Online citations, reference lists, and bibliographies.
Please confirm you are human
(Sign Up for free to never see this)
← Back to Search

Synthesis Mechanical Properties And Self-healing Behavior Of Aliphatic Polycarbonate Hydrogels Based On Cooperation Hydrogen Bonds

Chaoxian Chen, N. Duan, Siwen Chen, Zhihao Guo, J. Hu, J. Guo, Z. Chen, L. Yang
Published 2020 · Materials Science

Save to my Library
Download PDF
Analyze on Scholarcy
Share
Abstract The weak mechanical property of hydrogels is a major obstacle to their extensive applications. Although many strategies are devoted to improve their mechanical properties, it is still a challenge to synthesize hydrogels with excellent mechanical properties and highly self-healing behaviors. Herein, we develop a novel aliphatic polycarbonate hydrogels with collaborative hydrogen bonds. In this work, the monomer 2-methyl-2-benzyloxy carbonyl propylene carbonate (MBC) is ring-opened by the hydroxyl group of methoxy poly(ethylene glycol) (mPEG113, Mn = 5000) based on the bulk polymerization approach. The monomer MBC as a hard segment contains abundant oxygen atoms and has a relatively high dynamic because of the steric effect of the benzene ring, which will facilitate further the formation of cooperative hydrogen bonds between the carbonyl and hydroxyl groups. The obtained hydrogels exhibited the excellent properties, such as outstanding mechanical properties, including higher storage modulus and loss modulus, it can be adjusted by the variation of the catalyst ratio. The brilliant ability of self-healing at room temperature that only takes 3 h to heal the fracture surface, without requiring any external stimuli. Thus, we provide a prospective strategy for the fabrication of split-new tough hydrogel with cooperative hydrogen bonding, which will increase the possibility of wide application of hydrogel.
This paper references
10.1016/J.MOLLIQ.2019.02.033
Layered double hydroxide/polyacrylamide nanocomposite hydrogels: Green preparation, rheology and application in methyl orange removal from aqueous solution
Xiu-Jie Yang (2019)
10.1038/nature11409
Highly stretchable and tough hydrogels
Jeong-Yun Sun (2012)
10.1021/acs.macromol.9b01686
Double-Network Physical Cross-Linking Strategy To Promote Bulk Mechanical and Surface Adhesive Properties of Hydrogels
Li Tang (2019)
10.1016/j.colsurfb.2008.08.026
pH-responsive self-assembly and conformational transition of partially propyl-esterified poly(alpha,beta-L-aspartic acid) as amphiphilic biodegradable polyanion.
Y. Wang (2009)
10.1021/acs.biomac.7b01688
Weak Hydrogen Bonds Lead to Self-Healable and Bioadhesive Hybrid Polymeric Hydrogels with Mineralization-Active Functions.
Lijing Teng (2018)
10.3390/nano9070937
Highly Stretchable and Self-Healing Strain Sensors Based on Nanocellulose-Supported Graphene Dispersed in Electro-Conductive Hydrogels
Chunxiao Zheng (2019)
10.1080/02678292.2018.1499974
Synthesis and liquid crystal properties of new cyclic carbonate monomers functionalised with cholesteryl moiety
X. Liu (2018)
10.1021/JACS.6B09014
Hierarchical Assembly of Bioactive Amphiphilic Molecule Pairs into Supramolecular Nanofibril Self-Supportive Scaffolds for Stem Cell Differentiation.
Zhe Wang (2016)
10.1021/acsami.7b16880
Counteranion-Mediated Intrinsic Healing of Poly(ionic liquid) Copolymers.
Panlong Guo (2018)
10.1016/j.foodhyd.2020.105751
β-cyclodextrin- soy soluble polysaccharide based core-shell bionanocomposites hydrogel for vitamin E swelling controlled delivery
M. Eid (2020)
10.1021/ACS.MACROMOL.5B00422
Polymer Adsorbed Bilayer Membranes Form Self-Healing Hydrogels with Tunable Superstructure
X. Li (2015)
10.1002/adma.201606117
Fluorescent Supramolecular Polymeric Materials.
H. Wang (2017)
10.1021/ACS.MACROMOL.6B02106
Supramolecular Hydrogel Formation Based on Tannic Acid
Hailong Fan (2017)
10.1002/marc.201500256
Hydrogen-Bonding Toughened Hydrogels and Emerging CO2-Responsive Shape Memory Effect.
B. Xu (2015)
10.1021/acsami.8b01725
Cooperative Assembly of a Peptide Gelator and Silk Fibroin Afford an Injectable Hydrogel for Tissue Engineering.
B. Cheng (2018)
10.1021/ACS.MACROMOL.6B00584
Dual Physically Cross-Linked Hydrogels with High Stretchability, Toughness, and Good Self-Recoverability
Y. Hu (2016)
10.1016/J.JALLCOM.2017.03.157
PAMPS/MMT composite hydrogel electrolyte for solid-state supercapacitors
J. Wang (2017)
10.1021/MA010625X
Effects of Carboxyls Attached at Alkyl Side Chain Ends on the Lamellar Structure of Hydrogels
T. Miyazaki (2001)
10.1002/marc.201900650
Transparent, High-Strength, and Shape Memory Hydrogels from Thermo-Responsive Amino Acid-Derived Vinyl Polymer Networks.
T. Koga (2020)
10.1002/PPAP.201600215
Macroscopic control of DMAHEMA and HEMA plasma polymerization to tune the surface mechanical properties of hydrogel‐like coatings
Mathieu Veuillet (2017)
10.1021/ACS.MACROMOL.7B01815
Two-Way Reversible Shape Memory Polymers Made of Cross-Linked Cocrystallizable Random Copolymers with Tunable Actuation Temperatures
Kaojin Wang (2017)
10.1016/j.foodhyd.2020.105730
Encapsulation of lycopene in emulsions and hydrogel beads using dual modified rice starch: Characterization, stability analysis and release behaviour during in-vitro digestion
Surangna Jain (2020)
10.1021/ar5001007
Engineering responsive polymer building blocks with host-guest molecular recognition for functional applications.
J. Hu (2014)
10.1002/adma.201700533
Skin-Inspired Multifunctional Autonomic-Intrinsic Conductive Self-Healing Hydrogels with Pressure Sensitivity, Stretchability, and 3D Printability.
M. Darabi (2017)
10.1039/c7sm01058c
Self-adaptive hydrogels to mineralization.
T. Shoaib (2017)
10.1016/j.carbpol.2020.116160
Sustainable, flexible and biocompatible hydrogels derived from microbial polysaccharides with tailorable structures for tissue engineering.
Xiaoliang Qi (2020)
10.1002/POLB.24620
Hydrogen bond‐reinforced double‐network hydrogels with ultrahigh elastic modulus and shape memory property
Y. Wang (2018)
10.1016/j.carbpol.2020.116125
Comparison of cast films and hydrogels based on chitin nanofibers prepared using TEMPO/NaBr/NaClO and TEMPO/NaClO/NaClO2 systems.
Wenbo Ye (2020)
10.1002/MACP.201900019
Viscoelastic Evaluation of Poly(Trimethylene Carbonate)s Bearing Oligoethylene Glycol Units Which Show Thermoresponsive Properties at Body Temperature
Yoshiaki Haramiishi (2019)
10.1021/ACS.MACROMOL.9B00032
A Self-Healing and Highly Stretchable Polyelectrolyte Hydrogel via Cooperative Hydrogen Bonding as a Superabsorbent Polymer
E. Su (2019)
10.1021/ACS.MACROMOL.6B02422
Dynamics of Dual Networks: Strain Rate and Temperature Effects in Hydrogels with Reversible H-Bonds
X. Hu (2017)
10.1111/jfpp.14426
Study on liquid core barberry (Berberis vulgaris) hydrogel beads based on calcium alginate: Effect of storage on physical and chemical characterizations
M. Maleki (2020)
10.1021/ACS.MACROMOL.7B01261
Malleable, Mechanically Strong, and Adaptive Elastomers Enabled by Interfacial Exchangeable Bonds
Z. Tang (2017)
10.1016/J.MOLLIQ.2018.08.141
Structural and molecular response in cyclodextrin-based pH-sensitive hydrogels by the joint use of Brillouin, UV Raman and Small Angle Neutron Scattering techniques
B. Rossi (2018)
10.1016/S0022-2860(98)00343-3
The importance of cooperativity for the properties of liquid water
W. A. Luck (1998)
10.1007/s13726-019-00759-7
Preformed particle gels of sulfonated polyacrylamide: preparation, characterization, and application as permeability modifier
A. Heidari (2019)
10.1016/J.PROGPOLYMSCI.2015.07.002
Self-healing polymeric materials based on microencapsulated healing agents: From design to preparation
D. Y. Zhu (2015)
10.3390/nano8110882
Exploring the Role of Nanoparticles in Enhancing Mechanical Properties of Hydrogel Nanocomposites
J. Zaragoza (2018)
10.1002/jps.22467
Poly(ethylene glycol)-block-poly(2-methyl-2-benzoxycarbonyl-propylene carbonate) micelles for rapamycin delivery: in vitro characterization and biodistribution.
Wenli Lu (2011)
10.1016/j.biomaterials.2020.119794
Injectable hydrogel enables local and sustained co-delivery to the brain: Two clinically approved biomolecules, cyclosporine and erythropoietin, accelerate functional recovery in rat model of stroke.
Anup Tuladhar (2020)
10.1016/j.foodhyd.2020.105692
Tribology and rheology of bead-layered hydrogels: Influence of bead size on sensory perception
Ecaterina Stribiţcaia (2020)
10.1021/acsami.9b14756
Highly Tough Hydrogels with Body Temperature-Responsive Shape Memory Effect.
Ruixue Liang (2019)
10.1002/POLA.28728
Control of thermoresponsivity of biocompatible poly(trimethylene carbonate) with direct introduction of oligo(ethylene glycol) under various circumstances
Nalinthip Chanthaset (2017)
10.1039/C9TB00372J
Biomimetic anisotropic poly(vinyl alcohol) hydrogels with significantly enhanced mechanical properties by freezing–thawing under drawing
Yuan-yuan Chen (2019)
10.1039/C7RA05120D
New endeavours involving the cooperative behaviour of TMAO and urea towards the globular state of poly(N-isopropylacrylamide)
Payal Narang (2017)
10.1016/J.MOLLIQ.2018.06.117
β-Cyclodextrin hydroxypropyl methylcellulose hydrogels for bisphenol A adsorption
Ícaro F.T. de Souza (2018)
10.1016/j.molliq.2019.112010
Self-assembled copper/cobalt-containing polypyrrole hydrogels for highly efficient ORR electrocatalysts
Yuting Meng (2020)
10.1021/JP070203A
Cooperative hydrogen bonds of macromolecules. 3. A model study of the proximity effect.
J. Kříž (2007)
10.1039/c9cp03300a
Cooperatively enhanced hydrogen bonds in ionic liquids: closing the loop with molecular mimics of hydroxy-functionalized cations.
T. Niemann (2019)
10.1021/acs.macromol.7b01832
Strategies To Increase the Thermal Stability of Truly Biomimetic Hydrogels: Combining Hydrophobicity and Directed Hydrogen Bonding
Hongbo Yuan (2017)
10.1016/J.PROGPOLYMSCI.2015.04.001
Recent progress in shape memory polymer: New behavior, enabling materials, and mechanistic understanding
Q. Zhao (2015)
10.1007/s10118-017-1960-3
A mechanically strong conductive hydrogel reinforced by diaminotriazine hydrogen bonding
Q. Wu (2017)
10.1039/C3SM52015C
Self-healing polyacrylic acid hydrogels
Umit Gulyuz (2013)
10.1007/s11095-018-2506-2
Improving Plasma Stability and Bioavailability In Vivo of Gemcitabine Via Nanoparticles of mPEG-PLG-GEM Complexed with Calcium Phosphate
W. Chu (2018)
10.1021/ACS.MACROMOL.9B01413
High-Performance Lignin-Containing Polyurethane Elastomers with Dynamic Covalent Polymer Networks
W. Liu (2019)
10.1016/j.molliq.2019.112087
Development of high alginate comprised hydrogels for removal of Pb(II) ions
K. Varaprasad (2020)
10.1021/BM990017D
Structural and rheological properties of methacrylamide modified gelatin hydrogels.
A. Van Den Bulcke (2000)
10.1021/MA401053C
Facile Fabrication of Tough Hydrogels Physically Cross-Linked by Strong Cooperative Hydrogen Bonding
G. Song (2013)
10.1021/ACS.MACROMOL.7B00162
Bulk Energy Dissipation Mechanism for the Fracture of Tough and Self-Healing Hydrogels
Tao Sun (2017)
10.1039/d0ta04933f
Highly efficient self-healing materials with excellent shape memory and unprecedented mechanical properties
Chaoxian Chen (2020)
10.1039/C7PY00223H
Highly cost-effective and high-strength hydrogels as dye adsorbents from natural polymers: chitosan and cellulose
Hu Tu (2017)
10.1016/j.molliq.2019.112072
Experimental model to describe the dielectric response of different dye and nanoparticles doped hydrogels for biological cell membranes and biological systems
R. Coskun (2019)
10.1002/adma.201702616
Tough Self-Healing Elastomers by Molecular Enforced Integration of Covalent and Reversible Networks.
J. Wu (2017)
10.1002/MACP.201700636
High‐Strength, Thermally Activated Shape Memory Hydrogels Based on Hydrogen Bonding between MAAc and NVP
C. Xu (2018)
10.1080/02678292.2019.1587527
Synthesis and mesomorphism of the liquid crystal based on diosgenyl end-capped polycarbonate
Chaoxian Chen (2019)
10.1016/J.MOLLIQ.2019.111576
Self-assembled polyelectrolyte-based composite hydrogels with enhanced stretchable and adsorption performances
R. Wang (2019)
10.1016/J.MOLLIQ.2018.12.073
Experimental, modeling and simulation investigations of a novel surfmer-co-poly acrylates crosslinked hydrogels for water shut-off and improved oil recovery
A. N. El-hoshoudy (2019)
10.1021/acs.biomac.7b00950
Reduction-Responsive Polypeptide Micelles for Intracellular Delivery of Antineoplastic Agent.
W. Xu (2017)
10.1002/POLA.28679
Photoresponsive biodegradable poly(carbonate)s with pendent o-nitrobenzyl ester
Huihui Shen (2017)
10.1016/j.molliq.2020.112472
Synthesis and characterization of cross-linked hydrogels using polyvinyl alcohol and polyvinyl pyrrolidone and their blend for water shut-off treatments
Reena (2020)



This paper is referenced by
Semantic Scholar Logo Some data provided by SemanticScholar