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Structural Effect On The Electrochemical Properties Of Polythiophene And Derivatives

G. Tourillon, F. Garnier
Published 1984 · Chemistry

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Abstract Grafted polythiophenes behave like modified electrodes, and even at large thicknesses, the whole film is electroactive. Due to the fibrillar structure of these polymers, the dopants do not modify the electrochemical characteristics, and the solvent has only a slight influence. When bulky groups are substituted on the β-carbon atoms in the thiophene unit, steric factors increase rapidly and render the oxidation and the reduction more and more difficult, owing to the loss of conjugation in the polymeric chains.
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