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Stereochemical Analysis Of Alicyclic Compounds By C-13 NMR Spectroscopy

J. K. Whitesell, M. Minton, K. J. Toyne
Published 1987 · Chemistry

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1 Fundamental Effects on Carbon Shifts.- 1.1 Simple examples.- 1.2 Substituent shift effects.- 2 Mono- and Bicyclic Systems.- 2.1 Monocyclic systems.- 2.2 Bicyclic systems.- 3 Stereochemical Considerations.- 3.1 Gauche ? effects.- 3.2 ? Eclipsed interactions.- 3.3 ? Anti interactions.- 3.4 Enforced ? Sinteractions.- 4 Multiple Substituent Shift Additivity.- 4.1 Examples.- 4.2 Polarizable groups.- 4.3 Conformationally mobile systems.- 5 Bicyclo[2.2.1]heptanes.- 5.1 Saturated bicyclo [2.2.1] heptanes.- 5.2 Unsaturated bicyclo[2.2.1]heptanes.- 6 Bicyclo [2.2.2] octanes.- 7 Bicyclo [3.1.0] hexanes.- 8 Bicyclo [3.1.1] heptanes.- 9 Bicyclo [3.2.0] heptanes.- 10 Bicyclo [3.2.1] octanes.- 11 Bicyclo [3.2.2] nonanes.- 12 Bicyclo [3.3.0] octanes.- 13 Bicyclo[3.3.1]nonanes and Tricyclo [3.3.1.13,7] decanes.- 13.1 Bicyclo[3.3.1]nonanes.- 13.2 Tricyclo [3.3.1.13,7] decanes.- 14 Bicyclo [4.1.0] heptanes.- 15 Bicyclo [4.2.0] octanes.- 16 Bicyclo [4.3.0] nonanes.- 16.1 cis-Bicyclo[4.3.0]nonanes.- 16.2 trans-Bicyclo [4.3.0] nonanes.- 17 Bicyclo [4.4.0] decanes.- 17.1 cis-Bicyclo[4.4.0]decanes.- 17.2 trans-Bicyclo[4.4.0]decanes.- 18 Spirocyclics.- 18.1 Spiro[3.4]octanes.- 18.2 Spiro [3.5] nonanes.- 18.3 Spiro [4.4] nonanes.- 18.4 Spiro [4.5] decanes.- 18.5 Spiro [5.5] undecanes.



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