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Poly(2-decylthieno[3,4-b]thiophene). A New Soluble Low-Bandgap Conducting Polymer

M. Pomerantz, X. Gu
Published 1997 · Materials Science

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Abstract A new soluble low-bandgap conducting polymer, poly(2-decylthieno[3,4- b ]thiophene) ( 5 ), has been prepared by a multistep synthetic sequence. The vis-NIR spectra of a film of 5 showed λ max = 738 nm with a band-edge bandgap of 1.2 eV. FeCl 3 doping of the film gave a conductivity of 7.2 × 10 −2 S cm − . The GPC molecular weight was n = 30,000.
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