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Unusual Chemical Behaviour Of Silylated 1,2-dithiins Under Lewis Acid Conditions

A. Degl'innocenti, A. Capperucci, I. Malesci, G. Castagnoli
Published 2005 · Chemistry

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Abstract Different silylated 1,2-dithiins, obtained through self-dimerization of the related α,β-ethylenic thioacylsilanes, in the presence of AlCl 3 show an unusual rearrangement leading in good yields to novel silyl-endodisulfide bicyclic systems.
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