← Back to Search
Synthesis Of Poly(acrylamide-co-itaconic Acid)/MWCNTs Superabsorbent Hydrogel Nanocomposite By Ultrasound-assisted Technique: Swelling Behavior And Pb (II) Adsorption Capacity.
Alireza Mohammadinezhad, G. B. Marandi, M. Farsadrooh, H. Javadian
Published 2018 · Chemistry, Medicine
Download PDFAnalyze on Scholarcy
In this research, the poly (acrylamide-co-itaconic acid)/multi-walled carbon nanotubes (P(AAm-co-IA)/MWCNTs) as a novel superabsorbent hydrogel nanocomposite was synthesized by graft copolymerization of acrylamide (AAm) and itaconic acid (IA) mixture in the presence of the MWCNTs using ammonium persulfate (APS) as a free radical initiator and methylenebisacrylamide (MBA) as a crosslinker under ultrasound-assisted condition. The blank P(AAm-co-IA) hydrogel and its composite with the MWCNTs were characterized by means of SEM, FTIR, XRD and TGA methods. The effects of different parameters such as pH, time, the MWCNTs content and salt solutions on swelling behavior were investigated. The stability of the hydrogel increased by any increase in the MWCNTs content, which might be attributed to the hydrophobic nature of the MWCNTs as well as the increase of the crosslinker density. The water retention capacity (WRC) of the P(AAm-co-IA) hydrogel increased in the presence of the MWCNT (10 wt%). The synthesized hydrogel nanocomposite was studied for Pb (II) adsorption from aqueous solution. The effects of different parameters such as contact time (5-90 min), Pb (II) initial concentration (25-175 mg/L) and initial pH (1.5-4.5) of solution on Pb (II) adsorption were investigated by batch method. In comparison to P(AAm-co-IA) hydrogel, the P(AAm-co-IA)/MWCNTs hydrogel nanocompoite showed better adsorption behavior toward Pb (II). One of the most important aspects of this research was to investigate the effects of ultrasonic waves on polymer matrix and its ability.
This paper references
Synthesis, characterization and swelling behavior of superabsorbent wheat straw graft copolymers.
Q. Li (2012)
Ultrasonic-assisted synthesis of superabsorbent hydrogels based on sodium lignosulfonate and their adsorption properties for Ni2.
X. Wang (2018)
Removal of Pb2+ Ions from Water by Poly(Acrylamide-co-Sodium Methacrylate) Hydrogels
M. K. Kalagasidis Krušić (2012)
Comparative adsorption of Cu(II), Zn(II), and Pb(II) ions in aqueous solution on the crosslinked chitosan with epichlorohydrin.
Arh-Hwang Chen (2008)
Ultrasound stimulus inducing change in hydrogen bonded crosslinking of aqueous polyvinyl alcohols.
Josué Addiel Venegas-Sánchez (2014)
Equilibria and Capacities for Adsorption on Carbon
W. J. Weber (1964)
Synthesis of linear low-density polyethylene-g-poly (acrylic acid)-co-starch/organo-montmorillonite hydrogel composite as an adsorbent for removal of Pb(ΙΙ) from aqueous solutions.
M. Irani (2015)
Modified chitosan 4. Superabsorbent hydrogels from poly(acrylic acid-co-acrylamide) grafted chitosan with salt- and pH-responsiveness properties
G. R. Mahdavinia (2004)
in situ FTIR study of adhesive interactions of 4,4′-methylene diphenyl diisocyanate and native metals
Frank Fug (2014)
THE CONSTITUTION AND FUNDAMENTAL PROPERTIES OF SOLIDS AND LIQUIDS. PART I. SOLIDS.
I. Langmuir (1916)
Preparation of poly(acrylic acid)–graphite oxide superabsorbent nanocomposites
Zhaoqi Zhu (2012)
Isotherms and kinetic study of ultrasound-assisted adsorption of malachite green and Pb2+ ions from aqueous samples by copper sulfide nanorods loaded on activated carbon: Experimental design optimization.
E. Sharifpour (2018)
Nanospace engineering and functionalization of MCM-48 mesoporous silica with dendrimer amines based on [1,3,5]-triazines for selective and pH-independent sorption of silver ions from aqueous solution and electroplating industry wastewater
Reza Taheri (2017)
Removal of Brilliant Green from wastewater using conventional and ultrasonically prepared poly(acrylic acid) hydrogel loaded with kaolin clay: A comparative study.
S. R. Shirsath (2013)
Conversion of organosolv lignin into an efficient mercury ion adsorbent by a microwave-assisted method
Y. Ge (2016)
Fuzzy logic modeling of Pb (II) sorption onto mesoporous NiO/ZnCl2-Rosa Canina-L seeds activated carbon nanocomposite prepared by ultrasound-assisted co-precipitation technique.
H. Javadian (2018)
Structure of polyvinyl alcohol-g-acrylic acid-2-acrylamido-2-methyl-1-propanesulfonic acid hydrogel and adsorption mechanism for advanced Pb(II) removal
Bing Hui (2016)
Fast and Efficient Removal of Cationic Dyes From Aqueous Solution by Collagen-Based Hydrogel Nanocomposites
G. B. Marandi (2013)
Swelling behavior of poly(N-cyclohexylacrylamide-co-acrylamide/AMPSNa) gold nanocomposite hydrogels.
E. Kayalvizhy (2016)
Effect of multiwalled carbon nanotube-grafted polymer brushes on the mechanical and swelling properties of polyacrylamide composite hydrogels
Z. Li (2016)
Semi‐IPN carrageenan‐based nanocomposite hydrogels: Synthesis and swelling behavior
G. R. Mahdavinia (2010)
Removal of heavy metals from aqueous solutions by multi-walled carbon nanotubes modified with 8-hydroxyquinoline
S. Kosa (2012)
Response surface methodology approach for optimization of simultaneous dye and metal ion ultrasound-assisted adsorption onto Mn doped Fe3O4-NPs loaded on AC: kinetic and isothermal studies.
Arash Asfaram (2015)
Adsorption of lead ions using a modified lignin hydrogel
Qingxin Yao (2014)
Isothermal crystallization behavior of β-nucleated isotactic polypropylene with different melt structures
J. Kang (2014)
Dual-stimuli sensitive composites based on multi-walled carbon nanotubes and poly(N,N-diethylacrylamide-co-acrylic acid) hydrogels
H. Liu (2010)
Application of kinetic, isotherm and thermodynamic models for the adsorption of Co(II) ions on polyaniline/polypyrrole copolymer nanofibers from aqueous solution
H. Javadian (2014)
Three-dimensional composite hydrogel based on polyamine zirconium oxide, alginate and tannic acid with high performance for Pb(II), Hg(II) and Cr(VI) trapping
Y. Zhang (2016)
Water retention and dye adsorption behavior of Gg-cl-poly(acrylic acid-aniline) based conductive hydrogels
K. Sharma (2014)
Pseudo-second order model for sorption processes
Y. Ho (1999)
Highly selective adsorption of lead ions by water-dispersible magnetic chitosan/graphene oxide composites.
Lulu Fan (2013)
ABOUT THE THEORY OF SO-CALLED ADSORPTION OF SOLUTION SUBSTANCES
S. Lagergren (1898)
Adsorption characteristics of Ni(II) from aqueous solution and industrial wastewater onto Polyaniline/HMS nanocomposite powder
H. Javadian (2013)
Swelling and electroresponsive characteristics of gelatin immobilized onto multi-walled carbon nanotubes
S. Haider (2007)
Lignin microspheres: An effective and recyclable natural polymer-based adsorbent for lead ion removal
Y. Ge (2016)
Swelling, mechanical and friction properties of PVA/PVP hydrogels after swelling in osmotic pressure solution.
Y. Shi (2016)
A novel semi-IPN hydrogel: Preparation, swelling properties and adsorption studies of Co (II)
X. Wang (2016)
Hydrothermal effect and mechanical stress properties of carboxymethylcellulose based hydrogel food packaging.
Adriána Gregorová (2015)
Synthesis and characterization of collagen-based hydrogel nanocomposites for adsorption of Cd2+, Pb2+, methylene green and crystal violet
M. Kurdtabar (2015)
Adsorption of copper(II), lead(II), and cadmium(II) ions from aqueous solution by using hydrogel with magnetic properties
G. Mahmoud (2013)
Effect of hydrophobic monomer on the synthesis and swelling behaviour of a collagen‐graft‐poly[(acrylic acid)‐co‐(sodium acrylate)] hydrogel
Gholam Bagheri Marandi (2009)
Poly(vinyl pyrrolidone) wrapped multi-walled carbon nanotube/poly(vinyl alcohol) composite hydrogels
Y. Huang (2011)
Study of the adsorption of Cd (II) from aqueous solution using zeolite-based geopolymer, synthesized from coal fly ash; kinetic, isotherm and thermodynamic studies
H. Javadian (2015)
Synthesis of magnetic γ-Fe2O3-based nanomaterial for ultrasonic assisted dyes adsorption: Modeling and optimization.
Arash Asfaram (2016)
Preparation and characterization of novel P(HEA/IA) hydrogels for Cd2+ ion removal from aqueous solution
K. Antić (2015)
Hydrogel: Preparation, characterization, and applications: A review
E. Ahmed (2015)
Chitosan/CNTs green nanocomposite membrane: synthesis, swelling and polyaromatic hydrocarbons removal.
Saira Bibi (2015)
Application of functionalized nano HMS type mesoporous silica with N-(2-aminoethyl)-3-aminopropyl methyldimethoxysilane as a suitable adsorbent for removal of Pb (II) from aqueous media and industrial wastewater
H. Javadian (2017)
Water swelling properties of the electron beam irradiated PVA-g-AAc hydrogels
Q. Wang (2016)
Preparation of PVA/α-MnO2-KH550 nanocomposite films and study of their morphology, thermal, mechanical and Pb(II) adsorption properties
S. Mallakpour (2017)
Removal of lead from water by amino modified multi-walled carbon nanotubes
G. Vuković (2011)
Application of polyrhodanine modified multi-walled carbon nanotubes for high efficiency removal of Pb(II) from aqueous solution
Bahareh Alizadeh (2016)
Structure of PVA/gelatin hydrogel beads and adsorption mechanism for advanced Pb(II) removal
Bing Hui (2015)
Hydrogel with high laponite content as nanoclay: swelling and cationic dye adsorption properties
G. B. Marandi (2014)
Adsorption of lead(II) ions from aqueous solution on low-temperature exfoliated graphene nanosheets.
Z. Huang (2011)
Swelling, pH sensitivity, and mechanical properties of poly(acrylamide-co-sodium methacrylate) nanocomposite hydrogels impregnated with carboxyl-functionalized carbon nanotubes
Zhanqing Liu (2012)
Modified carrageenan 3. Synthesis of a novel polysaccharide-based superabsorbent hydrogel via graft copolymerization of acrylic acid onto kappa-carrageenan in air
A. Pourjavadi (2004)
Graphene/gelatin hydrogel composites with high storage modulus sensitivity for using as electroactive actuator: Effects of surface area and electric field strength
Thawatchai Tungkavet (2015)
Chitosan reinforced with modified CaCO3 nanoparticles to enhance thermal, hydrophobicity properties and removal of cu(II) and cd(II) ions
S. Mallakpour (2017)
Utilization of ultrasonic irradiation as a green and effective strategy to prepare poly(N-vinyl-2-pyrrolidone)/modified nano-copper (II) oxide nanocomposites.
S. Mallakpour (2017)
Comparison of novel sorbents for preconcentration of metal ions prior to their flame atomic absorption spectrometry determination
M. Ghaedi (2013)
Preparation of nanomaterials for the ultrasound-enhanced removal of Pb2+ ions and malachite green dye: Chemometric optimization and modeling.
E. A. Dil (2017)
Multiwalled carbon nanotube–polyurethane (MWCNT/PU) composite adsorbent for safranin T and Pb(II) removal from aqueous solution: Batch and fixed-bed studies
T. Khan (2015)
PEG-PCL based micelle hydrogels as oral docetaxel delivery systems for breast cancer therapy.
Y. Wang (2014)
Removal of lead ions from water using a resin of mimosa tannin and carbon nanotubes
F. H. M. Luzardo (2017)
Synthesis and characterization of polyaniline/γ-alumina nanocomposite: A comparative study for the adsorption of three different anionic dyes
H. Javadian (2014)
Swelling properties of amino acid containing cross-linked polymeric organogels and their respective polyelectrolytic hydrogels with pH and salt responsive property
S. G. Roy (2014)
Polysaccharides based superabsorbent hydrogel from Linseed: Dynamic swelling, stimuli responsive on-off switching and drug release.
Muhammad T. Haseeb (2016)
Covalent surface modification of α-MnO2 nanorods with L-valine amino acid by solvothermal strategy, preparation of PVA/α-MnO2-L-valine nanocomposite films and study of their morphology, thermal, mechanical, Pb(II) and Cd(II) adsorption properties
S. Mallakpour (2016)
Silica-g-poly[2-(N,N-dimethyl amino) ethyl methacrylate] hybrid nanospheres with polymer brushes as stabilizer for metallic nanocolloids
B. Liu (2014)
Ultrasonic-assisted synthesis of polyvinyl alcohol/phytic acid polymer film and its thermal stability, mechanical properties and surface resistivity.
J. Li (2017)
Removal of lead ion and oil droplet from aqueous solution by lignin-grafted carbon nanotubes
Z. Li (2017)
A novel Enteromorpha based hydrogel optimized with Box–Behnken response surface method: Synthesis, characterization and swelling behaviors
Liwei Zhao (2016)
Adsorption performance of suitable nanostructured novel composite adsorbent of poly(N-methylaniline) for removal of heavy metal from aqueous solutions
H. Javadian (2014)
Experimental contribution to the understanding of transport through polydimethylsiloxanenanofiltration membranes: Influence of swelling, compaction and solvent on permeation properties
Loïc Leitner (2014)
Application of activated carbon derived from 'waste' bamboo culms for the adsorption of azo disperse dye: kinetic, equilibrium and thermodynamic studies.
Lianggui Wang (2012)
Lead removal from water by choline chloride based deep eutectic solvents functionalized carbon nanotubes
M. Alomar (2016)
Poly(vinyl alcohol)/CaCO3-diacid nanocomposite: investigation of physical and wetting properties and application in heavy metal adsorption
S. Mallakpour (2017)
Enhanced photodegradation of dye in waste water using iron vanadate nanocomposite; ultrasound-assisted preparation and characterization.
Maryam Ghiyasiyan-Arani (2017)
Collagen-g-poly(Sodium Acrylate-co-Acrylamide)/sodium montmorillonite superabsorbent nanocomposites: synthesis and swelling behavior
G. Bagheri Marandi (2011)
Carbon nanotubes as structural nanofibers for hyaluronic acid hydrogel scaffolds.
S. Bhattacharyya (2008)
Pb(II) biosorption using chitosan and chitosan derivatives beads: equilibrium, ion exchange and mechanism studies.
W. Ngah (2010)
This paper is referenced by
Enhancement of Pb(II) Adsorption and Antibacterial Performances of Sodium Alginate/Acrylic Acid Composite Hydrogel via Snowflake-like ZnO Modification
B. Wang (2020)
Modeling and optimization of ultrasound-assisted high performance adsorption of Basic Fuchsin by starch-capped zinc selenide nanoparticles/AC as a novel composite using response surface methodology.
E. Sharifpour (2020)
Enhanced antibacterial and corrosion resistance properties of Ag substituted hydroxyapatite/functionalized multiwall carbon nanotube nanocomposite coating on 316L stainless steel for biomedical application.
D. Sivaraj (2019)
Effect of bis[2-(methacryloyloxy)ethyl] phosphate as a crosslinker on poly(AAm-co-AMPS)/Na-MMT hydrogel nanocomposite as potential adsorbent for dyes: kinetic, isotherm and thermodynamic study
Mahdi Taghvay Nakhjiri (2018)
Synthesis of a superabsorbent hybrid hydrogel with excellent mechanical properties: Water transport and methylene blue absorption profiles
Stéphanie C. Ribeiro (2019)
High efficiency removal of methylene blue dye using κ-carrageenan-poly(acrylamide-co-methacrylic acid)/AQSOA-Z05 zeolite hydrogel composites
H. Mittal (2020)
Tailoring Cu substituted hydroxyapatite/functionalized multiwalled carbon nanotube composite coating on 316L SS implant for enhanced corrosion resistance, antibacterial and bioactive properties.
Durairaj Sivaraj (2020)
Removal of Cu2+ ions by cellulose nanofibers-assisted starch-g-poly(acrylic acid) superadsorbent hydrogels
Nooshin Bahadoran Baghbadorani (2019)
MWCNT induced negative real permittivity in a copolyester of Bisphenol-A with terephthalic and isophthalic acids
Z. G. Özdemir (2020)
Recent progress in the structural modification of chitosan for applications in diversified biomedical fields
H. Mittal (2018)
Effective removal of heavy metals from an aqueous solution with poly(N-vinylimidazole-acrylamide) hydrogels
V. N. Tirtom (2020)
Processing and modification of hydrogel and its application in emerging contaminant adsorption and in catalyst immobilization: a review
Hongxue Du (2020)
The effects of carbon disulfide driven functionalization on graphene oxide for enhanced Pb(II) adsorption: Investigation of adsorption mechanism.
Qiyu Lian (2020)
Adsorption of Methylene Blue, Brilliant Green and Rhodamine B from Aqueous Solution Using Collagen-g-p(AA-co-NVP)/Fe3O4@SiO2 Nanocomposite Hydrogel
Mahdi Taghvay Nakhjiri (2019)
Hydrogel composites containing nanocellulose as adsorbents for aqueous removal of heavy metals: design, optimization, and application
F. Rodrigues (2019)
Multicavity triethylenetetramine-chitosan/alginate composite beads for enhanced Cr(VI) removal
Wei Zhang (2019)
Novel pectin based composite hydrogel derived from grapefruit peel for enhanced Cu(II) removal.
W. Zhang (2019)
Poly(AA-co-VPA) hydrogel cross-linked with N-maleyl chitosan as dye adsorbent: Isotherms, kinetics and thermodynamic investigation.
Mahdi Taghvay Nakhjiri (2018)