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Catalytic Transesterification Of Pistacia Chinensis Seed Oil Using HPW Immobilized On Magnetic Composite Graphene Oxide/cellulose Microspheres

Tian-Feng Li, Xi-Qing Wang, Jiao Jiao, Ju-Zhao Liu, H. Zhang, Li-li Niu, Chunjian Zhao, C B Gu, Thomas Efferth, Yu-Jie Fu
Published 2018 · Engineering
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Abstract In the present study, magnetic composite graphene oxide/cellulose (GO/CM@Fe3O4) microspheres were prepared as support material, which are cost-efficient, non-toxic and environmental friendly. The microspheres with higher adsorption capacity were further modified using triethylene tetramine (TETA), and H3PW12O40 (HPW) was immobilized to form GO/CM-NH2@Fe3O4-HPW microspheres as heterogeneous catalyst for biodiesel production. The novel heterogeneous catalyst was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmett-Teller (BET) and X-ray diffractometry (XRD). For the first time, GO/CM-NH2@Fe3O4--HPW was applied in the transesterification of highly-acidic Pistacia chinensis seed oil to biodiesel. Under optimal reaction conditions 80 °C, methanol/oil molar ratio 12:1, catalyst 15 wt% (w/w of oil) for 8 h, a 94% biodiesel yield was achieved. The heterogeneous catalyst could be easily separated from the reaction system by using magnetic field and efficiently recycled for at least six times. This novel procedure overcomes the disadvantages of the current catalyst support such as active site leaching, complicated preparation process and high costs. Therefore, it was a potential novel heterogeneous catalyst for biodiesel production.
This paper references
10.1016/J.CAP.2016.12.001
Bacterial cellulose/graphene oxide nanocomposite as a novel drug delivery system
Honglin Luo (2017)
10.1016/J.CARBON.2013.06.049
Scalable preparation of three-dimensional porous structures of reduced graphene oxide/cellulose composites and their application in supercapacitors
Wenzhu Ouyang (2013)
10.1016/J.SYNTHMET.2016.12.010
Porous cellulose/graphene oxide nanocomposite as flexible and renewable electrode material for supercapacitor
Abdullahil Kafy (2017)
10.1016/J.APENERGY.2015.06.044
Biodiesel production direct from high acid value oil with a novel magnetic carbonaceous acid
Fan Zhang (2015)
10.1016/J.JCLEPRO.2014.02.057
12-Tungstophosphoric acid supported on mesoporous molecular material: synthesis, characterization and performance in biodiesel production
Sukriti Singh (2014)
10.1016/j.jcat.2007.02.016
Structure–activity relations in Cs-doped heteropolyacid catalysts for biodiesel production
Katabathini Narasimharao (2007)
10.1080/09276440.2016.1227655
Efficient dispersion of carbon nanotube by synergistic effects of sisal cellulose nano-fiber and graphene oxide
Zihao Xu (2017)
10.1016/J.MICROMESO.2008.02.017
Influence of microporosity of activated carbons as a support of polyoxometalates
Juan Alcañiz-Monge (2008)
10.1016/J.INDCROP.2016.05.015
Biodiesel production from Pistacia chinensis seed oil via transesterification using recyclable magnetic cellulose-based catalyst
Yingzhi Han (2016)
10.1016/J.APENERGY.2013.10.025
Biodiesel production from Camptotheca acuminata seed oil catalyzed by novel Brönsted–Lewis acidic ionic liquid
Ji Li (2014)
10.1016/J.APENERGY.2013.11.044
Biodiesel production via esterification of oleic acid catalyzed by chlorosulfonic acid modified zirconia
Yue Zhang (2014)
10.1016/j.biortech.2013.06.018
Biodiesel from Forsythia suspense [(Thunb.) Vahl (Oleaceae)] seed oil.
Jiao Jiao (2013)
10.1021/ja072367a
Poly(vinylpyrrolidone)-modified graphite carbon nanofibers as promising supports for PtRu catalysts in direct methanol fuel cells.
Yu Lin Hsin (2007)
10.1016/J.JPOWSOUR.2013.12.081
Low surface area graphene/cellulose composite as a host matrix for lithium sulphur batteries
Manu U. M. Patel (2014)
10.1016/J.APCATA.2009.10.027
Esterification of oleic acid with ethanol by 12-tungstophosphoric acid supported on zirconia
Claudinei F. Oliveira (2010)
10.1016/j.biortech.2013.12.002
A green recyclable SO(3)H-carbon catalyst derived from glycerol for the production of biodiesel from FFA-containing karanja (Pongamia glabra) oil in a single step.
B. L. A. Prabhavathi Devi (2014)
10.1039/C3GC42333F
Advancements in solid acid catalysts for biodiesel production
Fang Su (2014)
10.1016/J.FUEL.2010.11.009
Transesterification of Pistacia chinensis oil for biodiesel catalyzed by CaO–CeO2 mixed oxides
Xinhai Yu (2011)
10.1260/0144-5987.28.1.37
Production and Analysis of Biodiesel from Non-Edible Seed Oil of Pistacia Chinensis
Shenjun Qin (2010)
10.1038/AM.2014.111
Hybridizing wood cellulose and graphene oxide toward high-performance fibers
Yuanyuan Li (2015)
10.1039/c4cp05921b
Designing flexible energy and memory storage materials using cellulose modified graphene oxide nanocomposites.
Abdullahil Kafy (2015)
10.1016/J.FUEL.2011.06.048
Enzymatic production of biodiesel from Pistacia chinensis bge seed oil using immobilized lipase
Xun Li (2012)
10.1016/j.carbpol.2016.10.001
Monitoring molecular dynamics of bacterial cellulose composites reinforced with graphene oxide by carboxymethyl cellulose addition.
Maria J Sanchis (2017)
10.1016/J.JCLEPRO.2017.09.097
Oxidative desulfurization of fuel oil catalyzed by magnetically recoverable nano-Fe3O4/SiO2 supported heteropoly compounds
Rijia Liu (2017)
10.1016/J.JIEC.2013.01.005
Study on the solid acid catalysts in biodiesel production from high acid value oil
Rizwan A. Sheikh (2013)
10.1002/cssc.201301149
Sulfonated graphene oxide as effective catalyst for conversion of 5-(hydroxymethyl)-2-furfural into biofuels.
Margarida M Antunes (2014)
10.1016/J.MATLET.2013.04.034
A novel method to prepare conductive nanocrystalline cellulose/graphene oxide composite films
Luca Valentini (2013)
10.1016/J.APCATA.2008.07.027
Heteropoly acids as catalysts for liquid-phase esterification and transesterification
Ali Alsalme (2008)
10.1016/j.biortech.2009.08.069
Rapid microwave-assisted transesterification of yellow horn oil to biodiesel using a heteropolyacid solid catalyst.
Su Zhang (2010)
10.1016/j.biortech.2012.12.011
Production of bioadditives from glycerol esterification over zirconia supported heteropolyacids.
Shanhui Zhu (2013)
10.1016/J.CARBON.2008.07.016
Sulfonated ordered mesoporous carbon for catalytic preparation of biodiesel
Rui Liu (2008)
10.1021/cr960400y
Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions.
I. Kozhevnikov (1998)
10.1016/j.biortech.2015.02.046
CaFeAl mixed oxide derived heterogeneous catalysts for transesterification of soybean oil to biodiesel.
Yongsheng Lu (2015)
10.1007/s10570-012-9855-5
Eco-friendly synthesis, characterization and properties of a sodium carboxymethyl cellulose/graphene oxide nanocomposite film
Mithilesh Yadav (2013)
10.1016/J.CARBPOL.2011.05.041
Graphene oxide/cellulose composite using NMMO monohydrate
Chan-Jun Kim (2011)
10.1016/J.CARBPOL.2011.08.039
A mechanically strong, flexible and conductive film based on bacterial cellulose/graphene nanocomposite
Yiyu Feng (2012)
10.1039/C6TA04844G
Flexible, highly conductive, and free-standing reduced graphene oxide/polypyrrole/cellulose hybrid papers for supercapacitor electrodes
Caichao Wan (2017)
10.1039/C5CY00339C
Graphene-based catalysis for biomass conversion
Shanhui Zhu (2015)
10.1016/J.JCLEPRO.2013.06.015
Biodiesel production from waste cooking oil using bifunctional heterogeneous solid catalysts
Muhammad Aboubakar Farooq (2013)
10.1039/C1JM12134K
Graphene/cellulose nanocomposite paper with high electrical and mechanical performances
Nguyen Dang Luong (2011)
10.1016/J.INDCROP.2016.08.009
A strategic laccase mediated lignin degradation of lignocellulosic feedstocks for ethanol production.
Althuri Avanthi (2016)
10.1016/J.FUEL.2015.12.020
Preparation of a novel cellulose-based immobilized heteropoly acid system and its application on the biodiesel production
Dong-yang Zhang (2016)
10.1016/J.FUEL.2007.04.013
Transesterification of soybean oil to biodiesel using CaO as a solid base catalyst
X. Liu (2008)
10.1016/j.elecom.2009.02.009
Preparation and electrochemical performance for methanol oxidation of pt/graphene nanocomposites
Yueming Li (2009)
10.1016/j.fuel.2006.04.017
Kinetics of hydrolysis and methyl esterification for biodiesel production in two-step supercritical methanol process
Eiji Minami (2006)
10.1016/j.apcata.2009.05.025
Esterification of free fatty acids for biodiesel production over heteropoly tungstate supported on niobia catalysts
Kt Srilatha (2009)
10.1016/j.biortech.2011.12.129
Biodiesel production from yellow horn (Xanthoceras sorbifolia Bunge.) seed oil using ion exchange resin as heterogeneous catalyst.
Ji Li (2012)
10.1016/J.CARBPOL.2011.06.061
Biosynthesis of spherical Fe3O4/bacterial cellulose nanocomposites as adsorbents for heavy metal ions
Huixia Zhu (2011)
10.1039/C3GC41379A
Phosphotungstic acid-functionalized magnetic nanoparticles as an efficient and recyclable catalyst for the one-pot production of biodiesel from grease via esterification and transesterification
Zillillah (2014)
10.1016/J.CEJ.2013.12.051
Amino-functionalized magnetic cellulose nanocomposite as adsorbent for removal of Cr(VI): Synthesis and adsorption studies
Xitong Sun (2014)
10.1039/B605713F
Solid acid catalyzed biodiesel production by simultaneous esterification and transesterification
M. G. Kulkarni (2006)
10.1016/J.CARBPOL.2010.09.006
Cellulose/graphite oxide composite films with improved mechanical properties over a wide range of temperature
Donglin Han (2011)
10.1039/B922966N
Synthesis of a novel multi –SO3H functionalized ionic liquid and its catalytic activities for biodiesel synthesis
X. Liang (2010)
10.1007/s11356-017-8765-3
Current advancements of magnetic nanoparticles in adsorption and degradation of organic pollutants
M. Ul-Islam (2017)



This paper is referenced by
10.1016/j.carbpol.2018.11.056
Bio-based polymer colorants from nonaqueous reactive dyeing of regenerated cellulose for plastics and textiles.
Jiangbin Zhao (2019)
10.1016/j.jclepro.2019.118201
Ionic liquid groups modified 3D porous cellulose microspheres for selective adsorption of AO7 dye
Yi Wan (2019)
10.1016/j.matpr.2020.01.513
Synthesis and characterization of local biomass supported magnetic catalyst for esterification reaction
Shamala Gowri Krishnan (2020)
10.1039/d0gc00924e
Functionalized magnetic nanosized materials for efficient biodiesel synthesis via acid–base/enzyme catalysis
Anping Wang (2020)
10.1016/J.RENENE.2018.10.035
Euonymus maackii Rupr. Seed oil as a new potential non-edible feedstock for biodiesel
Ju-Zhao Liu (2019)
10.1016/j.renene.2020.03.031
Synergism effect of first row transition metals in experimental and theoretical activity of NiM/rGO alloys at hydrogen evolution reaction in alkaline electrolyzer
Saeedeh Kamali (2020)
10.1515/chem-2019-0088
Preparation of ternary ZnO/Ag/cellulose and its enhanced photocatalytic degradation property on phenol and benzene in VOCs
Xiao-Hang Zou (2019)
10.1080/23802359.2019.1611395
The complete chloroplast genome sequences of Pistacia chinensis Bunge, a potential bioenergy tree
Jiuheng Xu (2019)
10.1016/j.apcata.2020.117613
Assembly of polyoxometalate with graphene foam as a compressible monolithic catalyst for biodiesel production
Xiaoting Jing (2020)
10.1039/C9GC00473D
Cascade utilization of lignocellulosic biomass to high-value products
Y. Liu (2019)
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