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Etude Dans La Serie Des Organosilylazoles : II. Reaction D'addition Nucleophile Sur Les Derives Carbonyles

J. Gasparini, R. Gassend, J. Maire, J. Elguero
Published 1981 · Chemistry

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Abstract The reactivity of organosilicon amines of imidazole, 1,2,4-triazole and benzotriazole towards aldehydes and ketones has been studied. Aldehydes react easily and give the addition products at room temeperature. With ketones, the reactions depend both on the organosilicon amine and the ketone used. With trimethylsilyl-1 imidazole, ketones hakving an enolic form stabilized by conjugation, form enoxysilanes.
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