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An Easy Access To α,β-unsaturated Thioacylsilanes: A Useful Route To Silylated 1,2-dithiins

A. Capperucci, A. Degl'innocenti, S. Biondi, T. Nocentini, G. Rinaudo
Published 2003 · Chemistry

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Abstract Treatment of different silylated allenes with hexamethyldisilathiane (HMDST) in the presence of CoCl2·6H2O affords an easy and high yielding access to α,β-unsaturated thioacylsilanes, which undergo a self-dimerization reaction to afford polyfunctionalized 1,2-dithiins as the major products.
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