2001)
Gazz
M. Gullotti (1972)
10.1063/1.3035225
Inorganic Electronic Spectroscopy
A. B. Lever (1968)
10.1016/0040-4020(68)88164-5
NMR spectra of intramolecularly hydrogen-bonded compounds—II : Schiff bases of β-diketones and o-hydroxycarbonyl compounds
N. Brown (1968)
Inorganic Chemistry: Principles of Structure and Reactivity
J. E. Huheey (1972)
10.1021/JA00169A051
Electrospray ionization: a new tool for the analysis of ionic transition-metal complexes
V. Katta (1990)
10.1016/0924-2031(92)87024-A
Spectrometric Identification of Organic Compounds
Gary W Small (1992)
10.1021/JA01005A012
An interpretation of the circular dichroism and electronic spectra of salicylaldimine complexes of square-coplanar diamagnetic nickel(II)
B. Bosnich (1968)
Rapid Commun
M. K. Kumar (2004)
10.1021/JA0164677
Chemical CO2 Fixation: Cr(III) Salen Complexes as Highly Efficient Catalysts for the Coupling of CO2 and Epoxides
R. L. Paddock (2001)
10.1016/S0304-4165(00)00063-5
Interaction of DNA with [Cr(Schiff base)(H(2)O)(2)]ClO(4).
R. Vijayalakshmi (2000)
Chem
E. G. Samsel (1985)
Biochem
K. Govindaraju (1989)
10.1016/J.JINORGBIO.2005.08.007
DNA damage induced by a chromium(III) Schiff base complex is reversible under physiological condition.
V. G. Vaidyanathan (2005)
Role of valence state and solubility of chromium compounds on induction of cytotoxicity, mutagenesis, and anchorage independence in diploid human fibroblasts.
K. A. Biedermann (1990)
10.1016/0022-1902(80)80143-6
Monomeric and dimeric products of protonation of dioxotetracyanometalates(IV)—III The oxoaquotetracyanocomplexes of molybdenum and tungsten
M. Dudek (1980)
Spectrochim
S. M. Grawford (1963)
10.1080/00958978808081660
SYNTHESIS AND CHARACTERIZATION OF SCHIFF BASE COMPLEXES WITH ZINC HALIDES
F. Bottino (1988)
Chem
R. L. Paddock (2001)
Transition Met
D. X. West (1994)
Chem
M. Kanthimathi (2000)
Synth
X. D. Zhu (2000)
10.1006/rtph.1997.1136
Chromium as an essential nutrient for humans.
R. Anderson (1997)
Tetrahedron Lett
M. Malinowska (2004)
Polyhedron 15 (1995) 245
O. Signorini (2006)
Chem
V. Katta (2006)
10.1016/0162-0134(89)80006-6
Chromium(III)-insulin derivatives and their implication in glucose metabolism.
K. Govindaraju (1989)
10.1016/0584-8539(76)80263-2
Infrared and electronic spectra of N-salicylideneglycinate complexes of cobalt and nickel
G. C. Percy (1976)
Spectrochim
P. Gluvchinsky (1976)
Acta Pharm
V. Mishra (2000)
10.1007/3-540-26367-5_1
A
A. Spring (2005)
Soc
D. Jamal (2000)
10.1023/A:1007027011216
Nuclease activity of 2-substituted heteroaromatic thiosemicarbazone and semicarbazone copper(II) complexes
K. Hussain Reddy (2000)
Chem
W. Adam (2000)
Chem
F. A. Bottino (1988)
Catal
N. J. Kerrigan (2005)
Nucl
H. Singh (1981)
Chem
S. E. Schaus (1998)
Sci
N. N. Gulerman (2001)
10.1016/S0009-2614(00)00527-3
Langmuir–Blodgett film properties of a donor–acceptor Schiff base
M. Kanthimathi (2000)
10.1002/ZAAC.19754120309
Lanthanide Compounds with SCHIFF Bases and with Copper(II) SCHIFF Base Complexes as Ligands
G. Condorelli (1975)
10.1246/BCSJ.42.1463
Chromium(III) Complexes Containing Bis(salicylaldehyde)ethylenediiminate as a Ligand
S. Yamada (1969)
10.1515/9783111576855-015
J
Seguin Hen (1824)
Catal
J. Wen (2006)
Chem
B. Bosnich (1968)
10.1021/JO971758C
Asymmetric Hetero-Diels−Alder Reactions Catalyzed by Chiral (Salen)Chromium(III) Complexes
S. Schaus (1998)
Transition Met
K. H. Reddy (2000)
10.1021/JO9913457
Chemoselective C-H oxidation of alcohols to carbonyl compounds with iodosobenzene catalyzed by (salen)chromium complex
Adam (2000)
10.1016/J.APCATA.2005.11.031
Selective alkene epoxidation and alkane hydroxylation with sodium periodate catalyzed by cationic Mn(III)-salen supported on Dowex MSC1
B. Bahramian (2006)
Chem
K. Ueno (1956)
10.1016/J.MOLCATA.2005.04.002
Asymmetric epoxidation catalyzed by Cr(III)-binaphthyl Schiff base complexes
Zhengkai Li (2005)
10.1002/1521-3773(20000703)39:13<2327::AID-ANIE2327>3.0.CO;2-9
Salen as a Chiral Activator:anti versussyn Switchable Diastereoselection in the Enantioselective Addition of Crotyl Bromide to Aromatic Aldehydes
M. Bandini (2000)
Inorg
L. Dubicki (1970)
Nucl
E. Konig (1970)
10.1016/J.MOLCATA.2005.09.039
Asymmetric pinacol coupling reaction catalyzed by dipeptide-type Schiff bases
Jiwu Wen (2006)
10.1016/J.TETASY.2004.03.010
Ligand tuning in the chromium–salen-mediated asymmetric epoxidation of alkenes
E. M. McGarrigle (2004)
10.1016/S0277-5387(00)00620-3
Preparation, characterization and thermogravimetric studies of [N,N′-cis-1,2-cyclohexylene bis(salicylideneaminato)]cobalt(II) and [N,N′-(±)-trans-1,2-cyclo-hexylene bis(salicylideneaminato)]cobalt(II)
R. C. Felício (2001)
10.1016/0022-1902(74)80621-4
Infrared spectra of N,N′-bis(salicylidene)-1,1-(dimethyl)ethylenediamine and its metal complexes
J. Faniran (1974)
10.1016/J.TETLET.2004.08.081
The enantioselective high-pressure Diels–Alder reaction of 1-methoxybuta-1,3-diene with tert-butyldimethylsilyloxyacetaldehyde catalyzed by (salen)Co(II) and (salen)Cr(III)Cl complexes
M. Malinowska (2004)
10.1080/00945710009351787
The Schiff Base N-salicylidene-O,S-dimethylthiophosphorylimine and its Metal Complexes: Synthesis, Characterization and Insecticidal Activity Studies
Xinde Zhu (2000)
10.1023/A:1007159301849
Antitumour activity of transition metal complexes with the thiosemicarbazone derived from 3-acetylumbelliferone
M. Wang (2001)
10.1515/9783486731620-002
I
John B. Shoven (1824)
Regul
R. A. Anderson (1997)
10.1002/RCM.1456
Coordination chemistry of chromium-Salen complexes studied by electrospray ionization mass spectrometry.
M. K. Kumar (2004)
10.1093/JN/123.4.626
Chromium in human nutrition: a review.
W. Mertz (1993)
10.1021/IC50083A038
Single-crystal polarized electronic spectrum of trans-difluorobis(ethylenediamine)chromium(III) perchlorate
L. Dubicki (1970)
Nucl
G. C. Percy (1973)
Indian J
N. K. Singh (2001)
Biochem
V. G. Vaidyanathan (2005)
10.1016/S0162-0134(00)00043-X
Biocatalytic and biomimetic oxidations with vanadium.
F. van de Velde (2000)
10.1016/0584-8539(77)80156-6
Nickel(II) complexes of some quadridentate Schiff-base ligands—II. Infrared spectra
Paul Gluvchinsky (1977)
Biochim
R. Vijayalakshmi (2000)
10.1198/000313001750358509
APPL
A. Glen (2001)
Chem
H. H. Freedman (1961)
Indian J
S. D. Dhumwad (1994)
10.1016/0162-0134(89)80005-4
Chymotrypsin-catalyzed hydrolysis of chromium (III) derivatives of insulin: evidence for stabilization of the protein through interactions with metal ions.
K. Govindaraju (1989)
10.1021/J150543A029
Infrared Studies on Synthetic Oxygen Carriers.
K. Ueno (1956)
Angew
M. Bandini (2000)
Biochem
E. J. Baran (2000)
Biochem
R. Rajaram (1995)
Transition Met
J. R. Zamian (1996)
Catal
Z. K. Li (2005)
10.1039/DT9750001538
Carbon-13 nuclear magnetic resonance spectra of -oxo-bis(disalicylideneiminatoiron) complexes
K. Murray (1975)
Bull
S. Yamada (1969)
10.1016/0371-1951(63)80104-6
The ultra-violet and visible spectra of some transition metal chelates with N,N'-bis-(o-hydroxybenzylidene)ethylenediamine and N,N'-bis-(o-hydroxybenzylidene)-o-phenylenediamine and related compounds
S. M. Crawford (1963)
10.1039/DT9810001241
The stereochemistry of oxovanadium(IV) complexes derived from salicylaldehyde and polymethylenediamines
Gabriel A. Kolawole (1981)
10.1016/0022-1902(70)80269-X
Electronic spectra of tris(2,2′-bipyridyl) complexes—I
E. König (1970)
10.1016/S0162-0134(00)00032-5
Oxovanadium(IV) and oxovanadium(V) complexes relevant to biological systems.
E. Barán (2000)
Spectrochim
P. Gluvchinsky (1977)
10.1016/J.MOLCATA.2004.10.027
Salen ligands derived from trans-1,2-dimethyl-1,2-cyclohexanediamine: preparation and application in oxo-chromium salen mediated asymmetric epoxidation of alkenes
N. J. Kerrigan (2005)
10.1016/0277-5387(95)91804-U
Synthesis properties and structure of vanadium(IV) schiff base complex (VO)[Salphen] · CH3CN
X. Wang (1995)
10.1006/BBRC.1995.1679
Chromium(III) induced abnormalities in human lymphocyte cell proliferation: evidence for apoptosis.
R. Rajaram (1995)
Acta Chim
B. N. Ghose (1987)
10.1128/JVI.78.20.11321-11326.2004
Protective Efficacy of a DNA Influenza Virus Vaccine Is Markedly Increased by the Coadministration of a Schiff Base-Forming Drug
J. Charo (2004)
10.1021/JA01474A026
Intramolecular H-Bonds. I. A Spectroscopic Study of the Hydrogen Bond between Hydroxyl and Nitrogen
H. Freedman (1961)
Transition Met
M. Wang (2001)
Biochem
F. Velde (2000)



This paper is referenced by
10.22146/ijc.44192
Preparation, Characterization and Study of the Photodecolorization of Mixed-Ligand Binuclear Co(II) Complex of Schiff Base by ZnO
Suhad Kareem Abass (2020)
10.1002/ZAAC.201700112
Synthesis, Kinetics, and Equilibrium Study of Highly Sensitive Colorimetric Chemosensor for Monitoring of Copper Ions based on Benzo[f]fluorescein Dye Derivatives
T. Elmorsi (2017)
10.1016/j.jinorgbio.2019.03.017
Silver(I) complexes with 4,7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection.
A. Pavic (2019)
Sintesis Co/Cu(II)-Salen yang Tertambatkan pada Silika Sebagai Katalis Padat Untuk Oksidasi Gliserol
Andriawan Subekti (2009)
10.1134/S1070328418030053
Supramolecular Heteroleptic Copper(II) Carboxylates: Synthesis, Spectral Characterization, Crystal Structures, and Enzyme Inhibition Assay
A. Mushtaq (2018)
10.1080/24701556.2019.1569681
Synthesis and characterization of transition metal complexes with a Schiff base derived from cephalexin and 1,2–diaminobenzene. antibacterial activity
J. Anacona (2018)
10.1016/j.saa.2015.04.054
Tetradentate metal complexes derived from cephalexin and 2,6-diacetylpyridine bis(hydrazone): Synthesis, characterization and antibacterial activity.
J. Anacona (2015)
10.1039/C7QO00821J
One-flask synthesis of dibenzotetraaza[14]annulene cyclic congeners bearing buta-1,3-diyne bridges
K. Zwoliński (2018)
10.1002/AOC.4562
Transition metal complexes containing a tridentate cefadroxil‐based Schiff base: An effective paramagnetic semiquinone Ag (I) complex against Staphylococcus aureus and Pseudomonas aeruginosa
J. Anacona (2018)
10.1002/rcm.8757
Bioinspired oxidation in the CYP of isomers orientin and isoorientin using Salen complexes.
M. B. Chagas (2020)
Chromium Schiff base complex as a electrocatalytic probe for the determination of hydroquinone
S. Praveen Kumar (2014)
10.1016/j.jinorgbio.2019.110872
New polynuclear 1,5-naphthyridine-silver(I) complexes as potential antimicrobial agents: The key role of the nature of donor coordinated to the metal center.
Sonja Ž. Đurić (2019)
10.1371/journal.pone.0158549
Novel preparation of highly photocatalytically active copper chromite nanostructured material via a simple hydrothermal route
Farshad Beshkar (2017)
10.1002/EJIC.201301384
One-Dimensional Structure of an Aluminum Coordination Compound
Z. Yang (2014)
10.1016/J.ARABJC.2012.10.007
Spectroscopic, electrochemical and biological studies of the metal complexes of the Schiff base derived from pyrrole-2-carbaldehyde and ethylenediamine
B. K. Singh (2017)
10.1071/CH11291
Synthesis, Structural, and Insulin-Enhancing Studies of Oxovanadium(IV) Complexes
Adeola A. Nejo (2011)
10.1080/00958972.2016.1274028
Chromium(III), manganese(II) and iron(III) complexes based on hydrazone Schiff-base and azide ligands: synthesis, crystal structure and antimicrobial activity
B. Shaabani (2017)
Seasonal temporal distribution of forecasted wind speed data in Langkawi, Malaysia
Siti Noratiqah Mohamad Deros (2017)
10.4172/2161-0444.1000385
Synthesis, Characterization and Antibacterial Activity of a Tridentate SchiffBase Derived from Cephalexin and 1,6-Hexanediamine and its TransitionMetal Complexes
J. Anacona (2016)
10.1016/j.saa.2017.04.019
A novel, highly sensitive, selective, reversible and turn-on chemi-sensor based on Schiff base for rapid detection of Cu(II).
S. Saleh (2017)
10.1016/J.ICA.2014.04.028
Synthesis, crystal structures, electrochemically studies and antibacterial properties of three new mono-nuclear and one very rare bi-nuclear cobalt(III) Schiff base complexes
Raziyeh Taherlo (2014)
10.1016/J.MOLSTRUC.2012.04.017
Synthesis, spectral characterization, DNA binding ability and antibacterial screening of copper(II) complexes of symmetrical NOON tetradentate Schiff bases bearing different bridges
Saleh O. Bahaffi (2012)
10.1524/ract.2011.1825
Photoluminescent nano-sized ternary and quaternary complexes of thorium(IV)
B. Baranwal (2011)
10.1016/j.saa.2012.06.023
Synthesis, spectroscopic, photoluminescence properties and biological evaluation of novel Zn(II) and Al(III) complexes of NOON tetradentate Schiff bases.
Ayman A. Abdel Aziz (2012)
10.1016/J.POLY.2007.08.030
Synthesis, characterization, crystal structure and catalytic property of [Cu(SalAHE)2] (SalAHE = salicylaldehydeimine-1-hydroxyethane) complex for the oxidation of 3,5-di-tert-butylcatechol
Ana C.D. Midões (2008)
10.11113/JT.V80.11109
SYNTHESIS, SPECTROSCOPIC INVESTIGATION AND CATALYTIC STUDIES OF NICKEL(II) AROMATIC AZOMETHINE COMPLEXES
S. Ahmad (2018)
10.1016/j.saa.2014.12.012
Synthesis and characterization of chromium(III) Schiff base complexes: antimicrobial activity and its electrocatalytic sensing ability of catechol.
S. P. Kumar (2015)
Substituent effect on catalytic activity of palladium(II) schiff base complexes for sonogashira reaction
H. Bahron (2017)
10.1016/j.mtchem.2019.100195
Metal complexes driven from Schiff bases and semicarbazones for biomedical and allied applications: a review
M. S. More (2019)
10.1007/s10534-020-00268-8
Novel complexes with ONNO tetradentate coumarin schiff-base donor ligands: x-ray structures, DFT calculations, molecular dynamics and potential anticarcinogenic activity.
Paula Daniela Mestizo (2020)
Oxidative coupling of ortho-aminophenol over mesoporous silica containing copper(ii) diethylamino-substituted salen complex
T. K. Chin (2010)
10.1080/00032710701487122
Electrochemical Modified Electrodes Based on Metal‐Salen Complexes
O. Fatibello-Filho (2007)
See more
Semantic Scholar Logo Some data provided by SemanticScholar