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Aza-Henry Reaction Of Substituted Nitroalkanes Using α-formamidoaryl Sulfones As N-acylimino Equivalents

M. Petrini, E. Torregiani
Published 2006 · Chemistry

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Base-promoted elimination of p-toluenesulfinic acid from N-formamidoaryl sulfones leads to the corresponding N-acylimines that react with primary and secondary nitronate anions giving anti-β-formamido nitroderivatives in good yields and high diastereoselectivity.
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