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Enhanced Production Of Aromatic Hydrocarbons By Rapeseed Oil Conversion Over Ga And Zn Modified ZSM-5 Catalysts

R. Ramos, A. García, J. Botas, D. Serrano
Published 2016 · Chemistry

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Rapeseed oil conversion has been investigated over catalysts based on Ga- and Zn-modified nanocrystalline HZSM-5 zeolite aimed to the production of hydrocarbons that could be used as both raw chemicals and/or fuels. The reactions have been carried out in a fixed bed reactor operating under nitrogen at 550 °C and atmospheric pressure. The incorporation of the metallic species to the parent zeolite was carried out by wetness-impregnation, resulting in a good metal dispersion, which is facilitated by the relatively high external surface area available in the nanocrystalline zeolitic support. This metal addition causes significant changes in the textural and acidic properties of the ZSM-5 zeolite. In all cases, a high deoxygenation degree of the raw oil was achieved through the formation of CO, CO2, and H2O, whereas the main products obtained were light olefins (mainly ethylene and propylene) and aromatic hydrocarbons (BTX). The incorporation of Ga and Zn in the parent zeolite increased the formation of gasol...
This paper references
10.1039/C1EE01230D
Catalytic conversion of biomass-derived feedstocks into olefins and aromatics with ZSM-5: the hydrogen to carbon effective ratio
Huiyan Zhang (2011)
10.1002/CJCE.5450730408
Catalytic conversion of canola oil to fuels and chemicals over various cracking catalysts
S. Katikaneni (1995)
10.1016/0926-860X(91)80008-M
Characterization by pulsed oxidation of coke on platinum/alumina
T. D. Basso (1991)
10.1016/S0920-5861(96)00019-3
Indium and gallium containing ZSM-5 zeolites: acidity and catalytic activity in propane transformation
J. Halász (1996)
10.1016/S0926-860X(96)00124-X
Zinc promoted H-ZSM-5 catalysts for conversion of propane to aromatics II. Nature of the active sites and their activation
H. Berndt (1996)
10.1021/JP800762V
Conversion of Methanol to Hydrocarbons: Spectroscopic Characterization of Carbonaceous Species Formed over H-ZSM-5
L. Palumbo (2008)
10.1023/A:1019184004885
Solid-acid-catalyzed alkane cracking mechanisms: evidence from reactions of small probe molecules
F. Jentoft (1997)
10.1016/J.APCATB.2012.12.023
Catalytic conversion of rapeseed oil for the production of raw chemicals, fuels and carbon nanotubes over Ni-modified nanocrystalline and hierarchical ZSM-5
J. A. Botas (2014)
10.1016/J.MOLCATA.2003.11.045
Cracking and aromatization properties of some metal modified ZSM-5 catalysts for light alkane conversions
N. Viswanadham (2004)
10.1016/J.ENERGY.2009.09.001
The current status and perspectives of biofuel production via catalytic cracking of edible and non-edible oils
Yee Kang Ong (2010)
10.1016/0926-860X(95)00146-8
Activity and structure-sensitivity of the water-gas shift reaction over CuZnAl mixed oxide catalysts
M. Ginés (1995)
10.1016/J.CATTOD.2004.06.067
A new approach of coke characterization on metal and support for Pt/Al2O3 by combination of Al2O3 and Pt/SiO2
Sunee Srihiranpullop (2004)
10.1016/J.MOLCATA.2008.06.014
Deactivation of FCC catalysts
H. Cerqueira (2008)
10.1039/C2CY20415K
An overview of catalytic conversion of vegetable oils/fats into middle distillates
J. K. Satyarthi (2013)
10.1016/0926-860X(93)80093-6
Adsorption, acid and catalytic changes induced in ZSM-5 by coking with different hydrocarbons
M. A. Uguina (1993)
10.1016/J.JCAT.2006.03.004
Characterization and reactivity of Ga+ and GaO+ cations in zeolite ZSM-5
Nj Neelesh Rane (2006)
10.1016/J.APCATA.2011.03.009
Catalytic cracking of hydrocarbons over modified ZSM-5 zeolites to produce light olefins: A review
Nazi Rahimi (2011)
10.1039/C0EE00460J
Catalytic cracking of edible and non-edible oils for the production of biofuels
N. Taufiqurrahmi (2011)
10.1126/science.206.4414.57
Catalytic Production of High-Grade Fuel (Gasoline) from Biomass Compounds by Shape-Selective Catalysis
P. Weisz (1979)
10.1023/A:1019181715731
The role of zinc oxide in Cu/ZnO catalysts for methanol synthesis and the water–gas shift reaction
M. S. Spencer (1999)
10.1016/J.FUPROC.2015.01.038
Conversion of rapeseed oil via catalytic cracking: Effect of the ZSM-5 catalyst on the deoxygenation process
P. Lovás (2015)
10.1016/S0378-3820(03)00048-1
Catalytic conversion of palm oil over mesoporous aluminosilicate MCM-41 for the production of liquid hydrocarbon fuels
F. Twaiq (2003)
10.1006/JCAT.1998.2312
Reaction Pathways and Rate-Determining Steps in Reactions of Alkanes on H-ZSM5 and Zn/H-ZSM5 Catalysts☆
Joseph A. Biscardi (1999)
10.1016/S0926-860X(96)00175-5
In-situ FTIR measurements of diffusion in coking zeolite catalysts
H. Karge (1996)
10.1016/J.FUEL.2013.12.014
HDO catalysts for triglycerides conversion into pyrolysis and isomerization feedstock
J. Horácek (2014)
10.1016/J.APCATB.2012.08.030
Catalytic upgrading of biomass pyrolysis vapors using transition metal-modified ZSM-5 zeolite
E. Iliopoulou (2012)
10.1016/J.APCATB.2011.02.024
Insights into the coke deposited on HZSM-5, Hβ and HY zeolites during the cracking of polyethylene
P. Castaño (2011)
10.1134/S207005041401005X
Conversion of vegetable oils under conditions of catalytic cracking
V. Doronin (2014)
10.1016/J.CATTOD.2015.12.009
Lamellar and pillared ZSM-5 zeolites modified with MgO and ZnO for catalytic fast-pyrolysis of eucalyptus woodchips
J. Fermoso (2016)
10.1039/C1EE02418C
From biodiesel and bioethanol to liquid hydrocarbon fuels: new hydrotreating and advanced microbial technologies
J. C. Serrano-Ruiz (2012)
10.1016/j.biortech.2011.08.068
Production of biofuel from waste cooking palm oil using nanocrystalline zeolite as catalyst: process optimization studies.
N. Taufiqurrahmi (2011)
10.1016/S0926-860X(02)00271-5
Light alkanes aromatization to BTX over Zn-ZSM-5 catalysts: Enhancements in BTX selectivity by means of a second transition metal ion
L. M. Lubango (2002)
10.1016/J.CATCOM.2004.05.011
Hydrothermal stability and catalytic activity of mesoporous aluminum-containing SBA-15
Y. Ooi (2004)
10.1021/IE980758F
Catalytic Conversion of Palm Oil to Hydrocarbons: Performance of Various Zeolite Catalysts
F. Twaiq (1999)
10.1016/0021-9517(86)90226-5
Adsorptive and catalytic properties of supported metal oxides: III. Water-gas shift over supported iron and zinc oxides
D. Rethwisch (1986)
10.1016/S1381-1169(01)00374-0
An attempt to predict the optimum zeolite-based catalyst for selective cracking of naphtha-range hydrocarbons to light olefins
B. Anderson (2002)
10.1016/S1387-1811(99)00204-8
The Haag–Dessau mechanism of protolytic cracking of alkanes☆
S. Kotrel (2000)
10.1016/J.CATCOM.2011.01.015
Synergistic role of Lewis and Brönsted acidities in Friedel-Crafts alkylation of resorcinol over gallium-zeolite beta
H. Nur (2011)
10.1016/J.CATTOD.2012.04.061
Catalytic conversion of rapeseed oil into raw chemicals and fuels over Ni- and Mo-modified nanocrystalline ZSM-5 zeolite
J. A. Botas (2012)
10.1016/S0926-860X(02)00142-4
Characterization of coke on equilibrium fluid catalytic cracking catalysts by temperature-programmed oxidation
O. Bayraktar (2002)
10.1016/J.MOLCATA.2008.11.012
Prevention of zeolite deactivation by coking
M. Guisnet (2009)
10.1021/JP990116L
Introduction of Zn, Ga, and Fe into HZSM-5 Cavities by Sublimation: Identification of Acid Sites
El-M El-Malki (1999)
10.1016/J.BIORTECH.2006.10.025
Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals.
K. Maher (2007)



This paper is referenced by
10.1016/J.JAAP.2017.09.021
Aromatic recovery from distillate oil of oily sludge through catalytic pyrolysis over Zn modified HZSM-5 zeolites
B. Lin (2017)
10.1016/j.biortech.2019.01.081
Influence of physicochemical properties of metal modified ZSM-5 catalyst on benzene, toluene and xylene production from biomass catalytic pyrolysis.
Qingfeng Che (2019)
10.1039/C9CY00237E
New insight into the enhanced catalytic performance of ZnPt/HZSM-5 catalysts for direct dehydrogenation of propane to propylene
C. Chen (2019)
10.1016/J.CATCOM.2020.106176
Dimethyl ether aromatization over nanosized zeolites: Effect of preparation method and zinc modification on catalyst performance
K. V. Golubev (2021)
10.1016/J.CRCI.2017.06.006
Multilayered catalysts for fatty acid ester hydrotreatment into fuel range hydrocarbons
C. Dusescu (2017)
10.1016/j.fuproc.2019.106242
High-efficiency nano [Zn,Al]ZSM-5 bifunctional catalysts for dimethyl ether conversion to isoparaffin-rich gasoline
Xiaofang Su (2020)
10.1016/j.pecs.2020.100852
Multi-scale complexities of solid acid catalysts in the catalytic fast pyrolysis of biomass for bio-oil production – A review
Ronghou Liu (2020)
10.1016/J.JCLEPRO.2019.06.109
Thermochemical conversion of waste acidic oil into hydrocarbon products over basic composite catalysts
F. Long (2019)
10.1016/J.CATCOM.2019.01.001
Doping of K and Zn elements in FeZr-Ni/ZSM-5: Highly selective catalyst for syngas to aromatics
H. Xu (2019)
10.1002/ENTE.201800222
Study on Catalytic Performance and Deactivation Behavior of HZSM‐5 in Aromatization of Glycerol
F. Wang (2018)
10.1016/j.jaap.2020.104964
Promotion of monocyclic aromatics by catalytic fast pyrolysis of biomass with modified HZSM-5
Q. Liu (2021)
10.1021/ACS.IECR.7B03450
Effect of Metal Active Sites on the Product Distribution over Composite Catalysts in the Direct Synthesis of Aromatics from Syngas
Tianhui Yang (2017)
10.1016/j.fuel.2020.119798
Green BTX production from methyl oleate over hierarchical HZSM-5 zeolites prepared by NaOH treatment
X. Chen (2020)
10.1016/J.JAAP.2017.06.001
Catalytic liquefaction of pine sawdust for biofuel development on bifunctional Zn/HZSM-5 catalyst in supercritical ethanol
S. Cheng (2017)
10.1007/s12649-020-00962-1
Production of High-Value Chemicals by Biomass Pyrolysis with Metal Oxides and Zeolites
Jingzhen Wang (2020)
10.1016/J.JCAT.2019.04.038
Selective conversion of 5-hydroxymethylfurfural to diketone derivatives over Beta zeolite-supported Pd catalysts in water
R. Ramos (2019)
10.1039/C8GC00629F
Ga-doped Cu/H-nanozeolite-Y catalyst for selective hydrogenation and hydrodeoxygenation of lignin-derived chemicals
D. Verma (2018)
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