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Mussel-inspired 3D Networks With Stiff-irreversible Or Soft-reversible Characteristics - It's All A Matter Of Solvent
Mohammad Vatankhah-Varnoosfaderani, S. Hashmi, F. J. Stadler, Amin Ghavaminejad
Published 2017 · Chemistry
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Abstract Mostly, catechol groups are used as cross-linkers either based on oxidation to make irreversible networks in presence of oxidizing agent or coordination with metal ions to form reversible networks. However, a systematic study of gelation of catecholic polymer by adding oxidizing agent in non-aqueous solvents are scarce. Here, we report a study of gelation of catecholic polymer by adding oxidizing agent in different media to show the effect of media on behavior of catechol groups. When the gelation performed in an aprotic solvent, the copolymer containing catechol units gelates supramolecularly by H-bonding, yielding reversible and self-healing behavior, while in aqueous solvents irreversibly crosslinked not self-healing gels are obtained. As polymer-bound catechol groups are often studied in water, knowledge of the behavior of catecholic polymer in organic solvents is important to create supramolecular structures with more precisely controlled properties.
This paper references
Competition between Oxidation and Coordination in Cross-Linking of Polystyrene Copolymer Containing Catechol Groups
H. Xu (2012)
Surface-initiated self-healing of polymers in aqueous media.
B. Ahn (2014)
Mussel-inspired pH-triggered reversible foamed multi-responsive gel--the surprising effect of water.
Mohammad Vatankhah-Varnoosfaderani (2013)
A new route to prepare multiresponsive organogels from a block ionomer via charge-driven assembly.
Tao Zhang (2013)
Self-healing mussel-inspired multi-pH-responsive hydrogels.
M. Krogsgaard (2013)
Amino acid-based multiresponsive low-molecular weight metallohydrogels with load-bearing and rapid self-healing abilities.
Subhadeep Saha (2014)
Rapid self-healing hydrogels
A. Phadke (2012)
Vanadyl−Catecholamine Hydrogels Inspired by Ascidians and Mussels
J. Park (2015)
Self-healing gels based on constitutional dynamic chemistry and their potential applications.
Z. Wei (2014)
pH-induced metal-ligand cross-links inspired by mussel yield self-healing polymer networks with near-covalent elastic moduli
Niels Holten-Andersen (2011)
Hydrogen bonding in aprotic solvents, a new strategy for gelation of bioinspired catecholic copolymers with N-isopropylamide.
Mohammad Vatankhah-Varnoosfaderani (2015)
Dimethyl sulfoxide (DMSO) and glycerol, hydroxyl radical scavengers, impair platelet aggregation within and eliminate the accompanying vasodilation of, injured mouse pial arterioles.
W. Rosenblum (1982)
Universal polymer coatings and their representative biomedical applications
Qiang Wei (2015)
Large amplitude oscillatory shear behavior of complex fluids investigated by a network model: a guideline for classification
H. Sim (2003)
Reply to Stadler: Combining network disassembly spectrometry with rheology/spectroscopy
B. Olsen (2013)
On the Theory of Dispersion of X-Rays
R. D. L. Kronig (1926)
A mussel-inspired adhesive with stronger bonding strength under underwater conditions than under dry conditions.
Ailei Li (2015)
Nonlinear Rheology of Telechelic Associative Polymer Networks: Shear Thickening and Thinning Behavior of Hydrophobically Modified Ethoxylated Urethane (HEUR) in Aqueous Solution
Shinya Suzuki (2012)
Catalyst-mediated yet catalyst-free hydrogels formed by interfacial chemical activation.
Eunkyoung Byun (2014)
Stimuli-responsive supramolecular hydrogels with high extensibility and fast self-healing via precoordinated mussel-inspired chemistry.
Sen Hou (2015)
Quantifying primary loops in polymer gels by linear viscoelasticity
F. J. Stadler (2013)
Synthesis and gelation of DOPA-modified poly(ethylene glycol) hydrogels.
B. P. Lee (2002)
Rapid self-healing and triple stimuli responsiveness of a supramolecular polymer gel based on boron–catechol interactions in a novel water-soluble mussel-inspired copolymer
Mohammad Vatankhah-Varnoosfaderani (2014)
Versatile tuning of supramolecular hydrogels through metal complexation of oxidation-resistant catechol-inspired ligands.
M. Menyo (2013)
ECM-incorporated hydrogels cross-linked via native chemical ligation to engineer stem cell microenvironments.
J. P. Jung (2013)
Oxidant-induced dopamine polymerization for multifunctional coatings
Q. Wei (2010)
Bioinspired pH and magnetic responsive catechol-functionalized chitosan hydrogels with tunable elastic properties.
A. Ghadban (2016)
Autonomic self-healing of hydrogel thin films.
A. B. South (2010)
In Situ Synthesis of Antimicrobial Silver Nanoparticles within Antifouling Zwitterionic Hydrogels by Catecholic Redox Chemistry for Wound Healing Application.
Amin Ghavaminejad (2016)
Effect of H2O and reduced graphene oxide on the structure and rheology of self-healing, stimuli responsive catecholic gels
Amin Ghavaminejad (2016)
Mussel-inspired dendritic polymers as universal multifunctional coatings.
Q. Wei (2014)
Numerical description of shear viscosity functions of long-chain branched metallocene-catalyzed polyethylenes
F. J. Stadler (2008)
The reaction of OH radicals with dimethyl sulfoxide. A comparative study of Fenton's reagent and the radiolysis of aqueous dimethyl sulfoxide solutions
M. Eberhardt (1988)
Self-healing polymers with PEG oligomer side chains based on multiple H-bonding and adhesion properties
Dandan Zhu (2015)
A Stiff Injectable Biodegradable Elastomer.
B. Mizrahi (2013)
Connecting micelles by metallo-supramolecular interactions: towards stimuli responsive hierarchical materials
Pierre Guillet (2009)
Bioinspired, calcium-free alginate hydrogels with tunable physical and mechanical properties and improved biocompatibility.
Changhyun Lee (2013)
Catechols as versatile platforms in polymer chemistry
E. Faure (2013)
Gelation and adhesion behavior of mussel adhesive protein mimetic polymer
Jin Nishida (2013)
Role of l-3,4-Dihydroxyphenylalanine in Mussel Adhesive Proteins
Miaoer Yu (1999)
Hydrogen bonding in dimethylsulphoxide‐proton donor interactions: A Raman and infrared study of the DMSO‐HCI system
A. Bertoluzza (1981)
Hyaluronic Acid Catechol: A Biopolymer Exhibiting a pH‐Dependent Adhesive or Cohesive Property for Human Neural Stem Cell Engineering
Seonki Hong (2013)
A comparison of the hydroxyl radical scavenging properties of the shark bile steroid 5β‐scymnol and plant pycnogenols
T. Macrides (1997)
Self-healing polymers: Sticky when wet.
J. Wilker (2014)
Control of hierarchical polymer mechanics with bioinspired metal-coordination dynamics
Scott C. Grindy (2015)
Chemistry of crosslinking processes for self-healing polymers.
Stijn Billiet (2013)
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