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Deposition Of Copper Sulfide On Modified Low-density Polyethylene Surface: Morphology And Electrical Characterization

M. H. Kunita, E. M. Girotto, E. Radovanovic, M. Gonçalves, O. P. Ferreira, E. Muniz, A. F. Rubira
Published 2002 · Chemistry

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Abstract The modification of polyethylene surface has been used to obtain better interaction between organic polymeric surfaces and inorganic species. A previous treatment with modifiers is required in order to provide the adherence to the polymer surface. Our objective was the synthesis and the electrical characterization of copper sulfide coated low-density polyethylene (CuS-LDPE) films. SEM micrographs and AFM images showed a homogeneous distribution of copper sulfide, which contributes to the increasing of the electrical conductivity. X-ray analysis showed an increase of the copper sulfide crystals according to the number of immersions in the precursor sulfide solution. The measured conductivity of the CuS-LDPE films was in the range of 3.6–163.3 S cm −1 , according to the number of immersions on the precursor solution.
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