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A Chiral Phosphine–olefin Ligand Derived From L-hydroxyproline And Its Use In The Rhodium-catalyzed Asymmetric 1,4-addition

Vasudeva Rao Gandi, Yun-teng Lu, T. Hayashi, T. Hayashi
Published 2015 · Chemistry

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A new chiral phosphine–olefin ligand (S)-1 has been designed and synthesized from l-hydroxyproline via a short reaction sequence. It was examined for its efficiency in the rhodium-catalyzed asymmetric addition of arylboronic acids and a phenylzinc reagent to cyclic α,β-unsaturated ketones, giving 1,4-addition products with high enantioselectivities.
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